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Study of the effect of light irradiation on the electronic structure of organic semiconductor films

Research Project

Project/Area Number 22760008
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Applied materials science/Crystal engineering
Research InstitutionShimane University

Principal Investigator

TANAKA Senku  島根大学, 総合理工学部, 助教 (20397855)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords有機太陽電池 / 表面・界面物性 / 光物性 / 光電子分光法 / フタロシアニン / フラーレン / 有機薄膜太陽電池 / 光電子分光 / 有機半導体 / 有機/金属界面 / 有機/有機界面
Research Abstract

The effect of the light irradiation on the electronic structure of a donor/acceptor(DA) heterojunction interface was investigated by using the photoelectron spectroscopy. Under the light irradiation, the photoelectron spectrum was shifted corresponds to the polarity of the photovoltage of the DA heterojunction photovoltaic cell. The shift of photoelectron spectrum was caused by the photo-generated holes(electrons) in the donor(acceptor) layer. The shift value was, however, smaller than the typical value of open-circuit voltage of the DA heterojunction photovoltaic cell. The present results imply that the development of an electromotive force in an organic photovoltaic cell is closely related to a presence of semipermeable membranes for the photo-generated charges in the photovoltaic cell.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (18 results)

All 2012 2011 2010 Other

All Journal Article (3 results) (of which Peer Reviewed: 1 results) Presentation (12 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Photoinduced Shift of the Photoelectron Spectra at the Zn-phthalocyanine/C_<60> Interface2011

    • Author(s)
      S.Tanaka, K.Fukuzawa, I.Hiromitsu
    • Journal Title

      UVSOR Activity Report 2010

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Improvement of power conversion efficiency of phthalocyanine/C_<60> heterojunction solar cells by inserting a lithium phthalocyanine layer at the indium-tin oxide/phthalocyanine interface2010

    • Author(s)
      Senku Tanaka, Toshiyuki Hanada, Koji Ono, Kazuya Watanabe, Katsumi Yoshino and Ichiro Hiromitsu
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2011 Final Research Report
  • [Journal Article] Improvement of power conversion efficiency of phthalocyanine/C60 heterojunction solar cells by inserting a lithium phthalocyanine layer at the indium-tin oxide/phthalocyanine interface2010

    • Author(s)
      Senku Tanaka
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機/有機界面での光起電力と太陽電池の開放電圧との相関2012

    • Author(s)
      田中仙君、他
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(新宿区)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 有機/有機界面での光起電力と太陽電池の開放電圧との相関2012

    • Author(s)
      田中仙君
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機半導体ナノ薄膜表面への光照射による電子構造変化の観測2012

    • Author(s)
      田中仙君、他
    • Organizer
      佐賀大学シンクロトロン光応用研究センターナノテク事業成果報告会
    • Place of Presentation
      サンメッセ鳥栖(鳥栖市)
    • Year and Date
      2012-03-14
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 亜鉛フタロシアニン/C60界面における光起電力の光電子分光法による観測2012

    • Author(s)
      田中仙君、他
    • Organizer
      第25回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      鳥栖市民文化会館(鳥栖市)
    • Year and Date
      2012-01-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 亜鉛フタロシアニン/C_<60>界面における光起電力の光電子分光法による観測2012

    • Author(s)
      田中仙君
    • Organizer
      第25回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      鳥栖市民文化会館(鳥栖市)
    • Year and Date
      2012-01-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] 電子構造から考える有機薄膜太陽電池の光電変換特性2011

    • Author(s)
      田中仙君
    • Organizer
      S-グリーン・ライフナノ材料プロジェクト研究講演会
    • Place of Presentation
      島根大学(松江市)
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Photoinduced Effects on the Electronic Structure of the Organic/Organic and Organic/Metal Interfaces2011

    • Author(s)
      田中仙君、他
    • Organizer
      2011 MRS(Materials Research Society) Fall Meeting
    • Place of Presentation
      Boston(MA, USA)
    • Year and Date
      2011-11-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Photoinduced Effects on the Electronic Structure of the Organic/Organic and Organic/Metal Interfaces2011

    • Author(s)
      Senku Tanaka
    • Organizer
      2011 MRS (Materials Research Society) Fall Meeting
    • Place of Presentation
      Boston (MA, USA)
    • Year and Date
      2011-11-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属ドーピングした光電変換層を持つ有機薄膜太陽電池2011

    • Author(s)
      福澤謙、田中仙君、他
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形市)
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 光照射による有機薄膜の電子構造変化と光電変換特性との相関2011

    • Author(s)
      田中仙君、他
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形市)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 透明導電膜/フタロシアニンおよびフタロシアニン/C60界面の電子構造と光電変換特性の関係2011

    • Author(s)
      田中仙君、他
    • Organizer
      第24回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      つくば国際会議場(つくば市)
    • Year and Date
      2011-01-09
    • Related Report
      2011 Final Research Report
  • [Presentation] 透明導電膜/フタロシアニンおよびフタロシアニン/C60界面の電子構造と光電変換特性の関係2011

    • Author(s)
      田中仙君
    • Organizer
      第24回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      つくば市
    • Year and Date
      2011-01-09
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.phys.shimane-u.ac.jp/hiromitsu_lab/

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 有機フォトカソードおよびその製造方法2012

    • Inventor(s)
      田中仙君、廣光一郎
    • Industrial Property Rights Holder
      島根大学
    • Filing Date
      2012-02-16
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 有機フォトカソードおよびその製造方法2012

    • Inventor(s)
      田中仙君、廣光一郎
    • Industrial Property Rights Holder
      島根大学
    • Industrial Property Number
      2012-031253
    • Filing Date
      2012-02-16
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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