Synthesis and Coordination Chemistry of Stabilized Oxidation Forms of Porphyrin
| Project/Area Number |
22750060
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Toho University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 錯体化学 / 酸化還元反応 / 典型元素 / 遷移金属 |
|---|
| Research Abstract |
Phosphorus(V), antimony(V) and gold(III) complexes of.-octaisobutyl-meso-tetraphenylporphyrin were successfully synthesized. Novel analogues of dodecasubstituted porphyrin were prepared. We found that the tetrathienyl derivative was more distorted than the tetraphenyl derivatives. We then examined a 2-electron oxidation reaction of our novel derivatives. The UV-vis measurements indicated that the formation of the oxidized forms.
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Report
(3 results)
Research Products
(34 results)
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[Journal Article] Synthesis, Characterization and Spectroscopic Analysis of Antiaromatic Benzofused Metalloporphyrin Species2012
Author(s)
S. Sugawara, Y. Hirata, S. Kojima, Y, Yamamoto, E. Miyazaki, K. Takimiya, S. Matsukawa, D. Hashizume, J. Mack, N. Kobayashi, Z. Fu, K. M. Kadish, Y. M. Sung, K. S. Kim, D. Kim
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Journal Title
Chemistry-A European Journal
Volume: 18(12)
Issue: 12
Pages: 3566-3581
DOI
Related Report
Peer Reviewed
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[Journal Article] Synthesis, Reactions, and Electronic Properties of 16π-electron Octaisobutyl-tetraphenyl porphyrin(OiBTPP)2010
Author(s)
Y. Yamamoto, Y. Hirata, M. Kodama, T. Yamaguchi, S. Matsukawa, K.-y. Akiba, D. Hashizume, F. Iwasaki, A. Muranaka, M. Uchiyama, P. Chen, K. M. Kadish, N. Kobayashi,
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Journal Title
J. Am. Chem. Soc.
Volume: 132(36)
Issue: 36
Pages: 12627-12638
DOI
Related Report
Peer Reviewed
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