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Novel photoresponsive LC polymer microparticles with actuator function

Research Project

Project/Area Number 22750168
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionNagaoka University of Technology

Principal Investigator

YU Haifeng  長岡技術科学大学, 産学融合トップランナー養成センター, 特任講師 (70509744)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsミクロアクチュエーター / 液晶高分子 / 光機能 / 微粒子 / 光応答
Research Abstract

Liquid-crystalline polymer microparticles were fabricated with a self-organized precipitation method, in which microparticles with narrow size distributions were fabricated in mixed solutions of a volatile good solvent and a nonvolatile poor one after evaporation of the good solvent. In such a narrow space of microparticles, their optical properties(such as refractive index, birefringence, et al.) were modulated by the photoinduced change in alignment of liquid crystals. These can be used as photo actuators. Then hybrid liquid crystalline materials were fabricated using optically transparent polymers(PMMA, PVA, et al.) by dispersing the Liquid-crystalline polymer microparticles inside them. The obtained hybrid materials showed good photoresponsive performance. Upon irradiation with UV light, the hybrid films after treatment of stretching bent towards the irradiation direction, directly transferring the light energy into mechanical energy. The present method can be used to fabricate stable hybrid materials with photoresponsive properties. The structure of the obtained materials can be easily modified by molecular design.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (13 results)

All 2011 2010

All Journal Article (9 results) (of which Peer Reviewed: 4 results) Presentation (4 results)

  • [Journal Article] Photomechanical behaviors of Hybrid Films of Liquid-Crystalline Polymer Microparticles2011

    • Author(s)
      Yu, H. F.; Dong, C., Zhou, W.; Kobayasi, T.; Yang, H.
    • Journal Title

      Small

      Volume: 7 Pages: 3039-3045

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] Electrically Conductive Hybrid Nanofibers Constructed with Two Amphiphilic Salt Components2011

    • Author(s)
      Zhou W.; Kobayashi, T.; Zhu, H.; Yu, H. F.
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 12768-12770

    • Related Report
      2011 Final Research Report
  • [Journal Article] Easy Fabrication and Morphology Control of Supramolecular Liquid-Crystalline Polymer Microparticles2011

    • Author(s)
      Liu, H.; Kobayasi, T.; Yu, H. F.
    • Journal Title

      Macromol. Rapid Commun.

      Volume: 32 Pages: 378-383

    • Related Report
      2011 Final Research Report
  • [Journal Article] Fabrication and Photoresponse of Supramolecular Liquid-Crystalline Microparticles. ACS Appl. Mater2011

    • Author(s)
      Yu, H. F.; Liu, H.; Kobayashi, T.
    • Journal Title

      Interfaces

      Volume: 3 Pages: 1333-1340

    • Related Report
      2011 Final Research Report
  • [Journal Article] A Nematic Liquid-Crystalline Polymer : Synthesis, Photoresponse and Optical Patterns.2011

    • Author(s)
      Zhou, W.; Dong, C.; Kobayashi, T.; Yu, H. F.
    • Journal Title

      Conf. Ser.: Mater. Sci. Eng

      Volume: 21

    • Related Report
      2011 Final Research Report
  • [Journal Article] Electrically Conductive Hybrid Nanofibers Constructed with Two Amphiphilic Salt Components2011

    • Author(s)
      Zhou W.; Kobayashi, T.; Zhu, H.; Yu, H.F.
    • Journal Title

      Chem.Commun.

      Volume: 47 Pages: 12768-12770

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Easy Fabrication and Morphology Control of Supramolecular Liquid-Crystalline Polymer Microparticles2011

    • Author(s)
      Liu, H.; Kobayasi, T.; Yu, H.F.
    • Journal Title

      Macromol.Rapid Commun.

      Volume: 32 Pages: 378-383

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Photoresponse of Supramolecular Liquid-Crystalline Microparticles2011

    • Author(s)
      Yu, H.F.; Liu, H.; Kobayashi, T.
    • Journal Title

      ACS Appl.Mater.Interfaces

      Volume: 3 Pages: 1333-1340

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Nematic Liquid-Crystalline Polymer : Synthesis, Photoresponse and Optical Patterns2011

    • Author(s)
      Zhou, W.; Dong, C.; Kobayashi, T.; Yu, H.F.
    • Journal Title

      IOP Conf.Ser.: Mater.Sci.Eng.

      Volume: 21

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fabrication of Novel Organic Nanofibers Containing Sulfonic Acid-Based Anionic Surfactants2011

    • Author(s)
      Zhou, W.; Zhu, H.; Yu, H. F.; Kobayashi, T.
    • Organizer
      第60回高分子学会年次
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Fabrication of Novel Organic Nanofibers Containing Aniline Hydrochloride2011

    • Author(s)
      Zhou, W.; Zhu, H.; Yu, H. F.; Kobayashi, T.
    • Organizer
      第60回高分子学会年次
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Simple Fabrication of Novel Organic Nanofibers Constructed with Ionic andπ-π2011

    • Author(s)
      Zhou, W.; Zhu, H.; Yu, H. F.; Kobayashi, T.
    • Organizer
      Stacking Interactions. International Symposium on Global Multidisciplinary Engineering 2011(S-GME2011)
    • Place of Presentation
      長岡技術科学大学
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] ネマチック液晶高分子における光応答性液晶微粒子の作製と評価2010

    • Author(s)
      董沖、于海峰、小林高臣
    • Organizer
      第59回高分子学会北陸支部研究発表会
    • Place of Presentation
      富山大学工学部
    • Year and Date
      2010-11-21
    • Related Report
      2011 Final Research Report 2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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