| Project/Area Number |
22750139
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Environmental chemistry
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| Research Institution | Kyushu Institute of Technology |
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Principal Investigator |
MURAKAMI Naoya 九州工業大学, 大学院・工学研究院, 助教 (10452822)
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| Project Period (FY) |
2010 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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| Keywords | ナノ材料 / 環境材料 / 触媒・化学プロセス / 表面・界面物性 |
|---|
| Research Abstract |
{111} exposed crystal faces of shape-controlled rutile titanium(IV) oxide(TiO_2) were site-selectively modified with trivalent iron(III)(Fe^<3+>) ions by utilizing adsorption property of iron(III)/ iron(II)(Fe^<3+>/ Fe^<2+>) ions. The rutile TiO_2 with site-selective modification of Fe^<3+> ions showed high photocatalytic activity under visible-light irradiation as a result of separation of redox sites, i. e., oxidation and reduction proceed over Fe^<3+> ions on{ 111} faces and the bare TiO_2 surface on{ 110} faces, respectively.
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