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Development of liquid-phase synthesis methods of opto-functionalized bulk silica glasses

Research Project

Project/Area Number 22750190
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionTokyo Metropolitan University

Principal Investigator

KAJIHARA Koichi  首都大学東京, 都市環境科学研究科, 准教授 (90293927)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsガラス / シリカガラス / 液相合成法 / 光機能化
Research Abstract

Liquid-phase synthesis methods of silica glass, which is an important optical material because of the excellent transparency over wide spectral range, high mechanical strength, and good chemical stability, have been developed. With overcoming the fracture during drying and sintering, which has been a long-standing problem in liquid-phase synthesis of silica glasses, various opto-functionalized bulk silica glasses, such as silica glasses with low SiOH concentrations, silica glasses doped with LaF_3 nanocrystals, and silica glasses doped with rare-earth ions at high concentrations, have been developed. Furthermore, fabrication of some new silica-based materials, including polysilsesquioxane liquids and ultraviolet-transparent organic-inorganic hybrids, have been demonstrated.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (31 results)

All 2012 2011 2010 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (20 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Sol-gel synthesis of rare-earth and phosphorus codoped monolithic silica glasses from a cosolvent-free phase-separating system2012

    • Author(s)
      K. Kajihara, S. Kuwatani, K. Kanamura
    • Journal Title

      Appl. Phys. Express

      Volume: 012601 Pages: 1-3

    • NAID

      10030154752

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nanocrystalline LaF-3 Doped Silica Glasses by Hydrofluoric Acid Catalyzed Sol-Gel Process2012

    • Author(s)
      S. Nagayama, K. Kajihara, K. Kanamura
    • Journal Title

      Mater. Sci. Eng. B

      Volume: 177 Pages: 510-514

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 相分離を伴う無共溶媒ゾル-ゲル法による希土類イオン高濃度ドープシリカガラスの合成2012

    • Author(s)
      梶原浩一
    • Journal Title

      化学工業

      Volume: 63 Pages: 368-372

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] Sol-gel synthesis of rare-earth and phosphorus codoped monolithic silica glasses from a cosolvent-free phase-separating system2012

    • Author(s)
      K.Kajihara, S.Kuwatani, K.Kanamura
    • Journal Title

      Appl.Phys.Express

      Volume: 5 Issue: 1 Pages: 012601-012601

    • DOI

      10.1143/apex.5.012601

    • NAID

      10030154752

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nanocrystalline LaF_3 Doped Silica Glasses by Hydrofluoric Acid Catalyzed Sol-Gel Process2012

    • Author(s)
      S.Nagayama, K.Kajihara, K.Kanamura
    • Journal Title

      Mater.Sci.Eng.B

      Volume: 177 Issue: 7 Pages: 510-514

    • DOI

      10.1016/j.mseb.2012.01.005

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sol-gel synthesis of fluorine-doped silica glasses with low SiOH concentrations2011

    • Author(s)
      R. Maehana, S. Kuwatani, K. Kajihara, K. Kanamura
    • Journal Title

      J. Ceram. Soc. Jpn

      Volume: 119 Pages: 393-396

    • NAID

      130000784597

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sol-gel synthesis of fluorine-doped silica glasses with low SiOH concentrations2011

    • Author(s)
      R.Maehana, S.Kuwatani, K.Kajihara, K.Kanamura
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 119 Issue: 1390 Pages: 393-396

    • DOI

      10.2109/jcersj2.119.393

    • NAID

      130000784597

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sol-gel synthesis of fluorine-doped silica glasses with low SiOH concentrations

    • Author(s)
      R.Maehana, S.Kuwatani, K.Kajihara., K.Kanamura
    • Journal Title

      J.Ceram.Soc.Jpn.

      Volume: (掲載決定)

    • NAID

      130000784597

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 紫外透明ポリシルセスキオキサンガラスの無共溶媒液相合成2012

    • Author(s)
      櫻木新,五十嵐雄太,梶原浩一,金村聖志
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都大学吉田キャンパス、京都
    • Year and Date
      2012-03-21
    • Related Report
      2011 Final Research Report
  • [Presentation] Cosolvent-free synthesis of thiol-modified polysiloxanes for organic-inorganic hybrids2012

    • Author(s)
      Y. Igarashi, K. Kajihara, K. Kanamura
    • Organizer
      セラミックス基礎科学討論会第50回記念大会
    • Place of Presentation
      国際ファッションセンター、東京
    • Year and Date
      2012-01-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Cosolvent-free sol-gel synthesis and fluorescence properties of rare earth-aluminum codoped silica glasses2012

    • Author(s)
      K. Kaneko, K. Kajihara, K. Kanamura
    • Organizer
      セラミックス基礎科学討論会第50回記念大会
    • Place of Presentation
      国際ファッションセンター、東京
    • Year and Date
      2012-01-12
    • Related Report
      2011 Final Research Report
  • [Presentation] 相分離を伴う無共溶媒ゾル-ゲル法による希土類ドープシリカガラスの合成2011

    • Author(s)
      梶原浩一、金子健、桑谷俊伍、金村聖志
    • Organizer
      第52回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      イーグレ姫路、兵庫
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 無共溶媒ゾル-ゲル法による希土類-アルミニウム共ドープシリカガラスの合成2011

    • Author(s)
      金子健、梶原浩一、金村聖志
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学、札幌
    • Year and Date
      2011-09-08
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 無共溶媒ゾル-ゲル法によるチオール基含有ポリシロキサンの合成2011

    • Author(s)
      五十嵐雄太、梶原浩一、金村聖志
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学、札幌
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Synthesis of Nanocrystalline LaF-3 Doped Silica Glasses by Hydrofluoric Acid Catalyzed Sol-Gel Process2011

    • Author(s)
      K. Kajihara, S. Nagayama, K. Kanamura
    • Organizer
      5th International Conference on Science and Technology for Advanced Ceramics(STAC5)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2011-06-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Nanocrystalline LaF_3 Doped Silica Glasses by Hydrofluoric Acid Catalyzed Sol-Gel Process2011

    • Author(s)
      K.Kajihara, S.Nagayama, K.Kanamura
    • Organizer
      5th International Conference on Science and Technology for Advanced Ceramics (STAC5)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2011-06-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 低SiOH含有量のフッ素ドープシリカガラスのゾル-ゲル合成2011

    • Author(s)
      梶原浩一、前花亮平、桑谷俊伍、金村聖志
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学、神奈川
    • Year and Date
      2011-03-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 希土類-リン共ドープシリカガラスのゾル-ゲル合成と発光特性2011

    • Author(s)
      梶原浩一、前花亮平、桑谷俊伍、金村聖志
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学、神奈川
    • Year and Date
      2011-03-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 紫外透明ポリシルセスキオキサンガラスの無共溶媒液相合成2011

    • Author(s)
      櫻木新・五十嵐雄太・梶原浩一・金村聖志
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都大学吉田キャンパス、京都
    • Year and Date
      2011-03-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 無共溶媒ゾル-ゲル法とトリフルオロ酢酸塩の熱分解によるLaF-3ナノ結晶ドープシリカガラスの合成2011

    • Author(s)
      鈴木琴美、永山修平、梶原浩一、金村聖志
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学、静岡
    • Year and Date
      2011-03-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 希土類-リン共ドープシリカガラスのゾル-ゲル合成と発光特性2011

    • Author(s)
      桑谷俊伍、梶原浩一、金村聖志
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学、静岡
    • Year and Date
      2011-03-16
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 無共溶媒ゾル-ゲル法とトリフルオロ酢酸塩の熱分解によるLaF_3ナノ結晶ドープシリカガラスの合成2011

    • Author(s)
      鈴木琴美、永山修平、梶原浩一、金村聖志
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学、静岡
    • Year and Date
      2011-03-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Cosolvent-free synthesis of thiol-modified polysiloxanes for organic-inorganic hybrids2011

    • Author(s)
      Yuta Igarashi, Koichi Kajihara, Kiyoshi Kanamura
    • Organizer
      セラミックス基礎科学討論会第50回記念大会
    • Place of Presentation
      国際ファッションセンター、東京
    • Year and Date
      2011-01-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Cosolvent-free sol-gel synthesis and fluorescence properties of rare earth-aluminum codoped silica glasses2011

    • Author(s)
      Ken Kaneko, Koichi Kajihara, Kiyoshi Kanamura
    • Organizer
      セラミックス基礎科学討論会第50回記念大会
    • Place of Presentation
      国際ファッションセンター、東京
    • Year and Date
      2011-01-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] Sintering behavior of sol-gel derived monolithic silica glasses doped with LaF-3 nanocrystals2011

    • Author(s)
      S. Nagayama, K. Kajihara, K. Kanamura
    • Organizer
      第49回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター、岡山
    • Year and Date
      2011-01-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Sintering behavior of sol-gel derived monolithic silica glasses doped with LaF_3 nanocrystals2011

    • Author(s)
      S.Nagayama, K.Kajihara, K.Kanamura
    • Organizer
      第49回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター、岡山
    • Year and Date
      2011-01-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Sol-Gel Synthesis of Nanocrystalline LaF-3 Doped Monolithic Silica Glasses from Solutions Containing Hydrofluoric Acid2010

    • Author(s)
      S. Nagayama, K. Kajihara, K. Kanamura
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      グランキューブ大阪、大阪
    • Year and Date
      2010-11-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Sol-Gel Synthesis of Nanocrystalline LaF_3 Doped Monolithic Silica Glasses from Solutions Containing Hydrofluoric Acid2010

    • Author(s)
      S.Nagayama, K.Kajihara, K.Kanamura
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      グランキューブ大阪、大阪
    • Year and Date
      2010-11-15
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] ポリシルセスキオキサン液体およびポリシルセスキオキサンガラスならびにその製造方法2012

    • Inventor(s)
      梶原浩一、桜木新、五十嵐雄太、金村聖志
    • Industrial Property Rights Holder
      首都大学東京
    • Industrial Property Number
      2012-049553
    • Filing Date
      2012-03-06
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Patent(Industrial Property Rights)] 金属元素ドープシリカガラスおよびその製造方法2011

    • Inventor(s)
      梶原浩一、桑谷俊伍、金子健
    • Industrial Property Rights Holder
      首都大学東京
    • Industrial Property Number
      2011-016831
    • Filing Date
      2011-01-28
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 金属元素ドープシリカガラスおよびその製造方法2011

    • Inventor(s)
      梶原浩一, 他4名
    • Industrial Property Rights Holder
      首都大学東京
    • Industrial Property Number
      2011-016831
    • Filing Date
      2011-01-28
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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