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A Novel Fullerene-Appended Initiator for Living Cationic Polymerization to Synthesize Fullerene-End-Capped Polymers and their Properties

Research Project

Project/Area Number 22750178
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic industrial materials
Research InstitutionKyoto Institute of Technology

Principal Investigator

MOTOYANAGI Jin  京都工芸繊維大学, 工芸科学研究科, 助教 (10505845)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords精密重合 / フラーレン / リビングカチオン / 特異構造高分子
Research Abstract

Since fullerene(C_<60>) has unique physical properties, biological activity and so on, fullerene polymer conjugates are expected to provide novel advanced materials in a variety of research fields. In this research, a fullerene-substituted polymerization initiator was newly designed, and fullerene-end-capped poly(vinyl ether) s having a definite structure were synthesized by living cationic polymerization of vinyl ethers. And functional group appended vinyl ethers were also polymerized by living cationic polymerization.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (16 results)

All 2012 2011 2010

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (12 results)

  • [Journal Article] A Novel[60] Fullerene-Appended Initiator for Living Cationic Polymerization and its Application to the Synthesis of[60] Fullerene-End-Capped Poly(vinyl ether) s2012

    • Author(s)
      Jin Motoyanagi, Ryo Miyabara, Masashi Suzuki, Sadao Miki, and Masahiko Minoda
    • Journal Title

      Polymer Chemistry

      Volume: 3 Pages: 329-331

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Novel [60]Fullerene-appended Initiator for Living Cationic Polymerization and its Application to the Synthesis of [60]Fullerene-end-capped Poly(vinyl ether)s2012

    • Author(s)
      Jin Motoyanagi
    • Journal Title

      Polymer Chemistry

      Volume: 3 Issue: 2 Pages: 329-331

    • DOI

      10.1039/c2py00522k

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living Cationic Polymerization of a Coumarin-Substituted Vinyl Ether and Reversible Photo induced Cross-linking of the Resulting Homopolymers and Amphiphilic Block Copolymers2011

    • Author(s)
      Jin Motoyanagi, Izumi Nishimura, and Masahiko Minoda
    • Journal Title

      Journal of Polymer Science Part A : Polymer Chemistry

      Volume: 49 Pages: 4701-4707

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Living Cationic Polymerization of a Coumarin-Substituted Vinyl Ether and Reversible Photoinduced Cross-linking of the Resulting Homopolymers and Amphiphilic Block Copolymers2011

    • Author(s)
      Jin Motoyanagi
    • Journal Title

      Journal of Polymer Science Part A : Polymer Chemistry

      Volume: 49 Issue: 21 Pages: 4701-4707

    • DOI

      10.1002/pola.24918

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 精密重合を用いた新規フラーレンポリマーコンジュゲートの創製2011

    • Author(s)
      本柳仁, 鈴木雅詞, 宮原亮, 箕田雅彦
    • Organizer
      第57回高分子研究発表会
    • Place of Presentation
      神戸
    • Year and Date
      2011-07-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 精密重合を用いた新規フラーレンポリマーコンジュゲートの創製2011

    • Author(s)
      本柳仁
    • Organizer
      第57回高分子研究発表会
    • Place of Presentation
      兵庫県民会館
    • Year and Date
      2011-07-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 配位結合を利用したブラシ形超分子ポリマーの創製2011

    • Author(s)
      小川裕之, 本柳仁, 箕田雅彦
    • Organizer
      第30回無機高分子研究討論会
    • Place of Presentation
      京都
    • Related Report
      2011 Final Research Report
  • [Presentation] 開始末端にフラーレンを有する両親媒性ポリビニルエーテルの精密合成と自己組織化挙動2011

    • Author(s)
      倉田彰弘, 鈴木雅詞, 本柳仁, 箕田雅彦
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Related Report
      2011 Final Research Report
  • [Presentation] 開始末端にフラーレンを有する両親媒性ポリビニルエーテルの精密合成と自己組織化挙動2011

    • Author(s)
      本柳仁
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 配位結合を利用したブラシ形超分子ポリマーの創製2011

    • Author(s)
      本柳仁
    • Organizer
      第30回無機高分子研究討論会
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of novel fullerene polymer conjugates by living polymerization2010

    • Author(s)
      Jin Motoyanagi, Ryo Miyabara, Masashi Suzuki, and Masahiko Minoda
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu
    • Related Report
      2011 Final Research Report
  • [Presentation] 光応答性官能基を有する両親媒性ブロックポリマーの精密合成と光誘起による構造形成2010

    • Author(s)
      西村いずみ, 本柳仁, 箕田雅彦
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Related Report
      2011 Final Research Report
  • [Presentation] 配位結合形成を利用したブラシ形超分子ポリマーの開発2010

    • Author(s)
      小川裕之, 本柳仁, 箕田雅彦
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Related Report
      2011 Final Research Report
  • [Presentation] 光応答性官能基を有する両親媒性ブロックポリマーの精密合成と光誘起による構造形成2010

    • Author(s)
      本柳仁
    • Organizer
      第59高分子討論会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 配位結合形成を利用したブラシ形超分子ポリマーの開発2010

    • Author(s)
      本柳仁
    • Organizer
      第59高分子討論会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of novel fullerene polymer conjugates by living polymerization2010

    • Author(s)
      本柳仁
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(アメリカ)
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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