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Development of a small-scale heavy metal detection system using pulse-modulated inductively coupled He microplasma combined with micro total analysis system

Research Project

Project/Area Number 22760051
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Applied physics, general
Research InstitutionThe University of Tokyo

Principal Investigator

TAJIMA Satomi  東京大学, 大学院・工学研究科, 特任研究員 (50537941)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsマイクロプラズマ / パルス変調 / ジェット進展 / ストリーマー / 血漿分離 / μTAS / パルス駆動 / 局所はっ水化 / プラズマレスエッチング / Heプラズマ / 高精度化 / プラズマへの液体導入 / 小型 / 電子エネルギー / 安定駆動
Research Abstract

Conventional inductively coupled plasma ICP-atomic emission spectroscopy AES with high-gas temperature can detect ppb level heavy metal from environmental samples, such as blood, water, and soil. However, the ICP-AES is large and require complicated environmental sample preparation sequences so that the system cannot be used for the real-time on-site heavy metal detection. In this study, a small-scale ICP was pulse-modulated. The initial peak, produced by the difference in the ramping speed of electron temperature and electron density was used to detect ppb level signal from reference sample. In the second year, a T-shape micro total analysis system(μTAS) was fabricated to collect blood serum from whole blood at high speed. The blood serum collection port was fixed at the width of 15 um while varying the blood cell collection port at 45-90 to obtain the optimum blood flow while preventing the hemolysis.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 2 results) Presentation (19 results)

  • [Journal Article] On/off pulse modulation of atmospheric-pressure helium/argon inductively coupled plasma mcrojet for plasma processing of polymers2010

    • Author(s)
      S. Tajima, S. Tsuchiya, M. Matsumori, S. Nakatsuka, and T. Ichiki
    • Journal Title

      J. Photopolym. Sci. Technol

      Volume: 23 Pages: 555-560

    • Related Report
      2011 Final Research Report
  • [Journal Article] Optical and electrical characterization of pulse-modulated argon atmospheric-pressure inductively coupled microplasma jets2010

    • Author(s)
      S. Tajima, M. Matsumori, S. Nakatsuka, S. Tsuchiya, and T. Ichiki
    • Journal Title

      J. Appl. Phys

      Volume: 108 Pages: 833021-5

    • Related Report
      2011 Final Research Report
  • [Journal Article] On/off pulse modulation of atmospheric-pressure helium/argon inductively coupled plasma mcrojet for plasma processing of polymers2010

    • Author(s)
      S.Tajima S.Tsuchiya, M.Matsumori, S.Nakatsuka, T.Ichiki
    • Journal Title

      J.Photopolym.Sci.Technol.

      Volume: 23 Pages: 555-560

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and electrical characterization of pulse-modulated argon atmospheric-pressure inductively coupled microplasma jets2010

    • Author(s)
      S.Tajima, M.Matsumori, S.Nakatsuka, S.Tsuchiya, T.Ichiki
    • Journal Title

      J.Appl.Phys

      Volume: 108

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Generation dynamics of an argon atmospheric-pressure inductively coupled plasma microjet evaluated by spectroscopic measurement techniques in review

    • Author(s)
      Satomi Tajima, Keiichiro Urabe, Dae-Sung Lee, Kunihide Tachibana, and Takanori Ichiki
    • Journal Title

      Satomi Tajima, Keiichiro Urabe, Dae-Sung Lee, Kunihide Tachibana, and Takanori Ichiki

    • Related Report
      2011 Final Research Report
  • [Presentation] Development of a plasma-less Si chemical dry etching method2012

    • Author(s)
      S. Tajima, K. Ishikawa, T. Hayashi, and M. Hori
    • Organizer
      59th Spring meeting of the Japan Society of Applied Physics
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of a plasma-less Si chemical dry etching method2012

    • Author(s)
      S.Tajima, K.Ishikawa, T.Hayashi, M.Hori
    • Organizer
      59^<th> Spring meeting of the Japan Society of Applied Physics
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of a Si dry chemical etching technique using NO/F_2 gas mixtures without using plasmas2012

    • Author(s)
      S. Tajima, K. Ishikawa, T. Hayashi, and M. Hori
    • Organizer
      The 5th International Conference on Plasma-Nanotechnology & Science
    • Place of Presentation
      犬山国際観光センター(愛知県)
    • Year and Date
      2012-03-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of a Si dry chemical etching technique using NO/F_2 gas mixtures without using plasmas2012

    • Author(s)
      S.Tajima, K.Ishikawa, T.Hayashi, M.Hori
    • Organizer
      The 5^<th> International Conference on Plasma-Nano technology & Science
    • Place of Presentation
      犬山国際観光センター(愛知県)
    • Year and Date
      2012-03-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Fast separation of blood cells by a T-shape microfluidic device2011

    • Author(s)
      S. Tajima and T. Ichiki
    • Organizer
      The 21st MRS-Japan Academic Symposium
    • Place of Presentation
      横浜情報文化センター(神奈川県)
    • Year and Date
      2011-12-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Fast separation of blood cells by a T-shape microfluidic device2011

    • Author(s)
      S.Tajima, T.Ichiki
    • Organizer
      The 21st MRS-Japan Academic Syrmposium
    • Place of Presentation
      横浜情報文化センター(神奈川県)
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] High-speed deposition of fluorocarbon films by C_4F_8/H_2/Ar atmospheric-pressure inductively coupled plasma2011

    • Author(s)
      S. Tajima and T. Ichiki
    • Organizer
      The 33rd International Symposium on Dry Process
    • Place of Presentation
      日京都ガーデンパレスホテル(京都府)
    • Year and Date
      2011-11-10
    • Related Report
      2011 Final Research Report
  • [Presentation] High-speed deposition of fluorocarbon films by C_4F_8/H_2/Ar atmospheric-pressure inductively coupled plasma2011

    • Author(s)
      S.Tajima, T.Ichiki
    • Organizer
      The 33rd International Symposium on Dry Process
    • Place of Presentation
      京都ガーデンパレスホテル(京都府)
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spatiotemporal distributions of excited state Ar atoms and N2 molecules in a pulse-modulated Ar atmospheric-pressure inductively coupled plasma microjet2011

    • Author(s)
      S. Tajima and T. Ichiki
    • Organizer
      The 24th Symposium on Plasma Science for Materials(SPSM-24)
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2011-07-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Spatiotemporal distributions of excited state Ar atoms and N_2 molecules in a pulse-modulated Ar atmospheric-pressure inductively coupled plasma microjet2011

    • Author(s)
      S.Tajiima, T.Ichiki
    • Organizer
      The 24th Symposium on Plasma Science for Materials (SPSM-24)
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2011-07-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] High-speed plasma enhanced chemical vapor deposition of flurocarbon film by atmosphereic-pressure inductively coupled plasma microjet2011

    • Author(s)
      S. Tajima, S. Tsuchiya, and T. Ichiki
    • Organizer
      The 28th International Conference of Photopolymer Science and Technology
    • Place of Presentation
      千葉大学(千葉県)
    • Year and Date
      2011-06-23
    • Related Report
      2011 Final Research Report
  • [Presentation] High-speed plasma enhanced chemical vapor deposition of flurocarbon film by atmosphereic-pressure inductively coupledplasma microjet2011

    • Author(s)
      S.Tajima, S.Tsuchiya, T.Ichiki
    • Organizer
      The 28^<th> International Conference of Photopolymer Science and Technology
    • Place of Presentation
      千葉大学(千葉県)
    • Year and Date
      2011-06-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Stable sample introduction to the pulse-modulated atmospheric-pressure inductively coupled plasma microjet atomic emission spectrometry2011

    • Author(s)
      T. Nomura, S. Tsuchiya, S. Tajima, and T. Ichiki
    • Organizer
      第58回春季応用物理学会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Optical observation of the atmospheric-pressure inductively coupled plasma jet propagation dynamics2011

    • Author(s)
      S. Tajima, and T. Ichiki
    • Organizer
      第58回春季応用物理学会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2011-03-24
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Dynamic observation of the pulse-modulated atmospheric-pressure ICP microjets2010

    • Author(s)
      S. Tajima, and T. Ichiki
    • Organizer
      20th Materials Research Society(MRS)-Japan Academic Symposium
    • Place of Presentation
      開港記念館(神奈川県)
    • Year and Date
      2010-12-21
    • Related Report
      2011 Final Research Report
  • [Presentation] Dynamic observation of the pulse-modulated atmospheric-pressure ICP microjets2010

    • Author(s)
      S.Tajima, T.Ichiki
    • Organizer
      20th Materials Research Society (MRS)-Japan Academic Symposium
    • Place of Presentation
      開港記念館(神奈川県)
    • Year and Date
      2010-12-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Generation of pulse-modulated He and He/Ar atmospheric-pressure inductively coupled microjets2010

    • Author(s)
      S. Tajima, S. Tsuchiya, T. Numura, M. Matsumori, S. Nakatsuka, and T. Ichiki
    • Organizer
      第70回秋季応用物理学会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2010-09-14
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] On/off pulse modulation of atmospheric-pressure helium/argon inductively coupled plasma microjet for plasma processing of polymers2010

    • Author(s)
      S. Tajima, S. Tsuchiya, M. Matsumori, S. Nakatsuka, and T. Ichiki
    • Organizer
      The 27th International conference of photopolymer science and technology(ICPST-27)
    • Place of Presentation
      千葉大学(千葉県)
    • Year and Date
      2010-06-24
    • Related Report
      2011 Final Research Report
  • [Presentation] On/off pulse modulation of atmospheric-pressure helium/argon inductively coupled plasma microjet for plasma processing of polymers2010

    • Author(s)
      S.Tajima, S.Tsuchiya, M.Matsumori, S.Nakatsuka, T.Ichiki
    • Organizer
      The 27th International conference of photopolymer science and technology (ICPST-27)
    • Place of Presentation
      千葉大学(千葉県)
    • Year and Date
      2010-06-24
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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