| Project/Area Number |
22750083
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
ITO Shingo 東京大学, 大学院・工学系研究科, 助教 (90508194)
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 錯体 / 有機金属触媒 / 複核金属錯体 / 遷移金属 / 触媒作用 / ロジウム / ヒドロホルミル化反応 / 重合反応 |
|---|
| Research Abstract |
This project aimed at the synthesis of multimetallic complexes having a proximal Lewis acidic moiety and the development of novel multimetallic catalysis, which has not been achieved by other single metal catalysis. In this project, we successfully synthesized early/late bimetallic complexes bearing a novel[ PONNO] ligand or[ PONNOP] ligand, and applied to catalytic transformations. In some reactions, synergetic effects of multiple metals were observed to enhance the catalytic activity and product selectivity.
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