Reactivity and Electronic Structure of Trigonal Planar Carbido Complexes
| Project/Area Number |
22750058
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Osaka Prefecture University |
|---|
Principal Investigator |
TAKEMOTO Shin 大阪府立大学, 大学院・理学系研究科, 准教授 (20347511)
|
|---|
| Project Period (FY) |
2010 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
|---|
| Keywords | カーバイド錯体 / 多核錯体 / クラスター / メチレン錯体 / メチリジン錯体 / カーバイド / 三方平面構造 / 遷移金属錯体 / フィッシャー・トロプシュ / イミド錯体 / カルベン錯体 |
|---|
| Research Abstract |
The first transition metal complexes containing trigonal planar carbide ligand have been synthesized, and their reactivity has been studied. The carbide ligand showed a diverse array of reactivity leading to carbon-carbon bond formation on the multimetallic site. In addition, a carbene-like electronic structure of these carbide complexes has been established. These results contribute to understanding of carbon-carbon bond forming processes on heterogeneous transition metal catalyst surfaces and to future development of new carbene compounds containing transition metal fragments as substituents(the metallocarbenes).
|
Report
(3 results)
Research Products
(13 results)
