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Development of Polymer-Supported Copper Catalysts for Aqueous Molecular Transformation

Research Project

Project/Area Number 22750141
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

OSAKO Takao  分子科学研究所, 生命・錯体分子科学領域, 助教 (90500984)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords高機能触媒 / 銅担持触媒 / 水中分子変換 / 両親媒性ポリマー / イミダゾインドールフォスフィン / 不斉分子変換 / O-H挿入反応 / トリアザシクロノナン / アミン酸
Research Abstract

Development of heterogeneous copper complex catalysts immobilized on an amphiphilic polystyrene-polyethylene resin and their application to a series of organic transformation(aqueous and asymmetric reactions) were investigated to establish new molecular transformations which realize environmentally benign and sustainable processes in next generation.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (11 results)

All 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Enantioselective Carbenoid Insertion into Phenolic O. H Bonds with a Chiral Copper(I) Imidazoindolephosphine Complex2012

    • Author(s)
      Takao OsakoTakao Osako, Duanghathai Panichakul, Yasuhiro Uozumi
    • Journal Title

      Organic Letters

      Volume: 14 Pages: 194-197

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding any transition metal catalysts2012

    • Author(s)
      Kiyofumi Inamoto, Chisa Hasegawa, Kou Hiroya, Yoshinori Kondo, Takao Osako, Yasuhiro Uozumi, Takayuki Doi
    • Journal Title

      Chem. Commun

      Volume: 48 Pages: 2912-1914

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Carbenoid Insertion into Phenolic O-H Bonds with a Chiral Copper (I) Imidazoindolephosphine Complex2012

    • Author(s)
      Takao Osako, Duanghathai Panichakul, Yasuhiro Uozumi
    • Journal Title

      Organic Letters

      Volume: 14 Pages: 194-197

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Use of Dimethyl Carbonate as a Solvent Greatly Enhances the Biaryl Coupling of Aryl Iodides and Organoboron Reagents without Adding Any Transition Metal Catalysts2012

    • Author(s)
      K.Inamoto, C.Hasegawa, K.Hiroya, Y.Kondo, T.Osako, Y.Uozumi, T.Doi
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 23 Pages: 2912-2914

    • DOI

      10.1039/c2cc17401d

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Self-Supported Palladium-Bipyridyl Catalyst For the Suzuki-Miyaura Coupling in Water2010

    • Author(s)
      Takao Osako, Yasuhiro Uozumi
    • Journal Title

      Heterocycles

      Volume: 80 Pages: 505-514

    • NAID

      40016900123

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] キラル銅錯体によるフェノール類O. H結合へのエナンチオ選択的カルベノイド挿入反応2012

    • Author(s)
      大迫隆男・PANICHAKUL, Duanghathai・魚住泰広
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] キラル銅錯体によるフェノール類O-H結合へのエナンチオ選択的カルベノイド挿入反応2012

    • Author(s)
      大迫隆男・PANICHAKUL, Duanghathai・魚住泰広
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] プラチナナノ触媒を用いたアルコール類の水中酸素酸化反応:フローリアクターへの展開反応集積化の合成化学革新的手法の開拓と有機物質創製への展開2011

    • Author(s)
      大迫隆男
    • Organizer
      第4回若手シンポジウム
    • Place of Presentation
      三重大学(三重県)
    • Year and Date
      2011-06-11
    • Related Report
      2011 Final Research Report
  • [Presentation] プラチナナノ触媒を用いたアルコール類の水中酸素酸化反応:フローリアクターへの展開2011

    • Author(s)
      大迫隆男
    • Organizer
      反応集積化の合成化学革新的手法の開拓と有機物質創製への展開第4回若手シンポジウム
    • Place of Presentation
      三重大学(三重県)
    • Year and Date
      2011-06-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] Aerobic Alcohol Oxidation and Suzuki-Miyaura Coupling in Water with Self-Supported Bipyridyl-Palladium Catalysts2010

    • Author(s)
      Takao Osako, Yasuhiro Uozumi
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-17
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Remarks]

    • URL

      http://groups.ims.ac.jp/organization/uozumi_g/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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