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Formation of Tandem Structures by Condensation Polymerization Using Photo-thermal Conversion

Research Project

Project/Area Number 22750209
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

KAWAMOTO Masuki  独立行政法人理化学研究所, 光電変換研究チーム, 副チームリーダー (70391927)

Research Collaborator NAGASE Yu  東海大学, 工学部・応用化学科, 教授 (40155932)
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Keywords光電変換 / 縮環系化合物 / カルバゾール / アモルファス固体 / オルソゴナル構造
Research Abstract

We investigated synthesis and characterization of amorphous compounds containing fused carbazole moieties. Upon cooling to room temperature, the moieties formed a transparent glass via a supercooled liquid state. Furthermore, amorphous films were prepared by spin coating onto a substrate. We found these compounds exhibit photo and electrochemical properties for application of photoelectric conversion systems.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (50 results)

All 2012 2011 2010

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (32 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Photoinversion of Cisoid/transoid Binaphthyls2012

    • Author(s)
      Kazuto Takaishi, Atsuya Muranaka, Masuki Kawamoto, and Masanobu Uchiyama
    • Journal Title

      Org. Lett

      Volume: 14 Pages: 276-279

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoinversion of Cisoid/transoid Binaphthyls2012

    • Author(s)
      Kazuto Takaishi, Atsuya Muranaka, Masuki Kawamoto, Masanobu Uchiyama
    • Journal Title

      Organic Letters

      Volume: 12 Pages: 276-279

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches2011

    • Author(s)
      Kazuto Takaishi, Masuki Kawamoto, Kazunori Tsubaki, Taniyuki Furuyama, Atsuya Muranaka, and Masanobu Uchiyama
    • Journal Title

      Chem. Eur. J

      Volume: 17 Pages: 1778-1782

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Conformation of Substituted Chiral Binaphthyl-Azobenzene Cyclic Dyads with Chiroptical Switching Capabilities2011

    • Author(s)
      Kazuto Takaishi and Masuki Kawamoto
    • Journal Title

      Molecules

      Volume: 16 Pages: 1603-1624

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Planar Chirality of Twisted trans-Azobenzene Structure Induced by Chiral Transfer from Binaphthyls2011

    • Author(s)
      Kazuto Takaishi, Atsuya Muranaka, Masuki Kawamoto, and Masanobu Uchiyama
    • Journal Title

      J. Org. Chem

      Volume: 76 Pages: 7623-7628

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mass Migration on a Polymer Surface Caused by Photoinduced Molecular Rotation2011

    • Author(s)
      Kunihiko Okano, Shohei Ogino, Masuki Kawamoto, and Takashi Yamashita
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 11891-11893

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and Properties of Copolymers Containing Indolocarbazole Moiety in the Side Chain2011

    • Author(s)
      Masaji Akimoto, Tatsuya Kawano, Yuta Iwasawa, Yusuke Takahashi, Kazuki Takahashi, Masuki Kawamoto, and Yu Nagase
    • Journal Title

      Polym. J

      Volume: 43 Pages: 959-965

    • NAID

      10030167569

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Planar Chirality of Twisted trans-Azobenzene Structure Induced by Chiral Transfer from Binaphthyls2011

    • Author(s)
      Kazuto Takaishi, Atsuya Muranaka, Masuki Kawamoto, Masanobu Uchiyama
    • Journal Title

      Journal of Organic Chemistry

      Volume: 76 Issue: 18 Pages: 7623-7628

    • DOI

      10.1021/jo201578z

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mass Migration on a Polymer Surface Caused by Photoinduced Molecular Rotation2011

    • Author(s)
      Kunihiko Okano, Shohei Ogino, Masuki Kawamoto, Takashi Yamashita
    • Journal Title

      Chemical Communications

      Volume: 47 Issue: 43 Pages: 11891-11893

    • DOI

      10.1039/c1cc14375a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and Properties of Copolymers Containing Indolocarbazole Moiety in the Side Chain2011

    • Author(s)
      Masaji Akimoto, Tatsuya Kawano, Yuta Iwasawa, Yusuke Takahashi, Kazuki Takahashi, Masuki Kawamoto, Yu Nagase
    • Journal Title

      Polymer Journal

      Volume: 43 Issue: 12 Pages: 959-965

    • DOI

      10.1038/pj.2011.102

    • NAID

      10030167569

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral Axis and Potential as Chiroptical Switches2011

    • Author(s)
      Kazuto Takaishi, Masuki Kawamoto, Kazunori Tsubaki, Taniyuki Furuyama, Atsuya Muranaka, Masanobu Uchiyama
    • Journal Title

      Chemistry : A European Journal

      Volume: 17 Pages: 1778-1782

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 動的分子ねじれ応答を利用した液晶らせん構造制御2010

    • Author(s)
      川本益揮
    • Journal Title

      日本液晶学会誌

      Volume: 14 Pages: 247-254

    • NAID

      10027650253

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-Destructive Erasable Molecular Switches and Memory Using Light-Driven Twisting Motions2010

    • Author(s)
      Masuki Kawamoto, Natsuki Shiga, Kazuto Takaishi, and Takashi Yamashita
    • Journal Title

      Chem. Commun

      Volume: 46 Pages: 8344-8346

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multi-Bridged Chiral Naphthalene Oligomers with Continuous Extreme-Cisoid Conformation2010

    • Author(s)
      Kazuto Takaishi, Masuki Kawamoto, Kazunori Tsubaki
    • Journal Title

      Organic Letters

      Volume: 12 Pages: 1832-1835

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-Destructive Erasable Molecular Switches and Memory Using Light-Driven Twisting Motions2010

    • Author(s)
      Masuki Kawamoto, Natsuki Shiga, Kazuto Takaishi, Takashi Yamashita
    • Journal Title

      Chemical Communications

      Volume: 46 Pages: 8344-8346

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 動的分子ねじれ応答を利用した液晶らせん構造制御2010

    • Author(s)
      川本益揮
    • Journal Title

      液晶

      Volume: 14 Pages: 247-254

    • NAID

      10027650253

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] インドロカルバゾール骨格を有するドナーアクセプター型イミド化合物の光・電気化学特性2012

    • Author(s)
      岩澤雄太,川本益揮,秋本雅史,長瀬裕,相田卓三
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27
    • Related Report
      2011 Final Research Report
  • [Presentation] インドロカルバゾール骨格を有するドナーアクセプター型イミド化合物の光・電気化学特性2012

    • Author(s)
      岩澤雄太, 川本益揮, 秋本雅史, 長瀬裕, 相田卓三
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ビナフチルからアゾベンゼンへの分子内不斉移動2012

    • Author(s)
      高石和人,川本益揮,村中厚哉,内山真伸
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-25
    • Related Report
      2011 Final Research Report
  • [Presentation] ビナフチルからアゾベンゼンへの分子内不斉移動2012

    • Author(s)
      高石和人, 川本益揮, 村中厚哉, 内山真伸
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] インドロカルバゾール含有ポリマーの合成と光学特性2011

    • Author(s)
      秋本雅史,山下和輝,高橋祐介,川本益揮,長瀬裕
    • Organizer
      第20回ポリマー材料フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2011-11-24
    • Related Report
      2011 Final Research Report
  • [Presentation] インドロカルバゾール含有ポリマーの合成と光学特性2011

    • Author(s)
      秋本雅史, 山下和輝, 高橋祐介, 川本益揮, 長瀬裕
    • Organizer
      第20回ポリマー材料フォーラム
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] ヘリカルキラリティーを有するシスアゾベンゼンの構築と光学特性の光スイッチング2011

    • Author(s)
      高石和人,川本益揮,椿一典,古山渓行,村中厚哉,内山真伸
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      筑波
    • Year and Date
      2011-09-23
    • Related Report
      2011 Final Research Report
  • [Presentation] ヘリカルキラリティーを有するシスアゾベンゼンの構築と光学特性の光スイッチング2011

    • Author(s)
      高石和人, 川本益揮, 椿一典, 古山渓行, 村中厚哉, 内山真伸
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場(筑波)
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] インドロカルバゾール含有共重合体の合成とフィルムの光学特性2011

    • Author(s)
      秋本雅史,山下和輝,岩澤雄太,高橋祐介,川本益揮,長瀬裕
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] インドロカルバゾール含有イミド化合物の合成と物性2011

    • Author(s)
      岩澤雄太,川本益揮,秋本雅史,高橋祐介,山下和輝,長瀬裕
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 分子モーターをドープしたPMMAフィルムの表面レリーフグレーティング形成挙動2011

    • Author(s)
      荻野昇平,川本益揮,岡野久仁彦,山下俊
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] インドロカルバゾール含有イミド化合物の合成と物性2011

    • Author(s)
      岩澤雄太, 川本益揮, 秋本雅史, 高橋祐介, 山下和輝, 長瀬裕
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 分子モーターをドープしたPMMAフィルムの表面レリーフク・レーティング・形成挙動2011

    • Author(s)
      荻野昇平, 川本益揮, 岡野久仁彦, 山下俊
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] インドロカルバゾール含有共重合体の合成とフィルムの光学特性2011

    • Author(s)
      秋本雅史, 山下和輝, 岩澤雄太, 高橋祐介, 川本益揮, 長瀬裕
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光駆動分子ねじれを利用した非破壊読み出しキラルメモリー2011

    • Author(s)
      川本益揮,志賀名月,高石和人,山下俊
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 光駆動分子ねじれを利用した非破壊読み出しキラルメモリー2011

    • Author(s)
      川本益揮・志賀名月・高石和人・山下俊
    • Organizer
      第91日本化学会春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] フォトリフラクティブポリマーDBR素子における書き込み光吸収の影響2011

    • Author(s)
      新美超・藤原隆・川本益揮・佐々高史・神成文彦
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      厚木
    • Year and Date
      2011-03-24
    • Related Report
      2011 Final Research Report
  • [Presentation] フォトリフラクティブポリマーDBE素子における書き込み光吸収の影響2011

    • Author(s)
      新美超・藤原隆・川本益揮・佐々高史・神成文彦
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学(厚木市)
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] フォトクロミック化合物を用いた新しい光リライタブルメモリー材料2011

    • Author(s)
      川本益揮・志賀名月・高石和人・山下俊
    • Organizer
      nano tech 2011国際ナノテクノロジー総合展・技術会議
    • Place of Presentation
      東京ビックサイト(東京都)
    • Year and Date
      2011-02-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and changeable chiroptical properties of axially chiral binapthyls linked to a photochromic azobenzene2010

    • Author(s)
      Kazuto Takaishi and Masuki Kawamoto
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies(Pacifichem 2010)
    • Place of Presentation
      Hawaii
    • Year and Date
      2010-12-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis and changeable chiroptical properties of axially chiral binapthyls linked to a photochromic azobenzene2010

    • Author(s)
      Kazuto Takaishi, Masuki Kawamoto, Kazunori Tsubaki
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Hawaii Convention Center (Hawaii)
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Graduated-Twistπ-Conjugation of Mutibridged Chiral Naphthalene Oligomaers2010

    • Author(s)
      Kazuto Takaishi, Masuki Kawamoto, and Kazunori Tsubaki
    • Organizer
      22nd international Symposium on Chirality 2010
    • Place of Presentation
      札幌
    • Year and Date
      2010-07-14
    • Related Report
      2011 Final Research Report
  • [Presentation] Photoinduced Modulation of Liquid Crystalline Helical Structures by Means of Dynamic Molecular Twisting Motions2010

    • Author(s)
      Masuki Kawamoto, Natsuki Shiga, and Takuya Aoki
    • Organizer
      22nd international Symposium on Chirality 2010
    • Place of Presentation
      札幌
    • Year and Date
      2010-07-14
    • Related Report
      2011 Final Research Report
  • [Presentation] Photoinduced Modulation of Liquid Crystalline Helical Structures by Means of Dynamic Molecular Twisting Motions2010

    • Author(s)
      Masuki Kawamoto, Natsuki Shiga, Takuya Aoki
    • Organizer
      22nd international Symposium on Chirality 2010
    • Place of Presentation
      Sapporo Convention Center (Sapporo)
    • Year and Date
      2010-07-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Graduated-Twist π-Conjugation of Mutibridged Chiral Naphthalene Oligomaers2010

    • Author(s)
      Kazuto Takaishi, Masuki Kawamoto, Kazunori Tsubaki
    • Organizer
      22nd international Symposium on Chirality 2010
    • Place of Presentation
      Sapporo Convention Center (Sapporo)
    • Year and Date
      2010-07-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] スター型液晶オリゴマーの合成と性質2010

    • Author(s)
      竹内智公・川本益揮
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-05-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光誘起分子配向変化を利用した超分子らせん構造形成2010

    • Author(s)
      川本益揮,佐々高史
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] インドロカルバゾールを主鎖骨格に有するポリマーの合成と性質2010

    • Author(s)
      高橋祐介,秋本雅史,川本益揮,長瀬裕
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ローター部位にフェニル基を有する分子モーターの合成と光応答性2010

    • Author(s)
      兵藤麻里江,岡野久仁彦,川本益揮,山下俊
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 光誘起分子配向変化を利用した超分子らせん構造形成2010

    • Author(s)
      川本益揮・佐々高史
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ローター部位にフェニル基を有する分子モーターの合成と光応答性2010

    • Author(s)
      兵藤麻里江・盧炯〓・岡野久仁彦・山下俊・川本益揮
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] インドロカルバゾールを主査骨格に有するポリマーの合成と性質2010

    • Author(s)
      高橋祐介・秋本雅史・川本益揮・長瀬裕
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] インドロカルバゾール含有イミド化合物及び合成中間体,これらの製造方法,有機半導体組成物,ならびに有機太陽電池素子2011

    • Inventor(s)
      川本益揮,岩澤雄太,長瀬裕,秋本雅史
    • Industrial Property Rights Holder
      独立行政法人理化学研究所,東海大学
    • Industrial Property Number
      2011-104785
    • Filing Date
      2011-05-09
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] インドロカルバゾール含有イミド化合物及び合成中間体,これらの製造方法,有機半導体組成物,ならびに有機太陽電池素子2011

    • Inventor(s)
      川本益揮・岩輝雄太・長瀬裕・秋本雅史
    • Industrial Property Rights Holder
      独立行政法人理化学研究所, 東海大学
    • Industrial Property Number
      2011-104785
    • Filing Date
      2011-05-09
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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