Creation of Alkaline IonConductor with Metal-OrganicFrameworks Having Acidic Functional Groups by Protection and Deprotection Method

• Project/Area Number: 22750053
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Inorganic chemistry
• Research Institution: Kyushu University (2012); Kyoto University (2010-2011)
• Principal Investigator: YAMADA Teppei 九州大学, 大学院・工学研究院, 准教授 (10404071)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: 配位高分子 / 保護-脱保護法 / イオン伝導 / 配置高分子 / イオン電導 / イオン交換

Research Abstract

Novel method for introducinc acidic functional groups was invented onto the inner surface of the metal-organic frameworks. Acidic functional groups were protected by organc group, which were reacted with metal ions to obtainnovel MOFs havinc acidic functional groups. We also succeeded in introducing various kinds of ionic species and also in finding MOFs showing high ionic conductivity

Research Products

• [Journal Article] Preparation of Sub-10 nm AgI Nanoparticles and a Study on their Phase Transition Temperature (2013)
  • Author(s): Yamasaki Shuhei、Yamada Teppei、Kobayashi Hirokazu、Kitagawa Hiroshi
  • Journal Title: Chem.-Asian J. Volume: Vo l. 8、No. 1 Issue: 1 Pages: 73-75
  • DOI: 10.1002/asia.201200790
  • URL: http://dx.doi.org/10.1002/asia.201200790
  • Peer Reviewed
• [Journal Article] Superprotonic Conductivity in a Highly Oriented Crystalline Metal-Organic Framework Nanofilm (2013)
  • Author(s): G. Xu, K. Otsubo, T. Yamada, S. Sakaida, H. Kitagawa
  • Journal Title: Journal of the American Chemical Society Volume: 135 Issue: 20 Pages: 7438-7441
  • DOI: 10.1021/ja402727d
  • URL: http://dx.doi.org/10.1021/ja402727d
  • Peer Reviewed
• [Journal Article] Proton-Conductive Magnetic Metal-Organic Frameworks, {NR3(CH2COOH)}[MaIIMbIII(ox)3]: Effect of Carboxyl Residue upon Proton Conduction (2013)
  • Author(s): Okawa Hisashi、Sadakiyo Masaaki、Yamad a Teppei、Maesato Mitsuhiko、Ohba Masaaki、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 1 3 5、No. 6 Issue: 6 Pages: 2256-2262
  • DOI: 10.1021/ja309968u
  • Peer Reviewed
• [Journal Article] Graphene Oxide Nanosheet with High Proton Conductivity (2013)
  • Author(s): M. Karim, K. Hatakeyama. T. Matsui, H. Takehiro, T. Taniguchi, M. Koinuma, Y. Matsumoto, T. Autogawa, T. Nakamura, S. Noro, T. Yamada, H. kitagawa, S. Hayami
  • Journal Title: Journal of the American Chemical Society Volume: 135 Issue: 22 Pages: 8097-8100
  • DOI: 10.1021/ja401060q
  • URL: http://dx.doi.org/10.1021/ja401060q
  • Peer Reviewed
• [Journal Article] A Key Mechanism of Ethanol Electrooxidation Reaction in a Noble-Metal-Free Metal-Organic Framework (2013)
  • Author(s): Ishimoto Takayoshi、Ogura Teppei、Koyama Michihisa、Yang Lifen、Kinoshita Shozo、Yamada Teppei、Tokunaga Makoto、Kitagawa Hiroshi
  • Journal Title: J. Phys. Chem. C Volume: Vo l. 11 7、No. 20 Issue: 20 Pages: 10607-10614
  • DOI: 10.1021/jp4031046
  • URL: http://dx.doi.org/10.1021/jp4031046
  • Peer Reviewed
• [Journal Article] Syntheses of metal-organic frameworks with protected phosphonate ligands (2012)
  • Author(s): Yamada Teppei、Kitagawa Hiroshi
  • Journal Title: CrystEngComm Volume: Vo l. 1 4、No. 12 Pages: 4148-4152
  • URL: http://dx.doi.org/10.1039/C2CE25358E
  • Peer Reviewed
• [Journal Article] Facile Modular Assembly for Fast Construction of Highly Oriented Crystalline MOF Nanofilm (2012)
  • Author(s): G.Xu, T. Yamada, K. Otsubo, S. Sakaida, H. Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Issue: 40 Pages: 16524-16527
  • DOI: 10.1021/ja307953m
  • URL: http://dx.doi.org/10.1021/ja307953m
  • Peer Reviewed
• [Journal Article] Selective Separation of Water, Methanol and Ethanol by a Porous Coordination Polymer Built with a Flexible Tetrahedral Ligand (2012)
  • Author(s): A. Shigematsu, T. Yamada, H. Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Issue: 32 Pages: 13145-13147
  • DOI: 10.1021/ja306401j
  • URL: http://dx.doi.org/10.1021/ja306401j
  • Peer Reviewed
• [Journal Article] High Proton Conductivity by a Metal-Organic Framework Incorporating Zn80 Clusters with Aligned Imidazolium Groups Decorating the Channels (2012)
  • Author(s): S. Sen, N. Nair, T. Yamada, H. Kitagawa, F. Bharadwaj
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Issue: 47 Pages: 19432-19437
  • DOI: 10.1021/ja3076378
  • URL: http://dx.doi.org/10.1021/ja3076378
  • Peer Reviewed
• [Journal Article] Promotion of Low-Humidity Proton Conduction by Controlling Hydrophilicity in Layered Metal-Organic Frameworks (2012)
  • Author(s): M.Sadakiyo, H.Okawa, A.Shigematsu, M.Ohba, T.Yamada, H.Kitagawa
  • Journal Title: Journal of the American Chemical Society Volume: 134 Issue: 12 Pages: 5472-5475
  • DOI: 10.1021/ja300122r
  • Peer Reviewed
• [Journal Article] Syntheses of Metal-Organic Frameworks with Protected Phosphonate Ligands (2012)
  • Author(s): T. Yamada, H. Kitagawa
  • Journal Title: CrystEngComm Volume: 14 Issue: 12 Pages: 4148-4152
  • DOI: 10.1039/c2ce25358e
  • Peer Reviewed
• [Journal Article] 空間設計の多彩さが生むプロトン伝導性やマルチフェロイック特性 (2012)
  • Author(s): 山田 鉄兵、北川 宏
  • Journal Title: 現代化学 Volume: 493 Pages: 44-45
• [Journal Article] エネルギーに対する「脇役の技術」 (2012)
  • Author(s): 山田 鉄兵
  • Journal Title: Bull. Chem. Soc. Coord. Chem. Volume: 60 Pages: 45-47
• [Journal Article] Quasi-Elastic Neutron Scattering Studies on Dynamics of Water Confined in Nanoporous Copper Rubeanate Hydrates (2011)
  • Author(s): T.Yamada, R.Yonamine, T.Yamada, H.Kitagawa, M.Tyagi, M.Nagao, O.Yamamuro
  • Journal Title: Journal of Physical Chemistry B Volume: 115 Issue: 46 Pages: 13563-13569
  • DOI: 10.1021/jp2029467
  • URL: http://dx.doi.org/10.1021/jp2029467
  • Peer Reviewed
• [Journal Article] Synthesis of A Novel Isoreticular Metal-Organic Framework by Protection and Complexation of 2,5-Dihydroxyterephthalic Acid (2011)
  • Author(s): T.Yamada, H.Kitagawa
  • Journal Title: Supramolecular Chemistry Volume: 23 Issue: 3-4 Pages: 315-318
  • DOI: 10.1080/10610278.2010.531138
  • URL: http://dx.doi.org/10.1080/10610278.2010.531138
  • Peer Reviewed
• [Journal Article] Porous Interpenetrating Metal-Organic Frameworks with Hierarchal Nodes (2011)
  • Author(s): T.Yamada, S.Iwakiri, T.Hara, K.Kanaizuka, M.Kurmoo, H.Kitagawa
  • Journal Title: Cryst.Growth Des. Volume: 11 Issue: 5 Pages: 1798-1806
  • DOI: 10.1021/cg1017278
  • URL: http://dx.doi.org/10.1021/cg1017278
  • Peer Reviewed
• [Journal Article] Structure manufacturing of proton-conducting organic-inorganic hybrid silicophosphite membranes by solventless synthesis (2011)
  • Author(s): Tokuda Yomei、Oku Satoshi、Yamada Teppei、Takahashi Masahide、Yoko Toshinobu、Kitagawa Hiroshi、Ueda Yoshikatsu
  • Journal Title: J. Mater. Res. Volume: Vo l. 2 6、No. 6 Issue: 6 Pages: 796-803
  • DOI: 10.1557/jmr.2010.89
  • NAID: 120003534361
  • Peer Reviewed
• [Journal Article] Wide Control of Proton Conductivity in Porous Coordination Polymers (2011)
  • Author(s): Shigematsu Akihito、Yamad a Tepp ei、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 133、No. 7 Issue: 7 Pages: 2034-2036
  • DOI: 10.1021/ja109810w
  • URL: http://dx.doi.org/10.1021/ja109810w
  • Peer Reviewed
• [Journal Article] Hydroxyl Group Recognition by Hydrogen-Bonding Donor and Acceptor Sites Embedded in a Layered Metal-Organic Framework (2011)
  • Author(s): M.Sadakiyo, T.Yamada, H.Kitagawa
  • Journal Title: Journal of the American Chemical Society Volume: 133 Issue: 29 Pages: 11050-11053
  • DOI: 10.1021/ja203291n
  • URL: http://pubs.acs.org/doi/abs/10.1021/ja203291n
  • Peer Reviewed
• [Journal Article] Wide Control of Proton Conductivity in Porous Coordination Polymers (2011)
  • Author(s): A.Shigematsu, T.Yamada, H.Kitagawa
  • Journal Title: Journal of the American Chemical Society Volume: Vol.133 Pages: 2034-2036
  • Peer Reviewed
• [Journal Article] Porous Interpenetrating Metal-Organic Frameworks with Hierarchal Nodes (2011)
  • Author(s): T.Yamada, S.Iwakiri, T.Hara, K.Kanaizuka, M.Kurmoo, H.Kitagawa
  • Journal Title: Crystal Growth & Design Volume: 11(5) Pages: 1798-1806
  • Peer Reviewed
• [Journal Article] Structure Manufacturing of Proton-Conducting Organic-Inorganic Hybrid Silicophosphilte Membranes by Solventless Synthesis (2011)
  • Author(s): T.Tokuda, S.Oku, T.Yamada, M.Takahashi, T.Yoko, H.Kitagawa, Y.Ueda
  • Journal Title: Journal of Materials Research Volume: Vol.26 Pages: 796-803
  • Peer Reviewed
• [Journal Article] Synthesis of A Novel Isoreticular Metal-Organic Framework by Protection and Complexation of 2,5-Dihydroxyterephthalic Acid. (2011)
  • Author(s): T.Yamada, H.Kitagawa
  • Journal Title: Supramolecular Chemistry Volume: 23 Pages: 315-318
  • Peer Reviewed
• [Journal Article] 燃料電池への元素戦略的アプローチ-配位高分子による非白金電極触媒- (2011)
  • Author(s): 山田鉄兵、北川宏
  • Journal Title: 月刊「化学」 Volume: 66 Pages: 36-41
  • NAID: 40018267444
• [Journal Article] 触媒作用と伝導性を併せ持つ配位高分子の誕生 (2011)
  • Author(s): 山田鉄兵、木下昌三、北川宏
  • Journal Title: 現代化学 Volume: 478 Pages: 50-54
• [Journal Article] A Metal-Organic Framework as an Electrocatalyst for Ethanol Oxidation (2010)
  • Author(s): Yang Lifen、Kinoshita Shozo、Yamada Teppei、Kanda Seiichi、Kitagawa Hiroshi、Tokunaga Makoto、Ishimoto Takayoshi、Ogura Teppei、Nagumo Ryo、Miyamoto Akira、Koyama Michihisa
  • Journal Title: Angew. Chem. Int. Ed. Volume: Vo l. 4 9、No. 31 Issue: 31 Pages: 5348-5351
  • DOI: 10.1002/anie.201000863
  • URL: http://dx.doi.org/10.1002/anie.201000863
  • Peer Reviewed
• [Journal Article] Calorimetric and Neutron Diffraction Studies on Transitions of Water Confined in Nanoporous Copper Rubeanate (2010)
  • Author(s): Yamada Takeshi、Yonamine Ryo、Yamad a Teppei、Kitagawa Hiroshi、Yamamuro Osamu
  • Journal Title: J. Phys. Chem. B Volume: Vo l. 1 1 4、No. 25 Issue: 25 Pages: 8405-8409
  • DOI: 10.1021/jp912212m
  • URL: http://dx.doi.org/10.1021/jp912212m
  • Peer Reviewed
• [Journal Article] Structures and Proton Conductivity of One-Dimensional M(dhbq)・nH2O (M = Mg, Mn, Co, Ni, and Zn, H2(dhbq) = 2,5-Dihydroxy-1,4-benzoquinone) Promoted by Connected Hydrogen-Bond Networks with Absorbed Water (2010)
  • Author(s): Yamada Teppei、Morikawa Shota、Kitagawa Hiroshi
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: Vo l. 8 3、No. 1 Issue: 1 Pages: 42-48
  • DOI: 10.1246/bcsj.20090216
  • NAID: 130004058970
  • URL: http://www.jstage.jst.go.jp/article/bcsj/83/1/83_42/_article
  • Peer Reviewed
• [Journal Article] Design and Characterization of a Polarized Coordination Polymer of a Zinc(II) Biphenyldicarboxylate Bearing a Sulfone Group (2010)
  • Author(s): Kanaizuka Katsuhiko、Iwakiri Shoji、Yamad a Teppei、Kitagawa Hiroshi
  • Journal Title: Chem. Lett. Volume: Vo l. 3 9、No. 1 Issue: 1 Pages: 28-29
  • DOI: 10.1246/cl.2010.28
  • NAID: 10027176334
  • URL: http://www.jstage.jst.go.jp/article/cl/39/1/39_28/_article
  • Peer Reviewed
• [Journal Article] A Metal-Organic Framework as An Electrocatalyst for Ethanol Oxidation (2010)
  • Author(s): L.Yang, S.Kinoshita, T.Yamada, S.Kanda, H.Kitagawa, M.Tokunaga, T.Ishimoto, T.Ogura, R.Nagumo, A.Miyamoto, M.Koyama
  • Journal Title: Angewandte Chemie, Intenational Edition Volume: Vol.49 Pages: 5348-5351
  • Peer Reviewed
• [Journal Article] Calorimetric and Neutron Diffraction Studies on Transitions of Water Confined in Nanoporous Copper Rubeanate (2010)
  • Author(s): T.Yamada, Ryo Yonamine, Teppei Yamada, Hiroshi Kitagawa, Osamu Yamamuro
  • Journal Title: Journal of Physical Chemistry B Volume: 114 Pages: 8405-8409
  • Peer Reviewed
• [Journal Article] 保護-脱保護法による配位高分子への官能基の導入 (2010)
  • Author(s): 山田鉄兵
  • Journal Title: 京都大学低温物質科学研究センター誌 Volume: 17 Pages: 3-9
  • NAID: 120003850825
  • Peer Reviewed
• [Journal Article] 非白金触媒を配位高分子で実現 (2010)
  • Author(s): 山田鉄兵、木下昌三、北川宏
  • Journal Title: Bulletin of the Ceramic Society of Japan
• [Presentation] 酸性配位高分子を用いたプロトン伝導体の創成 (2013)
  • Author(s): 山田 鉄兵
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
  • Invited
• [Presentation] 配位高分子(Cu(mtpm)のレドックス挙動とイオンの選択吸着挙動) (2013)
  • Author(s): 山田 鉄兵
  • Organizer: 第１回東北大学「卓越大学院」研究会
  • Place of Presentation: 東北大学
  • Invited
• [Presentation] MIL53(Al)PO3H2のプロトン伝導性とイオン交換特性 (2012)
  • Author(s): 山田鉄兵、北川宏
  • Organizer: 日本化学会
  • Place of Presentation: 慶応大学
  • Year and Date: 2012-03-28
• [Presentation] 配位高分子を用いたプロトン伝導体の創製 (2012)
  • Author(s): 山田鉄兵
  • Organizer: 山形大学理学部講演会
  • Place of Presentation: 山形大学(招待講演)
  • Year and Date: 2012-01-23
• [Presentation] 配位高分子細孔内に取り込まれたゲスト分子の相挙動 (2012)
  • Author(s): 山田鉄兵
  • Organizer: 第5回東北大学G-COE研究会
  • Place of Presentation: 東北大学(招待講演)
  • Year and Date: 2012-01-20
• [Presentation] 配位高分子の酸点を利用したプロトン伝導性と分子認識 (2012)
  • Author(s): 山田 鉄兵
  • Organizer: 第14回規則性多孔体セミナー
  • Place of Presentation: 鳥取大学
  • Invited
• [Presentation] 配位高分子の細孔を用いた固体プロトン伝導体 (2011)
  • Author(s): 山田鉄兵
  • Organizer: 第2回京都大学GCOE-理化学研究所共同シンポジウム
  • Place of Presentation: 京都大学
  • Year and Date: 2011-11-11
• [Presentation] Consecutive and Wide Control of Proton Conductivity by Embedded Functional Groups into Porous Coordination Polymers (2011)
  • Author(s): Teppei Yamada
  • Organizer: BIT's 1st International conference on nano science and technology
  • Place of Presentation: 大連、中国(招待講演)
  • Year and Date: 2011-10-25
• [Presentation] Consecutive and Wide Control of Proton Conductivity by Embedded Functional Groups into Porous Coordination Polymers (2011)
  • Author(s): Teppei YAMADA, Akihito SHIGEMATSU, Hiroshi KITAGAWA
  • Organizer: Asian Confference on Coordination Chemistry
  • Place of Presentation: デリー、インド(招待)
  • Year and Date: 2011-10-17
• [Presentation] MIL-53(Al)PO3H2Oの合成とプロトン伝導性 (2011)
  • Author(s): 山田鉄兵、北川宏
  • Organizer: 分子科学討論会
  • Place of Presentation: 札幌コンベンションセンター
  • Year and Date: 2011-09-22
• [Presentation] Synthesis and Proton Conductivity of MIL-53(Al)PO3H2 (2011)
  • Author(s): Teppei YAMADA, Hiroshi KITAGAWA
  • Organizer: 61st JSCC Symposium
  • Place of Presentation: 岡山理科大学
  • Year and Date: 2011-09-17
• [Presentation] Proton Conductivity of Preciously Controlled Hydrogen Bond Networks Constructed in Metal-Organic Frameworks (2011)
  • Author(s): Teppei YAMADA, Hiroshi KITAGAWA
  • Organizer: 分子研研究会「金属錯体の機能化の現状と将来展望」
  • Place of Presentation: 岡崎カンファレンスルーム(愛知県)
  • Year and Date: 2011-01-09
• [Presentation] Protection and Deprotection Approach for Constructing Metal-Organic Frameworks having Large Pore Aperture (2010)
  • Author(s): Teppei YAMADA, Hiroshi KITAGAWA
  • Organizer: Pacifichem 2010
  • Place of Presentation: ホノルル(ハワイ州、USA)
  • Year and Date: 2010-12-18
• [Presentation] Synthesis of Metal-Organic Frameworks Having Phosphate Group and Their Proton Conductivity (2010)
  • Author(s): Teppei YAMADA, Hiroshi KITAGAWA
  • Organizer: 60th Anniversary Conference on Coordination Chemistry in OSAKA
  • Place of Presentation: 大阪府
  • Year and Date: 2010-09-28
• [Book] Metal-Organic Frameworks: Materials, Properties and Applications (2012)
  • Author(s): Yamada Teppei、Kitagawa Hiroshi
  • Publisher: eds. O. L. Ortiz and L. D. Ramirez, Nova publishers
• [Book] Bull. Chem. Soc. Coord. Chem. Vol . 60 (2012)
  • Author(s): 山田 鉄兵
• [Book] 現代化学 Vol. 493、No. 4 (2012)
  • Author(s): 山田 鉄兵、北川 宏
• [Book] 現代化学 (2012)
  • Author(s): 山田鉄兵、北川宏
  • Total Pages: 2
  • Publisher: 空間設計の多彩さが生むプロトン伝導性やマルチフェロイック特性
• [Book] 化学同人 Vol . 66 (2011)
  • Author(s): 山田 鉄兵、北川 宏
• [Book] 触媒技術の動向と展望 Vol. 2011 (2011)
  • Author(s): 山田 鉄兵、北川 宏、牧浦 理恵
• [Book] 東京化学同人 Vol . 478 (2011)
  • Author(s): 山田 鉄兵、木下 昌三、北川 宏
• [Book] 京都大学低温物質科学研究センター誌 Vol . 17 (2010)
  • Author(s): 山田 鉄兵
  • Publisher: 京都大学低温物質科学センター
• [Book] 空間を持つ機能性物質の創成 Vol . 3 (2010)
  • Author(s): 山田 鉄兵、北川 宏
• [Book] Bulletin of the Ceramic Society of Japan Vol . 45 (2010)
  • Author(s): 山田 鉄兵、木下 昌三、北川 宏
  • Total Pages: 930
  • Publisher: 日本セラミックス協会
• [Book] CSJカレントレビュー3、革新的な多孔質材料空間を持つ機能性物質の創成 (2010)
  • Author(s): 日本化学会(編集)
  • Publisher: 化学同人
• [Remarks] 受賞 1. 第62回進歩賞(日本化学会) 酸性配位高分子を用いたプロトン伝導体の創成、2013年3月
• [Remarks] 受賞 2. 錯体化学会研究奨励賞(錯体化学会) 配位高分子を用いたプロトン伝導体の創成、2012年9月
• [Remarks] 受賞 3. 第1回新化学技術研究奨励賞(新化学技術推進協会)課題2:世界に先駆ける新製品開発に資する「新素材」実現のための基礎的・基盤的研究 細孔内物質の相転移コントロールによる「漏れない液体」、2012年5月25日
• [Remarks]
  • URL: http://www.chem.kyushu-u.ac.jp/~kimizuka/
• [Remarks]
  • URL: http://www.chem.kyushu-u.ac.jp/~cms/