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Height control of pi-conjugated systems on solid surfaces

Research Project

Project/Area Number 22760027
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

ENDO Osamu  東京農工大学, 大学院・工学研究院, 助教 (30343156)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords表面 / X 線吸収分光 / π共役系 / 有機薄膜 / 軟X線吸収分光 / π電子系 / 自己組織化 / グラフェン / 軟X線吸収分光
Research Abstract

Organic and carbon-based materials are important for constructing novel flexible nano-devices. The electronic properties of devices are strongly related to the pi-conjugated systems, which interact with the substrate depending on the height. In this study, X-ray absorption fine structure spectroscopy at the carbon near K-edge has been developed for the height (or depth)-dependent analysis, and the spectra for the n-alkane monolayer is separated from those of the monolayer graphene grown on the Pt(111) surface as a demonstration.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (21 results)

All 2013 2012 2011 2010 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (15 results)

  • [Journal Article] Separation of C K-NEXAFS Spectra for Layer-by-Layer Analysis of Carbon-Based Thin Films2013

    • Author(s)
      O.Endo, M. Nakamura, K. Amemiya
    • Journal Title

      An n-Alkane Monolayer Adsorbed on a Monolayer Graphene Substrate Grown ona Pt(111) Surface

      Volume: accepted Pages: 27-31

    • DOI

      10.1016/j.elspec.2013.05.003

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Depth-dependent C K-NEXAFS spectra for self-assembled monolayers of 4-methylbenzenethiol and 4-ethylbenzenethiol on Au(111)2012

    • Author(s)
      O.Endo, M. Nakamura, K. Amemiya
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 187 Pages: 72-76

    • DOI

      10.1016/j.elspec.2013.04.012

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Amemiya, 1D Hydrogen Bond Chain on Pt(211) Stepped Surface Observed by O K-NEXAFS Spectroscopy2012

    • Author(s)
      O.Endo, M. Nakamura, R. Sumii, K
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 116 Issue: 26 Pages: 13980-13984

    • DOI

      10.1021/jp302509k

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Incommensurate Crystalline phase of n-Alkane Monolayers on Graphite (0001)2011

    • Author(s)
      O.Endo, T. Horikoshi, N. Katsumata, K. Otani, T. Fujishima, H. Goto, K. Minami, K. Akaike, H. Ozaki, R. Sumii, K. Amemiya, M. Nakamura, N. Kosugi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 115 Issue: 13 Pages: 5720-5725

    • DOI

      10.1021/jp1102143

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orientation of n-alkane in thin films on graphite(0001) studied using C K-NEXAFS2011

    • Author(s)
      O.Endo, H. Ozaki, R. Sumii, K. Amemiya, M. Nakamura, N. Kosugi
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 184 Pages: 257-260

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Orientation of n-alkane in thin films on graphite (0001) studied using CK-NEXAFS2011

    • Author(s)
      O.Endo, et al.
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: (accepted)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金(111)面におけるアルカン単分子層の脱水素反応2013

    • Author(s)
      遠藤理
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学東広島キャンパス(広島)
    • Year and Date
      2013-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Pt(111)面に形成した単層グラフェン上における直鎖アルカンの凝集構造2012

    • Author(s)
      遠藤理
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス(東京)
    • Year and Date
      2012-09-18
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 有機単分子層の深さ分解CK-NEXAFS測定2012

    • Author(s)
      遠藤理
    • Organizer
      第15回XAFS討論会
    • Place of Presentation
      鳥取白兎会館(鳥取)
    • Year and Date
      2012-09-11
    • Related Report
      2012 Final Research Report
  • [Presentation] Orientation Changes of n-Alkane in a Monolayer on Graphene Modified Pt(111) Studied by C KNEXAFS2012

    • Author(s)
      O.Endo
    • Organizer
      CMD-24, ECOSS-29, ECSCD-11, CMMP-12
    • Place of Presentation
      エジンバラ国際会議場(イギ リス)
    • Year and Date
      2012-09-06
    • Related Report
      2012 Final Research Report
  • [Presentation] グラフェン修飾白金(111)面におけるアルカン薄膜の深さ分解CK-NEXAFS測定2012

    • Author(s)
      遠藤理
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学西宮上ヶ原キャンパス(大阪)
    • Year and Date
      2012-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] グラフェン修飾白金(111)面におけるアルカン薄膜の深さ分解C K-NEXAFS測定2012

    • Author(s)
      遠藤理
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学西宮上ヶ原キャンパス(兵庫)
    • Year and Date
      2012-03-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機薄膜の深さ分解CK-NEXAFS測定2011

    • Author(s)
      遠藤理
    • Organizer
      第14回XAFS討論会
    • Place of Presentation
      岡崎コンファレンスセンター(愛知)
    • Year and Date
      2011-09-11
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機薄膜の深さ分解C K-NEXAFS測定2011

    • Author(s)
      遠藤理
    • Organizer
      第14回XAFS討論会
    • Place of Presentation
      岡崎コンファレンスセンター(愛知
    • Year and Date
      2011-09-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] グラファイト(0001)面におけるアルカン薄膜の深さ分解CK-NEXAFS2011

    • Author(s)
      遠藤理
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      第66回年次大会講演資料公開サイト
    • Related Report
      2012 Final Research Report
  • [Presentation] グラファイト(0001)面におけるアルカン薄膜の深さ分解C K-NEXAFS2011

    • Author(s)
      遠藤理
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      (第66回年次大会講演資料公開サイト)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Orientation of n-Alkane in Thin Films on Graphite (0001) Studied by C K-NEXAFS2010

    • Author(s)
      O.Endo
    • Organizer
      37th international Conference on Vacuum UltraViolet and X-ray Physics
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-07-16
    • Related Report
      2012 Final Research Report
  • [Presentation] Orientation of n-Alkane in Thin Films on Graphite (0001) Studied by CK-NEXAFS2010

    • Author(s)
      O.Endo
    • Organizer
      37^<th> international Conference on Vacuum Ultra Violet and X-ray Physics
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-07-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Orientation Changes of n-Alkane in a Monolayer on Graphene Modified Pt(111) Studied by C K-NEXAFS

    • Author(s)
      O. Endo
    • Organizer
      CMD-24, ECOSS-29, ECSCD-11, CMMP-12
    • Place of Presentation
      エジンバラ国際会議場(イギリス)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 有機単分子層の深さ分解C K-NEXAFS測定

    • Author(s)
      遠藤理
    • Organizer
      第15回XAFS討論会
    • Place of Presentation
      鳥取白兎会館(鳥取)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金(111)面におけるアルカン単分子層の脱水素反応

    • Author(s)
      遠藤理
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学 東広島キャンパス(広島)
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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