Synthesis and Coordination Chemistry of Stabilized Oxidation Forms of Porphyrin

• Project/Area Number: 22750060
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Inorganic chemistry
• Research Institution: Toho University
• Principal Investigator: MATSUKAWA Shiro 東邦大学, 理学部, 准教授 (90448259)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
• Keywords: 錯体化学 / 酸化還元反応 / 典型元素 / 遷移金属

Research Abstract

Phosphorus(V), antimony(V) and gold(III) complexes of.-octaisobutyl-meso-tetraphenylporphyrin were successfully synthesized. Novel analogues of dodecasubstituted porphyrin were prepared. We found that the tetrathienyl derivative was more distorted than the tetraphenyl derivatives. We then examined a 2-electron oxidation reaction of our novel derivatives. The UV-vis measurements indicated that the formation of the oxidized forms.

Research Products

• [Journal Article] Synthesis, Characterization and Spectroscopic Analysis of Antiaromatic Benzofused Metalloporphyrin Species (2012)
  • Author(s): S. Sugawara, Y. Hirata, S. Kojima, Y, Yamamoto, E. Miyazaki, K. Takimiya, S. Matsukawa, D. Hashizume, J. Mack, N. Kobayashi, Z. Fu, K. M. Kadish, Y. M. Sung, K. S. Kim, D. Kim
  • Journal Title: Chemistry-A European Journal Volume: 18(12) Issue: 12 Pages: 3566-3581
  • DOI: 10.1002/chem.201101846
  • Peer Reviewed
• [Journal Article] Structure and Dynamic Behavior of Neutral Hexacoordinate Antimony Compounds with Intramolecular Coordination (2011)
  • Author(s): H. Yamamichi, S. Matsukawa, S. Kojima, K. Ando, Y. Yamamoto
  • Journal Title: Heteroatom Chemistry Volume: 22(3/ 4) Issue: 3-4 Pages: 553-561
  • DOI: 10.1002/hc.20721
  • Peer Reviewed
• [Journal Article] Crystallographic and NMR Studies on Species Intermediate Between Haloalkoxyphosphoranes and Alkoxyphosphonium Halides (2011)
  • Author(s): Y. Yamamoto, K. Nakao, T. Hashimoto, S. Matsukawa, N. Suzukawa, S. Kojima, K-y. Akiba
  • Journal Title: Heteroatom Chemistry Volume: 22(3/ 4) Issue: 3-4 Pages: 523-530
  • DOI: 10.1002/hc.20717
  • Peer Reviewed
• [Journal Article] Stereomutation of a Diastereomeric Pair of 10-P-5 Hydroxyphosphoranes (2011)
  • Author(s): Satoshi Kojima, Masaaki Nakamoto, Shiro Matsukawa, Kin-ya Akiba
  • Journal Title: Heteroatom Chem Volume: 22(3/4) Issue: 3-4 Pages: 491-499
  • DOI: 10.1002/hc.20712
  • Peer Reviewed
• [Journal Article] Efficient synthesis of tetradecafluoro-4-phenylheptan-4-ol by a Cannizzaro-type reaction and application of the alcohol as a bulky Martin ligand variant for a new anti-apicophilic Phosphorane (2010)
  • Author(s): X.-D. Jiang, S. Matsukawa, K. Kakuda, Y. Fukuzaki, W.-L. Zhao, L.-S. Li, H.-B. Shen, S. Kojimaand Y. Yamamoto
  • Journal Title: Dalton Transactions Volume: 39(41) Issue: 41 Pages: 9823-9829
  • DOI: 10.1039/c0dt00539h
  • Peer Reviewed
• [Journal Article] Synthesis, Reactions, and Electronic Properties of 16π-electron Octaisobutyl-tetraphenyl porphyrin(OiBTPP) (2010)
  • Author(s): Y. Yamamoto, Y. Hirata, M. Kodama, T. Yamaguchi, S. Matsukawa, K.-y. Akiba, D. Hashizume, F. Iwasaki, A. Muranaka, M. Uchiyama, P. Chen, K. M. Kadish, N. Kobayashi,
  • Journal Title: J. Am. Chem. Soc. Volume: 132(36) Issue: 36 Pages: 12627-12638
  • DOI: 10.1021/ja102817a
  • Peer Reviewed
• [Journal Article] Formation of Epoxides from Pentacoordinated Organoarsenic Compounds with aβ-Hydroxyethyl Group (2010)
  • Author(s): X.-D. Jiang, S. Matsukawa, Y. Fukuzaki, Y. Yamamoto
  • Journal Title: NewJournal of Chemistry Volume: 34 Issue: 8 Pages: 1623-1629
  • DOI: 10.1039/c0nj00035c
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Monohaloalkoxyarsoranes Bearing a Novel Tridentate Ligand Occupying One Apical and Two Equatorial Sites (2010)
  • Author(s): H. Yamamichi, S. Matsukawa, and Y. Yamamoto
  • Journal Title: Phosphorus, Sulfur, and Silicon and the Related Elements Volume: 185 Issue: 5-6 Pages: 974-982
  • DOI: 10.1080/10426501003772003
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Monohaloalkoxyarsoranes Bearing a Novel Tridentate Ligand Occupying One Apical and Two Equatorial Sites (2010)
  • Author(s): Hideaki Yamamichi
  • Journal Title: Phosphorus, Sulfur and Silicon, and the Related Elements Volume: 185 Pages: 974-982
  • Peer Reviewed
• [Journal Article] Formation of Epoxides from Pentacoordinated Organoarsenic Compounds with a β-Hydroxyethyl Group (2010)
  • Author(s): Xin-Dong Jiang
  • Journal Title: New J.Chem. Volume: 34 Pages: 1623-1629
  • Peer Reviewed
• [Journal Article] Synthesis, Reactions, and Electronic Properties of 16 π-electron Octaisobutyltetraphenylporphyrin (OiBTPP) (2010)
  • Author(s): Yohsuke Yamamoto
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 12627-12638
  • Peer Reviewed
• [Journal Article] Efficient synthesis of tetradecafluoro-4-phenylheptan-4-ol by a Cannizzaro-type reaction and application of the alcohol as a bulky Martin lig and variant for a new anti-apicophilic phosphorane (2010)
  • Author(s): Xin-Dong Jiang
  • Journal Title: Dalton Trans. Volume: 39 Pages: 9823-9829
  • Peer Reviewed
• [Presentation] アピカル-エクアトリアル-エクアトリアル型新規三座配位子の合成の検討 (2012)
  • Author(s): 鈴木かおり・松川史郎・高橋正
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜(慶応義塾大学)
  • Year and Date: 2012-03-27
• [Presentation] β-オクタイソブチル-meso-テトラフェニルポルフィリン-リン(V)錯体の合成 (2012)
  • Author(s): 戸井永允・松川史郎・高橋正
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜(慶応義塾大学)
  • Year and Date: 2012-03-27
• [Presentation] β位にアルコキシ基を持つドデカ置換ポルフィリンの2電子酸化体(16π)の合成の検討 (2012)
  • Author(s): 川戸邦宏・松川史郎・高橋正
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜(慶応義塾大学)
  • Year and Date: 2012-03-27
• [Presentation] meso位にチエニル基を導入した新規ドデカ置換ポルフィリンの合成と16π酸化体の合成検討 (2012)
  • Author(s): 福井新・松川史郎・高橋正
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜(慶応義塾大学)
  • Year and Date: 2012-03-27
• [Presentation] meso位にチエニル基を導入した新規ドデカ置換ポルフィリンの合成と16π酸化体の合成検討 (2012)
  • Author(s): 福井新
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学(横浜)
  • Year and Date: 2012-03-27
• [Presentation] β位にアルコキシ基を持つドデカ置換ポルフィリンの2電子酸化体(16π)の合成の検討 (2012)
  • Author(s): 川戸邦宏
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学(横浜)
  • Year and Date: 2012-03-27
• [Presentation] β-オクタイソブチル-meso-テトラフェニルポルフィリン-リン(V)錯体の合成 (2012)
  • Author(s): 戸井永允
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学(横浜)
  • Year and Date: 2012-03-27
• [Presentation] アピカル-エクアトリアル-エクアトリアル型新規三座配位子の合成の検討 (2012)
  • Author(s): 鈴木かおり
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学(横浜)
  • Year and Date: 2012-03-27
• [Presentation] 強固な三座配位子と二座配位子を有する超原子価5配位アンチモン化合物のTurnstile Rotationによる異性化機構の研究 (2011)
  • Author(s): 今田康公
  • Organizer: 第38回有機典型元素化学討論会
  • Place of Presentation: 金沢大学(金沢)
  • Year and Date: 2011-12-08
• [Presentation] 超原子価5配位アンチモン化合物のTurnstile Rotationによる異性化機構の研究 (2011)
  • Author(s): 今田康公
  • Organizer: 第27回若手研究者のための化学道場
  • Place of Presentation: 高知大学(高知)
  • Year and Date: 2011-09-09
• [Presentation] アンチモン(V)テトラアリールポルフィリン錯体の_<121>Sbメスバウアー分光法による電子状態の研究 (2011)
  • Author(s): 戸井永允
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: (講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] ベンゾ縮環した骨格を有する16πポルフィリン亜鉛錯体の構造及び反芳香族性評価 (2011)
  • Author(s): 菅原峻
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: (講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] 超原子価5配位アンチモン化合物のTurnstile Rotationによる異性化機構の研究 (2011)
  • Author(s): 今田康公
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: (講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] アピコフィリシティーに反した5配位超原子価アンチモン化合物の合成の検討 (2011)
  • Author(s): 武内俊洋
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: (講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] Attempts at synthesis of anti-apicophilic stiboranes using the rigid tridentate ligand (2010)
  • Author(s): Shiro Matsukawa, Toshihiro Takeuchi, Hirokazu Nishikawa, Hideaki, Yamamichi, Masashi Takahashi, Yohsuke Yamamoto
  • Organizer: International Chemical Congress of Pacific Basin Societies(Pacifichem 2010)
  • Place of Presentation: Honolulu(Conventional Center), USA
  • Year and Date: 2010-12-16
• [Presentation] ^<121> Sb Mossbauer spectra of antimony(V)-porphyrin complexes (2010)
  • Author(s): Makoto Toinaga, Shiro Matsukawa, Masashi Takahashi
  • Organizer: International Chemical Congress of Pacific Basin Societies(Pacifichem 2010)
  • Place of Presentation: Honolulu(Conventional Center), USA
  • Year and Date: 2010-12-16
• [Presentation] ^<121>Sb Mossbauer spectra of antimony(V)-porphyrin complexes (2010)
  • Author(s): Makoto Toinaga
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
  • Place of Presentation: コンベンションセンター(ホノルル)
  • Year and Date: 2010-12-16
• [Presentation] Attempts at synthesis of anti-apicophilic stiboranes using the rigid tridentate ligand (2010)
  • Author(s): Shiro Matsukawa
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
  • Place of Presentation: コンベンションセンター(ホノルル)
  • Year and Date: 2010-12-16
• [Presentation] Structures and Properties of 16πMetalloporphyrins (2010)
  • Author(s): Shun Sugawara, Yuusuke Hirata, Shiro Matsukawa, Daisuke Hashizume, Satoshi Kojima, Yohsuke Yamamoto
  • Organizer: The 7th Nano Bio Info Chemistry Symposium Higashi-Hiroshima(Hiroshima Univ.)
  • Place of Presentation: Japan
  • Year and Date: 2010-12-04
• [Presentation] Structures and Properties of 16π Metalloporphyrins (2010)
  • Author(s): Shun Sugawara
  • Organizer: The 7th Nano Bio Info Chemistry Symposium
  • Place of Presentation: 広島大学(広島県)
  • Year and Date: 2010-12-04
• [Presentation] 新規三座配位子と二座配位子を有する超原子価5配位アンチモン化合物の合成 (2010)
  • Author(s): 今田康公
  • Organizer: 第26回若手研究者のための化学道場
  • Place of Presentation: 鳥取大学(鳥取県)
  • Year and Date: 2010-09-06
• [Presentation] 新規スフェランドの合成と超原子価5配位スズアート錯体の安定化 (2010)
  • Author(s): 鈴川直幸
  • Organizer: 20周年記念万有福岡シンポジウム
  • Place of Presentation: 九州大学(福岡県)
  • Year and Date: 2010-05-22