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High efficient spin injection into graphene

Research Project

Project/Area Number 22760033
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

ENTANI Shiro  独立行政法人日本原子力研究開発機構, 先端基礎研究センター, 任期付研究員 (40549664)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsグラフェン / エピタキシャル成長 / ラマン分光
Research Abstract

Studies have been conducted for the realization of high efficient spin injection into graphene. Dependences of the peaks shifts of the Raman bands on the graphene layers number and metal species at the graphene/metal interfaces reveal that the interfacial interactions are dramatically different between single layer and multilayer graphenes. In situ analysis was performed on the graphene growth in ultrahigh vacuum chemical vapor deposition by exposing the epitaxial Ni(111) thin film to benzene vapor. It is shown that the highly uniform single- and bi-layer graphenes can be synthesized by the control of benzene exposure in the range of 10-10 5 langmuirs, reflecting a change in the graphene growth-rate by three orders of magnitude in between the first and second layer. Based on the above results, the graphene lateral devices with bottom contact-configuration were fabricated.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (35 results)

All 2013 2012 2011 2010

All Journal Article (17 results) (of which Peer Reviewed: 16 results) Presentation (18 results)

  • [Journal Article] Spin polarization of single-layer graphene epitaxially growon on Ni(111) thin film2013

    • Author(s)
      S. Entani, M. Kurahashi, X. Sun, Y. Yamauchi
    • Journal Title

      Carbon

      Volume: (in press) Pages: 134-139

    • DOI

      10.1016/j.carbon.2013.04.077

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Contact-induced spin polarization in graphene/h-BN/Ni Nanocomposites2012

    • Author(s)
      P.V. Avramov, A.A. Kuzubov, S. Sakai, H. Naramoto, M. Ohtomo, S. Entani, Y. Matsumoto, P.B. Sorokin
    • Journal Title

      J. Appl. Phys.

      Volume: 112 Issue: 11 Pages: 114303-114303

    • DOI

      10.1063/1.4767134

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High hydrogen-adsorption-rate material based on graphene decorated with alkali metals2012

    • Author(s)
      L.Y. Antipina, P.V. Avramov, S. Sakai, H. Naramoto, M. Ohtomo, S. Entani, Y. Matsumoto, P.B. Sorokin
    • Journal Title

      Phys. Rev. B

      Volume: 86 Issue: 8 Pages: 85435-85435

    • DOI

      10.1103/physrevb.86.085435

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intrinsic edge asymmetry in narrow zigzag hexagonal heteroatomic nanoribbons causes their subtle uniform curvature2012

    • Author(s)
      P.V. Avramov, D.G. Fedorov, P.B. Sorokin, S. Sakai, H. Naramoto, M. Ohtomo, S. Entani, Y. Matsumoto, H. Naramoto
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 3 Issue: 15 Pages: 2003-2003

    • DOI

      10.1021/jz300625t

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure determination of self-assembled monlayer on oxide surface by soft-X-ray standing wave2012

    • Author(s)
      Y. Baba, A. Narita, T. Sekiguchi, I. Shimoyama, N. Hirao, S. Entani, S. Sakai
    • Journal Title

      e-J. Surf. Sci. Nanotech.

      Volume: 10 Pages: 69-73

    • URL

      http://www.sssj.org/ejssnt

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Precise control of single- and bi-layer graphene growths on epitaxial Ni(111) thin film2012

    • Author(s)
      S. Entani, Y. Matsumoto, M. Ohtomo, P.V. Avramov, H. Naramoto, S. Sakai
    • Journal Title

      J. Appl. Phys.

      Volume: 111 Issue: 6 Pages: 64324-64324

    • DOI

      10.1063/1.3694662

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local structures and magnetic properties of Fullerene-Co systems studied by XAFS and XMCD analyses2012

    • Author(s)
      I. Hojo, A. Koide, Y. Matsumoto, T. Maruyama, S. Nagamatsu, S. Entani, S. Sakai, T. Fujikawa
    • Journal Title

      J. Elect. Spect. Relat. Phenom.

      Volume: 185 Pages: 32-38

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bias voltage dependence of tunneling magnetoresistance in granular C_<60>-Co films with current-perpendicular-to-plane geometry2012

    • Author(s)
      S. Sakai, S. Mitani, Y. Matsumoto, S. Entani, P.V. Avramov, M. Ohtomo, H. Naramoto, K. Takanashi
    • Journal Title

      J. Magn. Magn. Mater

      Volume: 324 Issue: 12 Pages: 1970-1970

    • DOI

      10.1016/j.jmmm.2012.01.033

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bias voltage dependence of tunneling magnetoresistance in granular C60-Co films with currentperpendicular-to-plane geometry2012

    • Author(s)
      S. Sakai, et al.
    • Journal Title

      J. Magn. Mag. Mater.

      Volume: 324 Pages: 1970-1974

    • DOI

      10.1016/j.jmmm.2013.01.033

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure determination of self-assembled monlayer on oxide surface by soft-X-ray standing wave2012

    • Author(s)
      Y. Baba, et al.
    • Journal Title

      e-Journal of Sur. Sci. Nanotech.

      Volume: 10 Pages: 69-73

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Ferromagnetic interlayer coupling in C_<60>-Co compound/Ni bilayer structure2011

    • Author(s)
      Y.Matsumoto, S.Sakai, S.Entani, Y.Takagi, T.Nakagawa, H.Naramoto, P.Avramov, T.Yokoyama
    • Journal Title

      Chem.Phys.Lett.

      Volume: 511 Issue: 1-3 Pages: 68-72

    • DOI

      10.1016/j.cplett.2011.05.038

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ab initio LC-DFT study of graphene, multilayer graphene and graphite2011

    • Author(s)
      P.V. Avramov, S. Sakai, S. Entani, Y. Matsumoto, H. Naramoto
    • Journal Title

      Chem. Phys. Lett.

      Volume: 508 Issue: 1-3 Pages: 86-86

    • DOI

      10.1016/j.cplett.2011.04.016

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface Properties of Ag and Au/Graphene Heterostructures Studied by Micro-Raman Spectroscopy2011

    • Author(s)
      S. Entani, S. Sakai, Y. Matsumoto, T. Hao, H. Naramoto, Y. Maeda
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 50

    • NAID

      210000070404

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of cotunneling and spin polarization on the large tunneling magnetoresistance effect in granular C_<60>-Co films2011

    • Author(s)
      S.Sakai, S.Mitani, I.Sugai, K.Takanashi, Y.Matsumoto, S.Entani, H.Naramoto, P.V.Avramov, Y.Maeda
    • Journal Title

      Physical Review B

      Volume: 83 Issue: 17 Pages: 174422-174422

    • DOI

      10.1103/physrevb.83.174422

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface Properties of Ag and Au/Graphene Heterostructures Studied by Micro-Raman Spectroscopy2011

    • Author(s)
      圓谷志郎
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 50

    • NAID

      210000070404

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface Properties of Metal/graphene Hetero- structures Studied by Micro-Raman Spectroscopy2010

    • Author(s)
      S. Entani, S. Sakai, Y. Matsumoto, T. Hao, H. Naramoto, Y. Maeda
    • Journal Title

      J. Phys. Chem. C

      Volume: 114 Issue: 47 Pages: 20042-20042

    • DOI

      10.1021/jp106188w

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface Properties of Metal/graphene Heterostructures Studied by Micro-Raman Spectroscopy2010

    • Author(s)
      圓谷志郎
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 114 Pages: 20042-20048

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] X線定在波法によるグラフェン/サファイア界面の解析2013

    • Author(s)
      圓谷志郎
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Atomic structure determination of the graphene/sapphire interface by normal incident X-ray standing wave spectroscopy2013

    • Author(s)
      圓谷志郎
    • Organizer
      第44回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2013-03-12
    • Related Report
      2012 Final Research Report
  • [Presentation] UHV-CVD growth of graphene for spintronic applications2012

    • Author(s)
      S. Entani
    • Organizer
      4th International Meeting on Spins in Organic Semiconductor
    • Place of Presentation
      クイーンメリー大学、英国
    • Year and Date
      2012-09-10
    • Related Report
      2012 Final Research Report
  • [Presentation] Growth of highly uniform graphene for spintronic applications2012

    • Author(s)
      S. Entani
    • Organizer
      19th International Conference on Magnetics
    • Place of Presentation
      BEXCO、韓国
    • Year and Date
      2012-07-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni(111)およびCu(111)薄膜上のグラフェン成長と伝導特性2012

    • Author(s)
      圓谷志郎
    • Organizer
      2012 年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2012 Final Research Report
  • [Presentation] Ni(111)およびCu(111)薄膜上のグラフェン成長と伝導特性2012

    • Author(s)
      境誠司、松本吉弘、圓谷志郎、大伴真名歩、アブラモフパベル、楢本洋
    • Organizer
      応用物理学会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Growth of highly uniform graphene for spintronic appliations2012

    • Author(s)
      圓谷志郎、他
    • Organizer
      19th International Conference on Magnetism
    • Place of Presentation
      韓国 釜山
    • Related Report
      2012 Annual Research Report
  • [Presentation] Direct probing of spin polarization in graphene on magnetic metal surface by metastable helium beam2012

    • Author(s)
      圓谷志郎、他
    • Organizer
      2nd Internationla Conference of Asia Union on Magnetics Societies
    • Place of Presentation
      奈良 奈良県新公会堂
    • Related Report
      2012 Annual Research Report
  • [Presentation] Precise control of layer number in graphene grown on Ni(111)2011

    • Author(s)
      S. Entani
    • Organizer
      2011 International Conference on Solid State Devices and Materials
    • Place of Presentation
      愛知県労働産業センター
    • Year and Date
      2011-09-29
    • Related Report
      2012 Final Research Report
  • [Presentation] Precise control of layer number in graphene grown on Ni (111)2011

    • Author(s)
      S.Entani, Y.Matsumoto, M.Ohtomo, P.V.Avramov, H.Naramoto, S.Sakai
    • Organizer
      2011 SSDM
    • Place of Presentation
      愛知県産業労働センター
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] グラフェンの精密層数制御2011

    • Author(s)
      圓谷志郎
    • Organizer
      第35回日本磁気学会学術講演会
    • Place of Presentation
      新潟コンベンションセンター
    • Year and Date
      2011-09-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 磁性金属表面上のグラフェン層数の精密制御2011

    • Author(s)
      圓谷志郎、松本吉弘、大伴真名歩、アブラモフパベル、楢本洋、境誠司
    • Organizer
      応用物理学会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 分子スピントロニクス創製に向けたナノカーボン材料の物性・分光研究2011

    • Author(s)
      圓谷志郎、松本吉弘、大伴真名歩、アブラモフパベル、楢本洋、境誠司
    • Organizer
      Vacuum 2011
    • Place of Presentation
      東京ビッグサイト
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] 磁性金属表面上のグラフェン層数の精密制御2011

    • Author(s)
      圓谷志郎
    • Organizer
      2011 年秋季第72回応用物理学学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-08-02
    • Related Report
      2012 Final Research Report
  • [Presentation] In-situ analysis of graphene growth process on magnetic metal thin film2011

    • Author(s)
      S. Entani
    • Organizer
      2011 MRS Spring Meeting
    • Place of Presentation
      モスコーニコンベンションセンター 米国
    • Year and Date
      2011-04-28
    • Related Report
      2012 Final Research Report
  • [Presentation] In-situ analysis of graphene growth process on magnetic metal thin films2011

    • Author(s)
      S.Entani, Y.Matsumoto, P.V.Avramov, H.Naramoto, S.Sakai
    • Organizer
      2011 MRS Spring Meeting
    • Place of Presentation
      San Francisco
    • Year and Date
      2011-04-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Graphene layers dependent vibrational property of metal-graphene heterostructures2010

    • Author(s)
      S. Entani
    • Organizer
      2011 International Conference on Solid Devices and Materials
    • Place of Presentation
      東京大学
    • Year and Date
      2010-09-23
    • Related Report
      2012 Final Research Report
  • [Presentation] 磁性金属薄膜上へのグラフェンのエピタキシャル成長2010

    • Author(s)
      圓谷志郎
    • Organizer
      応用物理学会
    • Place of Presentation
      長崎
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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