Project/Area Number |
22750172
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Single-year Grants |
Research Field |
Functional materials/Devices
|
Research Institution | Hiroshima University |
Principal Investigator |
OSAKA Itaru 広島大学, 大学院・工学研究院, 助教 (80549791)
|
Project Period (FY) |
2010 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
Keywords | 高分子合成 / 高分子機能 / 物性 / 有機トランジスタ / 導電性高分子 / 高分子半導体 / 有機半導体 / キャリア移動度 / 高分子機能・物性 |
Research Abstract |
π-extended heteroarenes and(ii) donor-acceptor(D-A) structure in the polymer backbone. As the approach(i), naphthodithiophene(NDT)-based polymers are synthesized, and as the approach(ii), benzobisthiazole(BBTz), naphthobisthiadiazole(NTz), and quinacridone(QA)-based polymers are synthesized. All these polymers form highly crystalline structures in the thin film with narrowπ-stacking distances of 3. 5~ 3. 6 A, and they exhibit high charge carrier mobilities of 0. 3~ 0. 8 cm2/ Vs, which are very high for semiconducting polymers. These results prove that the proposed approaches are quite effective for the creation of high performance semiconducting polymers.
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