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Preparation of circularly polarized photoluminescent material using nonclassical method

Research Project

Project/Area Number 22750133
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionKinki University

Principal Investigator

IMAI Yoshitane  近畿大学, 理工学部, 講師 (80388496)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords円偏光発光(CPL) / 超分子 / 蛍光 / 円偏光発光 / CPL / 円偏光二色性 / 光学活性 / キラル / 有機発光体
Research Abstract

Many solid-state organic fluorophores composed of a single organic molecule have been reported. However, most of the previously reported organic fluorophores do not have chirality, and therefore, they do not show solid-state circularly polarized luminescence(CPL). In this study, chiral two-component supramolecular organic fluorophore was successfully prepared by using achiral fluorescent carboxylic acid molecule and chiral amine molecule. Intersetingly, it was found that the solid-state chiral optical properties of acid/amine supramolecular organic fluorophore can be controlled by changing the type of the achiral acid component molecule(that is, by changing the packing structure of the fluorescent unit) instead of changing the chirality of the chiral amine component molecule. Supramolecular organic fluorophores offering these functionalities are expected to be useful in the development of novel solid-state chiral supramolecular fluorophores.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2011 2010

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (9 results)

  • [Journal Article] Solid-state chiral optical properties of axially chiral binaphthyl acid derivatives2011

    • Author(s)
      Kinuta, T.; Sato, T.; Nakano, Y.; Harada, T.; Tajima, N.; Fujiki, M.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry

      Pages: 134-138

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control of solid-state chiral optical properties of a supramolecular organic fluorophore containing of 4-(2-arylethynyl)-ben-zoic acid2011

    • Author(s)
      Nishiguchi, N.; Kinuta, T.; Nakano, Y.; Harada, T.; Tajima, N.; Sato, T.; Fujiki, M.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      Chem. Asian J

      Volume: 6 Pages: 1092-1098

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solid-state fluorescence host complex formed by assembly of two-dimensional layered network structure composed of 2, 6-naphthalene-dicarboxylic acid and 2-naphthylethylamine2011

    • Author(s)
      Shiota N.; Okuno T.; Kinuta T.; Sato T.; Kuroda R.; Matsubara Y.; Imai Y
    • Journal Title

      CrystEngComm

      Volume: 13 Pages: 1683-1686

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structures and Solid-state Optical Properties of Supramolecular Organic Fluorophore Composed of 1D Columnar Network Structure Consisting of Fluorescent 2-Naphthalenecarboxylic Acid2011

    • Author(s)
      Nishiguchi, N.; Sato, T; Kinuta, T.; Kuroda, R.; Matsubara, Y.; Imai, Y.
    • Journal Title

      Cryst.Growth Des.

      Volume: 11 Issue: 3 Pages: 827-831

    • DOI

      10.1021/cg101480x

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Solid-state Chiral Optical Properties of a Supramolecular Organic Fluorophore Containing of 4-(2-arylethynyl)-benzoic acid2011

    • Author(s)
      Nishiguchi, N.; Kinuta, T.; Nakano, Y.; Harada, T.; Tajima, N.; Sato, T.; Fujiki, M.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      Chem.Asian J.

      Volume: 6 Issue: 4 Pages: 1092-1098

    • DOI

      10.1002/asia.201000780

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid-state Fluorescence Host Complex formed by Assembly of Two-dimensional Layered Network Structure composed of 2,6-Naphthalenedicarboxylic acid and 2-Naphthylethylamine2011

    • Author(s)
      Shiota, N.; Okuno T.; Kinuta T.; Sato T.; Kuroda R.; Matsubara Y.; Imai Y
    • Journal Title

      CrystEngComm.

      Volume: 13 Issue: 5 Pages: 1683-1686

    • DOI

      10.1039/c0ce00446d

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral crystallization of ether-and imide-bridged biphenyl compounds without any outside chiral source2010

    • Author(s)
      Kinuta T.; Sato, T.; Tajima, N.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      CrystEngComm

      Volume: 12 Pages: 3483-3486

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Colored supramolecular charge-transfer host system using 10, 10′-dihydroxy-9, 9′-biphenanthr-yl and 2, 5-disubstituted-1, 4-benzoquinone2010

    • Author(s)
      Ukegawa T.; Kinuta, T.; Sato, T.; Tajima, N.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 8756-8762

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solid-state thermochromism observed in charge-transfer complex composed of binaphthol and viologen2010

    • Author(s)
      Kinuta, T.; Sato, T.; Tajima, N.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      J. Mol. Struc

      Volume: 982 Pages: 45-49

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control of relationship between conformational and color polymorphs of achiral 2-methyl-3-arylthio-1, 4-naphthalenediones2010

    • Author(s)
      Kinuta, T.; Sato, T.; Harada, T.; Tajima, N.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      J. Mol. Struc

      Volume: 982 Pages: 16-21

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular recognition of bisphenol A and its derivatives using p-benzoquinone molecule2010

    • Author(s)
      Iwase, N.; Kinuta, T.; Tajima, N.; Sato, T.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      CrystEngComm

      Volume: 12 Pages: 3195-3200

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tuning mechanism in helical columnar thiophene host system with 2-thienylacetic acid by using(1R, 2S)-2-amino-1, 2-diphenylethanol2010

    • Author(s)
      Shiota, N.; Kinuta, T.; Sato, T.; Kuroda, R.; Matsubara, Y.; Imai, Y
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 5589-5593

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solid-state thermochromism observed in charge-transfer complex composed of binaphthol and viologen2010

    • Author(s)
      Kinuta, T.; Sato, T.; Tajima, N.; Kuroda, R.; Matsubara, Y.; Imai, Y.
    • Journal Title

      J.Mol.Struc.

      Volume: 982 Pages: 45-49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning mechanism in helical columnar thiophene host system with 2-thienylacetic acid by using (1R,2S)-2-amino-1,2-diphenylethanol2010

    • Author(s)
      Shiota, N.; Kinuta, T.; Sato, T.; Kuroda, R.; Matsubara, Y.; Imai, Y.
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 5589-5593

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral crystallization of ether- and imide-bridged biphenyl compounds without any outside chiral source2010

    • Author(s)
      Kinuta, T.; Sato, T.; Tajima, N.; Kuroda, R.; Matsubara, Y.; Imai, Y.
    • Journal Title

      CrystEngComm.

      Volume: 12 Pages: 3483-3486

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 軸不斉化合物及びアミン誘導体との超分子錯体における円偏光発光(CPL)特性2011

    • Author(s)
      絹田貴史、汐田直貴、佐藤友宏、徳留隼人、黒田玲子、藤木道也、松原凱男、宮澤三雄、今井喜胤
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎(宮崎市河畔コンベンションセンター)
    • Year and Date
      2011-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] フェニルスルホン酸誘導体とキラルなアミン誘導体を用いた光学活性超分子有機発光体の創製2011

    • Author(s)
      奥野峻大・汐田直貴・絹田貴史・佐藤友宏・中野陽子・徳留隼人・藤木道也・黒田玲子・松原凱男・今井喜胤
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎(宮崎市河畔コンベンションセンター)
    • Year and Date
      2011-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 2-ナフトエ酸と各種アミン分子を用いた光学活性超分子有機発光体の光学特性2011

    • Author(s)
      西口範昭・小林雄平・絹田貴史・佐藤友宏・徳留隼人・中野陽子・藤木道也・黒田玲子・今井喜胤
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎市コンベンションセンター(宮崎県)
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] ナフトキノン骨格を有するチオエーテル化合物のポリモルフィズム特性2010

    • Author(s)
      絹田貴史・原田拓典・田島暢夫・佐藤友宏・黒田玲子・松原凱男・今井喜胤
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋(名古屋大学・東山キャンパス)
    • Year and Date
      2010-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] チオフェンカルボン酸-アミン系超分子ホスト発光体の創製2010

    • Author(s)
      汐田直貴・木本貴也・絹田貴史・佐藤友宏・黒田玲子・松原凱男・今井喜胤
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋(名古屋大学・東山キャスパス)
    • Year and Date
      2010-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] π-共役拡張型超分子有機発光体のキラル光学特性制御2010

    • Author(s)
      西口範昭・絹田貴史・原田拓典・中野陽子・田島暢夫・佐藤友宏・藤木道也・黒田玲子・松原凱男・今井喜胤
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋(名古屋大学・東山キャンパス)
    • Year and Date
      2010-09-10
    • Related Report
      2011 Final Research Report
  • [Presentation] π共役拡張型超分子有機発光体のキラル光学特性制御2010

    • Author(s)
      西口範昭・絹田貴史・原田拓典・中野陽子・田島暢夫・佐藤友宏・藤木道也・黒田玲子・松原凱男・今井喜胤
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] 架橋ビフェニルおよびビナフチル誘導体の結晶構造とキラルな光学特性2010

    • Author(s)
      絹田貴史・中野陽子・原田拓典・佐藤友宏・藤木道也・黒田玲子・松原凱男・今井喜胤
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋(名古屋大学・東山キャンパス)
    • Year and Date
      2010-09-09
    • Related Report
      2011 Final Research Report
  • [Presentation] π共役拡張型ビナフトール誘導体-メチルベンゾキノン系CTホスト錯体の創製2010

    • Author(s)
      受川達也・絹田貴史・田嶋暢夫・佐藤友宏・黒田玲子・松原凱男・今井喜胤
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋(名古屋大学)
    • Year and Date
      2010-09-09
    • Related Report
      2011 Final Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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