Construction of novel fluorous polymer based on photoinduced reaction

• Project/Area Number: 22750201
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Polymer/Textile materials
• Research Institution: Ochanomizu University
• Principal Investigator: YAJIMA Tomoko お茶の水女子大学, 大学院・人間文化創成科学研究科, 准教授 (10302994)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2010: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
• Keywords: 含フッ素ポリマー / 撥水性 / 光ラジカル反応 / 高分子合成 / 高分子構造・物性 / 環境材料 / ナノ材料

Research Abstract

New fluorine-containing polymers were successfully prepared with high yield based on our photoinduced radical reaction. We also demonstrated that the films of the polymers showed high water repellency, yet the polymers were low fluorine content. This synthetic method provides a highly efficient and practical route to a variety of new fluorous polymers.

Research Products

• [Journal Article] Promotion effects of optical antipodes on the formation of helical fibrils : chiral perfluorinated gelators (2012)
  • Author(s): Kazuhiro Kohno, Kazuya Morimoto, Naoko Manabe, Tomoko Yajima, Akihiko Yamagishi and Hisako Sato
  • Journal Title: Chem. Comm Volume: 48 Pages: 3860-3862
  • Peer Reviewed
• [Journal Article] Promotion effects of optical antipodes on the formation of helical fibrils : chiral perfluorinated gelators (2012)
  • Author(s): Kazuhiro Kohno, Kazuya Morimoto, Naoko Manabe, Tomoko Yajima, Akihiko Yamagishi, Hisako Sato
  • Journal Title: Chem.Comm. Volume: 48 Issue: 32 Pages: 3860-3862
  • DOI: 10.1039/c2cc18164a
  • Peer Reviewed
• [Journal Article] Molecular Origin for Helical Winding of Fibrils Formed by Perfluorinated Gelators (2011)
  • Author(s): Hisako Sato, Tomoko Yajima and Akihiko Yamagishi
  • Journal Title: Chem. Comm Volume: 47 Pages: 3736-3730
  • Peer Reviewed
• [Journal Article] Molecular Origin for Helical Winding of Fibrils Formed by Perfluorinated Gelators (2011)
  • Author(s): Hisako Sato, Tomoko Yajima, Akihiko Yamagishi
  • Journal Title: Chem.Comm. Volume: 47 Pages: 3736-3738
  • Peer Reviewed
• [Journal Article] (2011)
  • Author(s): Rie Hirokane, Kanano Yamaguchi, Tomoko Yajima
  • Journal Title: Peptide Science Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] Stereoselective synthesis ofβ-perfluoroalkyl amino acids and peptides (2010)
  • Author(s): Rie Hirokane, Kanako Yamaguchi, Tomoko Yajima
  • Journal Title: Peptide Science Volume: 47 Pages: 186-186
  • Peer Reviewed
• [Presentation] Promotion effects of optical antipodes on the formation of helical fibrils : chiral perfluorinated gelators (2012)
  • Author(s): Kazuhiro Kohno, Kazuya Morimoto, Naoko Manabe, Tomoko Yajima, Akihiko Yamagishi and Hisako Sato
  • Organizer: Chem. Comm
• [Presentation] 光ラジカル反応を用いたキラル含フッ素アミノ酸類の合成 (2012)
  • Author(s): 廣兼理恵・矢島知子
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川、慶応義塾大学
• [Presentation] キラルルイス塩基を用いたラジカル付加反応の立体制御 (2012)
  • Author(s): 眞鍋尚子・矢島知子
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川、慶応義塾大学
• [Presentation] らせん構造を有する有機ゲルの振動円二色性スペクトル (2012)
  • Author(s): 河野和宏、矢島知子、山岸皓彦、佐藤久子
  • Organizer: 化学系学協会北海道支部2012年冬季研究発表会
  • Place of Presentation: 北海道、北海道大学
• [Presentation] 光ラジカル反応による含フッ素化合物の合成と応用 (2011)
  • Author(s): 矢島知子
  • Organizer: 科学技術振興調整費「女性研究者支援モデル育成」事業「理工系女性研究者プロモーションプログラム」男性研究者・女性研究者合同研究発表会
  • Place of Presentation: 東京・東京工業大学大岡山キャンパス
  • Year and Date: 2011-02-01
• [Presentation] 光ラジカル反応を用いた新規含フッ素オリゴマーの合成 (2011)
  • Author(s): 新免愛実・矢島知子
  • Organizer: 第35回フッ素化学討論会
  • Place of Presentation: 岡山・岡山大学
• [Presentation] Photoinduced radical perfluoroalkylation and synthesis of fluorinated aminoacids (2011)
  • Author(s): Tomoko Yajima
  • Organizer: 5th Pacific Symposium on Radical Chemistry
  • Place of Presentation: Shirahama, Wakayama
• [Presentation] トリクロロシロキシ基を用いたラジカル付加反応の立体制御 (2011)
  • Author(s): 眞鍋尚子・矢島知子
  • Organizer: 第1回CSJ化学フェスタ
  • Place of Presentation: 東京、早稲田大学
• [Presentation] 含フッ素アミノ酸およびペプチドの合成とその応用 (2011)
  • Author(s): 廣兼理恵・矢島知子
  • Organizer: 第1回CSJ化学フェスタ
  • Place of Presentation: 東京、早稲田大学
• [Presentation] パーフルオロ基を有する有機ゲルのゲル化機構 (2011)
  • Author(s): 河野和宏、矢島知子、山岸皓彦、佐藤久子
  • Organizer: 第35回フッ素化学討論会
  • Place of Presentation: 岡山、岡山大学
• [Presentation] 光ラジカル反応を用いた新規含フッ素オリゴマーの合成 (2011)
  • Author(s): 新免愛実・矢島知子
  • Organizer: 第35回フッ素化学討論会
  • Place of Presentation: 岡山、岡山大学
• [Presentation] Stereoselectivity of Radical Addition Reaction by Trichlorosiloxy group (2011)
  • Author(s): Naoko Manabe, Tomoko Yajima
  • Organizer: 5th Pacific Symposium on Radical Chemistry
  • Place of Presentation: Shirahama, Wakayama
• [Presentation] Photoinduced radical perfluoroalkylation and synthesis of fluorinated amino acids (2011)
  • Author(s): Tomoko Yajima
  • Organizer: 5th Pacific Symposium on Radical Chemistry
  • Place of Presentation: Shirahama, Wakayama(招待講演)
• [Presentation] 含フッ素βペプチドの合成とその構造 (2011)
  • Author(s): 関根依純・矢島知子
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学横浜キャンパス(神奈川)
• [Presentation] トリクロロシロキシ基を用いたラジカル付加反応の立体制御 (2011)
  • Author(s): 眞鍋尚子・矢島知子
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学横浜キャンパス(神奈川)
• [Presentation] 光ラジカル付加反応を用いたフルオラスプロリン触媒の設計と合成 (2010)
  • Author(s): 吉田恵理子・矢島知子
  • Organizer: フルオラス科学研究会第3回シンポジウム
  • Place of Presentation: 長良川国際会議場(岐阜)
  • Year and Date: 2010-10-08
• [Presentation] ペルフルオロアルキル基の導入と液晶 (2010)
  • Author(s): 矢島知子
  • Organizer: 第14回液晶化学研究会シンポジウム
  • Place of Presentation: 東京大学山上会館(東京)
  • Year and Date: 2010-06-28
• [Presentation] RADICALPERFLUOROALKYLATION AND SYNTHESIS OF FLUORINE-CONTAINING AMINO ACIDS (2010)
  • Author(s): Tomoko Yajima
  • Organizer: 3^<rd> Korea-Japan-China Joint Seminar on Fluorine Chemistry
  • Place of Presentation: Daejeon, Korea
• [Presentation] Stereoselective synthesis of β-perfluoroalkyl amino acids and peptides (2010)
  • Author(s): Rie Hirokane, Kanako Yamaguchi, Tomoko Yajima
  • Organizer: 5^<th> International Peptide Symposium
  • Place of Presentation: Kyoto International Conference Center (Kyoto)
• [Presentation] 含フッ素β-ペプチドの合成とその構造 (2010)
  • Author(s): 関根依純・廣兼理恵・矢島知子
  • Organizer: 第34回フッ素化学討論会
  • Place of Presentation: 札幌サンプラザコンサートホール(北海道)
• [Presentation] MOLECULAR ORIGIN FOR HELICAL WINDING OF FIBRILS IN A GEL AS REVEALED BY VIBRATIONAL CIRCULAR DICHROISM SPECTRA (2010)
  • Author(s): Hisako Sato, Tomoko Yajima, Kayako Hori, Akihiko Yamgishi
  • Organizer: 22nd International Symposium on Chirality (Chirality 2010 ; ISCD-22)
  • Place of Presentation: Sapporo
• [Presentation] RADICAL PERFLUOROALKYLATION AND SYNTHESIS OF FLUORINE-CONTAINING AMINO ACIDS. (2010)
  • Author(s): Tomoko Yajima
  • Organizer: 3^<rd> Korea-Japan-China Joint Seminar on Fluorine Chemistry
  • Place of Presentation: Hotel Riviera Yuseong, Daejeon (Korea)