Development of Polymer-Supported Copper Catalysts for Aqueous Molecular Transformation

• Project/Area Number: 22750141
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Environmental chemistry
• Research Institution: Institute for Molecular Science
• Principal Investigator: OSAKO Takao 分子科学研究所, 生命・錯体分子科学領域, 助教 (90500984)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000); Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
• Keywords: 高機能触媒 / 銅担持触媒 / 水中分子変換 / 両親媒性ポリマー / イミダゾインドールフォスフィン / 不斉分子変換 / O-H挿入反応 / トリアザシクロノナン / アミン酸

Research Abstract

Development of heterogeneous copper complex catalysts immobilized on an amphiphilic polystyrene-polyethylene resin and their application to a series of organic transformation(aqueous and asymmetric reactions) were investigated to establish new molecular transformations which realize environmentally benign and sustainable processes in next generation.

Research Products

• [Journal Article] Enantioselective Carbenoid Insertion into Phenolic O. H Bonds with a Chiral Copper(I) Imidazoindolephosphine Complex (2012)
  • Author(s): Takao OsakoTakao Osako, Duanghathai Panichakul, Yasuhiro Uozumi
  • Journal Title: Organic Letters Volume: 14 Pages: 194-197
  • Peer Reviewed
• [Journal Article] Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding any transition metal catalysts (2012)
  • Author(s): Kiyofumi Inamoto, Chisa Hasegawa, Kou Hiroya, Yoshinori Kondo, Takao Osako, Yasuhiro Uozumi, Takayuki Doi
  • Journal Title: Chem. Commun Volume: 48 Pages: 2912-1914
  • Peer Reviewed
• [Journal Article] Enantioselective Carbenoid Insertion into Phenolic O-H Bonds with a Chiral Copper (I) Imidazoindolephosphine Complex (2012)
  • Author(s): Takao Osako, Duanghathai Panichakul, Yasuhiro Uozumi
  • Journal Title: Organic Letters Volume: 14 Pages: 194-197
  • Peer Reviewed
• [Journal Article] Use of Dimethyl Carbonate as a Solvent Greatly Enhances the Biaryl Coupling of Aryl Iodides and Organoboron Reagents without Adding Any Transition Metal Catalysts (2012)
  • Author(s): K.Inamoto, C.Hasegawa, K.Hiroya, Y.Kondo, T.Osako, Y.Uozumi, T.Doi
  • Journal Title: Chemical Communications Volume: 48 Issue: 23 Pages: 2912-2914
  • DOI: 10.1039/c2cc17401d
  • Peer Reviewed
• [Journal Article] A Self-Supported Palladium-Bipyridyl Catalyst For the Suzuki-Miyaura Coupling in Water (2010)
  • Author(s): Takao Osako, Yasuhiro Uozumi
  • Journal Title: Heterocycles Volume: 80 Pages: 505-514
  • NAID: 40016900123
  • Peer Reviewed
• [Presentation] キラル銅錯体によるフェノール類O. H結合へのエナンチオ選択的カルベノイド挿入反応 (2012)
  • Author(s): 大迫隆男・PANICHAKUL, Duanghathai・魚住泰広
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学日吉キャンパス(神奈川県)
  • Year and Date: 2012-03-27
• [Presentation] キラル銅錯体によるフェノール類O-H結合へのエナンチオ選択的カルベノイド挿入反応 (2012)
  • Author(s): 大迫隆男・PANICHAKUL, Duanghathai・魚住泰広
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学日吉キャンパス(神奈川県)
  • Year and Date: 2012-03-27
• [Presentation] プラチナナノ触媒を用いたアルコール類の水中酸素酸化反応:フローリアクターへの展開反応集積化の合成化学革新的手法の開拓と有機物質創製への展開 (2011)
  • Author(s): 大迫隆男
  • Organizer: 第4回若手シンポジウム
  • Place of Presentation: 三重大学(三重県)
  • Year and Date: 2011-06-11
• [Presentation] プラチナナノ触媒を用いたアルコール類の水中酸素酸化反応:フローリアクターへの展開 (2011)
  • Author(s): 大迫隆男
  • Organizer: 反応集積化の合成化学革新的手法の開拓と有機物質創製への展開第4回若手シンポジウム
  • Place of Presentation: 三重大学(三重県)
  • Year and Date: 2011-06-11
• [Presentation] Aerobic Alcohol Oxidation and Suzuki-Miyaura Coupling in Water with Self-Supported Bipyridyl-Palladium Catalysts (2010)
  • Author(s): Takao Osako, Yasuhiro Uozumi
  • Organizer: Pacifichem 2010
  • Place of Presentation: ホノルル(米国)
  • Year and Date: 2010-12-17
• [Remarks]
  • URL: http://groups.ims.ac.jp/organization/uozumi_g/