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Surfaceand interfacial propertiesofpoIymer thinfilmas studied by neutron scattering

Research Project

Project/Area Number 22750110
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

INOUE Rintaro  京都大学, 化学研究所, 助教 (80563840)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords高分子薄膜 / 表面 / ガラス転移温度 / 中性子反射率 / ガラス転移 / 中性子散乱
Research Abstract

It is quite well known that physical properties of polymer are different from those of bulk state. In order to understand the singular physical properties of polymer thin films, we have studied the physical properties of polymer thin films both surface region and interfacial region by neutron reflectivity. As a result we found that the mobility near the surface region increased compared to that of bulk, on the other hand we also found that the mobility near the interfacial region drastically decreased compared to that of bulk. That is to say, the resulting physical properties of polymer thin film are determined by the counterbalance between surface effect and interfacial effect.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (14 results)

All 2011 2010 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (6 results) Remarks (2 results)

  • [Journal Article] Interfacial properties of polystyrene thin films as revealed by neutron reflectivity2011

    • Author(s)
      R. Inoue, K. Kawashima, K. Matsui, M. Nakamura, K. Ni shr da, T. Kanaya and N. L. Yamada
    • Journal Title

      Phys. Rev. E

      Volume: 84 Issue: 3

    • DOI

      10.1103/physreve.84.031802

    • NAID

      120003437136

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Distributions of glass-ransition temperature and thermal expansivity in multilayered polystyrene thin film studied by neutron reflectivity2011

    • Author(s)
      R. Inoue, K. Kawashima, K. Matsui, T. Kanaya, K. Nishida, G. Matsuba and M. Hino
    • Journal Title

      Phys. Rev. E

      Volume: 83 Issue: 2 Pages: 0218011021801-7

    • DOI

      10.1103/physreve.83.021801

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Distributions of glass transition temperature and thermal expansivity in multi-layered polystyrene thin film studied by neutron reflectivity2011

    • Author(s)
      Rintaro Inoue
    • Journal Title

      Phys.Rev.E

      Volume: 83

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Neutron scattering studies on soft materials2010

    • Author(s)
      R. Inoue and T. Kanaya
    • Journal Title

      J. Vac. Soc. Jpn

      Pages: 732-738

    • NAID

      10027705335

    • URL

      https://www.jstage.go.jp/browse/jvsj2/53/12/contents/-char/ja/

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Scattering Studies on Soft Materials2010

    • Author(s)
      Rintaro Inoue
    • Journal Title

      J.Vac.Soc.Jpn

      Volume: 53 Pages: 732-738

    • NAID

      10027705335

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Large Domain Fluctuations on 50-ns Timescale Enable Catalytic Activity in Phosphoglycerate Kinase2010

    • Author(s)
      Rintaro Inoue
    • Journal Title

      Biophysical Journal

      Volume: 99 Pages: 2309-2317

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Glass transition temperature of polymer thin film as studied by neutron reflectivity2011

    • Author(s)
      Rintaro Inoue, Toshiji Kanaya, Koji Norifumi L. Yamada, Masahiro Hino
    • Organizer
      1st Asia-Oceania Conference on Neutron Scattering
    • Place of Presentation
      Tsukuba
    • Year and Date
      2011-11-23
    • Related Report
      2011 Final Research Report
  • [Presentation] Distribution of glass transition temperature as studied by neutron reflectivity2011

    • Author(s)
      Rintaro Inoue Toshiji Kanaya, Koji Nishida
    • Organizer
      Asian Textile Conference 11
    • Place of Presentation
      Deagu, Korea
    • Year and Date
      2011-11-03
    • Related Report
      2011 Final Research Report
  • [Presentation] Distribution or glass transition temperature in polystyrene thin films as studied by neutron reflectivity2011

    • Author(s)
      Rintaro Inoue
    • Organizer
      ATC-11
    • Place of Presentation
      Daegu, Korea
    • Year and Date
      2011-11-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] Glasstransitiontem Peratu「einpolymerthin film2010

    • Author(s)
      Rintaro lnoue Toshiji Kanaya, Koji Nishida
    • Organizer
      International Symposiumon Non-Equilibrium Soft Matter 2010
    • Place of Presentation
      Nara
    • Year and Date
      2010-08-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Glasstransitiontem Peratu「einpolymerthinfilm2010

    • Author(s)
      Rintaro Inoue Toshiji Kanaya, Koji Nishida
    • Organizer
      5^<th> Pacific Rim Conference on Rheology
    • Place of Presentation
      Hokkaido
    • Year and Date
      2010-08-03
    • Related Report
      2011 Final Research Report
  • [Presentation] Distribution of Glass Transition Temperature in Polymer Thin Film2010

    • Author(s)
      Rintaro Inoue
    • Organizer
      5th Pacific Rim Conference on Rheology
    • Place of Presentation
      Hokkaido
    • Year and Date
      2010-08-03
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://rob.kuier.kyoto-co.ac.jp/researchers/view/inoue+rintaro

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://rdb.kuicr.kyoto-u.ac.jp/researchers/view/inoue+rintaro

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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