| Project/Area Number |
22750086
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | University of Toyama |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 触媒反応 / 金属カルベノイド / メタラシクロブテン / 金 / パラジウム / 金触媒 / パラジウム触媒 / シクロプロパン化反応 / 二量化反応 / カチオン性金触媒 / カルベノイド / C-H結合挿入 / アルキン / 炭素-炭素結合反応 / ビニリデン |
|---|
| Research Abstract |
Simple and efficient methods of generation for gold alkylidene complexes or other transition metal alkylidene complexes have been developed, and applied them to new molecular transformations. Interestingly, depending on the reaction conditions, formation ofα-silyl orα-boryl-σ-allylpalladium acetate complexes generated from 3-trimethylsilyl or 3-pinacolatoboryl-1-allylacetate and palladium complex was found to produce palladacyclobutene intermediate and palladium carbenoid intermediate, respectively. While the palladacyclobutene intermediate reacts with strained olefins to give cyclopropanation products, the palladium carbenoid intermediate undergoes dimerization.
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