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Synthesis of Aggregation Control of Novel Organic Dyes for Dye-sensitized Solar Cells

Research Project

Project/Area Number 22750180
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic industrial materials
Research InstitutionOsaka Prefecture University

Principal Investigator

MAEDA Takeshi  大阪府立大学, 大学院・工学研究科, 助教 (90507956)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsスクアリリウム / 色素増感太陽電池 / 近赤外 / メタルフリー有機色素 / π共役系 / トリフェニルアミン
Research Abstract

Synthsis and characterization of metal-free organic dyes consisting of squaraine chromophores were investigated in order to improve photovoltaic performance of dye-sensitized solar cells(DSSCs). A variety of near-infrared absorbing squaraine-based dyes with extendedπ-conjugated system and squaraine-based dyes with tripodal structures were successfully synthesized. DSSCs based on these dyes exhibited spectral response in the long-wavelength region. In addition, the 3D-tripodal structure was found to promote not only the adsorption on titania electrode but also the suppression of charge recombination in the cells.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (13 results)

All 2012 2011 2010 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (7 results) Remarks (2 results)

  • [Journal Article] Unsymmetrical squarylium dyes withπ-extended heterocyclic components and their application to organic dye-sensitized solar cells2011

    • Author(s)
      Takeshi Maeda, Shima Naoki, Tatsuya Tsukamoto, Shigeyuki Yagi, Hiroyuki Nakazumi
    • Journal Title

      Synth. Met

      Volume: 161 Pages: 2481-2487

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Absorbing Squarylium Dyes with Linearly Extendedπ-Conjugated Structure for Dye-sensitized Solar Cell Application2011

    • Author(s)
      Takeshi Maeda, Yuuto Hamamura, Kyohei Miyanaga, Shigeyuki Yagi, Hiroyuki Nakazumi
    • Journal Title

      Org. Lett

      Volume: 13 Pages: 5994-5997

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unsymmetrical Squarylium Dyes with π-Extended Heterocyclic Components and Their Application to Organic Dye-sensitized Solar Cells2011

    • Author(s)
      T.Maeda, N.Shima, T.Tsukamoto, S.Yagi, H.Nakazumi
    • Journal Title

      Synthetic Metals

      Volume: 161 Issue: 21-22 Pages: 2481-2487

    • DOI

      10.1016/j.synthmet.2011.09.035

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared Absorbing Squarylium Dyes with Linearly Extended π-Conjugated Structure for Dye-sensitized Solar Cell Applications2011

    • Author(s)
      T.Maeda, Y.Hamamura, K.Miyanaga, N.Shima, S.Yagi, H.Nakazumi
    • Journal Title

      Organic Letters

      Volume: 13 Pages: 5994-5997

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] スクアリリウム色素を基盤とする三脚型有機色素の設計・合成及び色素増感太陽電池への応用2012

    • Author(s)
      前田壮志
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(横浜)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] スクアリリウム色素を基盤とする三脚型有機色素の設計・合成及び色素増感太陽電池への応用2012

    • Author(s)
      前田壮志, 八木繁幸, 中澄博行
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学,横浜市
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Design and Synthesis of NIR Absorbing Squarylium Dyes and Their Application to Dye-sensitized Solar Cells2011

    • Author(s)
      Takeshi Maeda
    • Organizer
      10^<th> International Symposium on Functional p-Electron Systems
    • Place of Presentation
      北京(中国)
    • Year and Date
      2011-10-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Design and Synthesis of NIR Absorbing Squarylium Dyes and Their Application to Dye-sensitized Solar Cells2011

    • Author(s)
      T.Maeda, Y.Hamamura, N.Shima, S.Yagi, H.Nakazumi
    • Organizer
      10^<th> International Symposium on Functional p-Electron Systems (Fp-10)
    • Place of Presentation
      Beijing, China
    • Year and Date
      2011-10-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 三脚型構造を有するスクアリリウム系色素の合成と二光子吸収特性2011

    • Author(s)
      前田壮志
    • Organizer
      日本化学会第91春季年会
    • Year and Date
      2011-03-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 三脚型構造を有するスクアリリウム系色素の合成と二光子吸収特性2011

    • Author(s)
      有川茂樹・前田壮志・八木繁幸・中澄博行
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (日本化学会第91春季年会(2011)講演予稿集)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] 三脚型スクアリリウム色素の二光子吸収特性2010

    • Author(s)
      前田壮志
    • Organizer
      2010年度色材研究発表会
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2010-10-11
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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