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Stabilization mechanism of Li-doped hydride phase synthesized by high pressure synthesis in GPa order.

Research Project

Project/Area Number 22760527
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

KAMEGAWA Atsunori  東北大学, 大学院・工学研究科, 准教授 (90292242)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords水素化物 / 高圧合成 / 相変態 / 水素 / 新エネルギー
Research Abstract

Novel hydrides in Li-TM system (TM=Ti、Zr、Hf、Ni、V、Nb、Ta)were explored by high pressure synthesis. In Li-TM system (TM=Zr, Hf, Ni, V, Nb, Ta), newly found hydrides were synthesized, and their thermal stabilities and crystal structures were evaluated. For Li-Ni-H system, novel hydride with a fcc structure was synthesized under 5GPa. This hydride desorbed hydrogen at 400K with endothermic reaction. For Li-Hf-H, Li-Nb-H and Li-Ta-H system, novel hydride with hexagonal, CaCu5-type and monoclinic structures were synthesized, respectively.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (5 results)

All 2011 2010

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (3 results)

  • [Journal Article] Novel Hydrides in Li-TM Systems Synthesized by High Pressure Method (TM=Ti, Zr, Hf)2011

    • Author(s)
      R.Kataoka, T.Sato, T.Kuriiwa, A.Kamegawa, M.Okada
    • Journal Title

      Materials Transactions

      Volume: 52 Pages: 49-53

    • NAID

      10027672195

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel Hydrides in Li-TM Systems Synthesized by High Pressure Method (TMDOI:Ti, Zr, Hf)2010

    • Author(s)
      R. Kataoka, T. Sato, T. Kuriiwa, A. Kamegawa, M. Okada
    • Journal Title

      Materials Transactions

      Volume: 52巻 Pages: 49-53

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] 超高圧法によるSn-TM系新規化合物の合成(TM=3d遷移金属)2011

    • Author(s)
      柴田章兵, 栗岩貴寛, 亀川厚則, 岡田益男
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      宜野湾市(沖縄)
    • Year and Date
      2011-11-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 超高圧法による新規金属間化合物Mg_<1. 1> Pd_<0. 9> の合成2011

    • Author(s)
      川上真世, 高荷直樹, 栗岩貴寛, 亀川厚則, 岡田益男
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      宜野湾市(沖縄)
    • Year and Date
      2011-11-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 超高圧合成法による新規水素貯蔵材料の探索2011

    • Author(s)
      亀川厚則, 岡田益男
    • Organizer
      MH利用開発研究会20周年シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      2011-02-09
    • Related Report
      2011 Final Research Report 2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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