| Project/Area Number |
22750118
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 超分子 / ポルフィリン / π共役系 / 遷移金属錯体 / ルイス酸 / 光電子機能 |
|---|
| Research Abstract |
To synthesize novel non-planar porphyrin derivatives, we have conducted ring-fused reactions with peripheral substituents of porphyrin derivatives. As results, we have obtained four kinds of novel ring-fused porphyrin derivatives. The ring-fused porphyrins possessed smaller HOMO-LUMO gaps due to the extended a-conjugation of the porphyrins, and consequently, red-shifted absorption bands were observed in the UV-vis spectra and negatively shifted oxidation potentials and positively shifted reduction potentials were obtained in the electrochemical measurements
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