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Functional advancement of complex hydrides as solid electrolyte and development of new electrode materials for lithium-ion batteries

Research Project

Project/Area Number 22760529
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

MATSUO Motoaki  東北大学, 金属材料研究所, 講師 (20509038)

Research Collaborator OGUCHI Hiroyuki  東北大学, 大学院・工学研究科, 特任助教 (40570908)
SATO Toyoto  東北大学, 金属材料研究所, 博士研究員 (20455851)
SEMBOSHI Satoshi  東北大学, 金属材料研究所, 講師 (00364026)
IKESHOJI Tamio  東北大学, 金属材料研究所, 客員研究員 (10356420)
MAEKAWA Hideki  東北大学, 大学院・工学研究科, 准教授 (60238847)
TAKAMURA Hitoshi  東北大学, 大学院・工学研究科, 教授 (30250715)
ORIMO Shin-ichi  東北大学, 金属材料研究所, 教授 (40284129)
IKEDA Kazutaka  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 特任准教授 (80451615)
OHTOMO Toshiya  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 教授 (90270397)
LI Hai-wen  九州大学, 水素エネルギー国際研究センター, 准教授 (20505771)
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords水素 / 水素化物 / エネルギー / リチウムイオン伝導 / 固体電解質 / 錯体水素化物 / ナトリウムイオン伝導 / 全固体電池 / イオン液体
Research Abstract

We have worked on the functional advancement of complex hydrides as solid electrolyte and development of new electrode materials for lithium-ion batteries. It was found that the ion substitution for Li+ and [BH4]. complex anion is effective to improve the ionic conductivity of LiBH4. As a result, we succeeded in synthesizing new complex hydrides such as Li_3N_2IH_4 and Na_2BNH_6 with fast ionic conductivities. We also confirmed the lithium deintercalation of Li_xBC, a potential candidate for high-capacity electrode materials, from x=1 to x approximate to 0. 5.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (45 results)

All 2012 2011 2010 Other

All Journal Article (14 results) (of which Peer Reviewed: 12 results) Presentation (24 results) Remarks (4 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Sodium ionic conduction in complex hydrides with [BH_4]-and [NH_2]-anions2012

    • Author(s)
      M. Matsuo, S. Kuromoto, T. Sato, H. Oguchi, H. Takamura, S. Orimo
    • Journal Title

      Applied Physics Letters

      Volume: 100 Issue: 20

    • DOI

      10.1063/1.4716021

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sodium-ion conduction in complex hydrides NaAlH_4 and Na_3AlH_62012

    • Author(s)
      H.Oguchi, M.Matsuo, S.Kuromoto, H.Kuwano, S.Orimo
    • Journal Title

      Journal of Applied Physics

      Volume: Vol.113 Issue: 3

    • DOI

      10.1063/1.3681362

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium fast-ionic conduction in complex hydrides : Review and prospects2011

    • Author(s)
      M. Matsuo, S. Orimo
    • Journal Title

      Advanced Energy Materials

      Volume: 1 Issue: 2 Pages: 161-172

    • DOI

      10.1002/aenm.201000012

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fast-ionic conductivity of Li^+ in LiBH_42011

    • Author(s)
      T.Ikeshoji, E.Tsuchida, T.Morishita, K.Ikeda, M.Matsuo, Y.Kawazoe, S.Orimo
    • Journal Title

      Physical Review B

      Volume: Vol.83 Issue: 14

    • DOI

      10.1103/physrevb.83.144301

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Electrical Conductivities of Complex Hydrides Li<SUB>2</SUB>(BH<SUB>4</SUB>)(NH<SUB>2</SUB>) and Li<SUB>4</SUB>(BH<SUB>4</SUB>)(NH<SUB>2</SUB>)<SUB>3</SUB> by Melting2011

    • Author(s)
      Y.Zhou, M.Matsuo, Y.Miura, H.Takamura, H.Maekawa, A.Remhof, A.Borgschulte, A.Zuttel, T.Otomo, S.Orimo
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 52 Issue: 4 Pages: 654-657

    • DOI

      10.2320/matertrans.MA201003

    • NAID

      130004454669

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rotational motion in LiBH_4/LiI solid solutions2011

    • Author(s)
      P.Martelli, A.Remhof, A.Borgschulte, R.Ackermann, T.Strassle, J.P.Embs, M.Ernst, M.Matsuo, S.Orimo, A.Zuttel
    • Journal Title

      Journal of Physical Chemistry A

      Volume: Vol.115 Issue: 21 Pages: 329-5334

    • DOI

      10.1021/jp201372b

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Order and disorder in lithium tetrahydroborate2011

    • Author(s)
      S.K.Callear, E.A.Nickels, M.O.Jones, M.Matsuo, S.Orimo, P.P.Edwards, W.I.F.David
    • Journal Title

      Journal of Materials Science

      Volume: Vol.46 Pages: 566-569

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 錯体水素化物の新展開-リチウム高速イオン伝導材料として-2011

    • Author(s)
      松尾元彰, 折茂慎一
    • Journal Title

      未来材料

      Volume: Vol.11 Pages: 26-31

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Lithium fast-ionic conduction in complex hydrides : Review and prospects2011

    • Author(s)
      M.Matsuo, S.Orimo
    • Journal Title

      Advanced Energy Materials

      Volume: Vol.1 Pages: 161-172

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and lithium fast-ion conductivity of a new complex hydride Li_3(NH_2)_2I with double-layered structure2010

    • Author(s)
      M. Matsuo, T. Sato, Y. Miura, H. Oguchi, Y. Zhou, H. Maekawa, H. Takamura, S. Orimo
    • Journal Title

      Chemistry of Materials

      Volume: 22 Issue: 9 Pages: 2702-2704

    • DOI

      10.1021/cm1006857

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and lithium fast-ion conductivity of a new complex hydride Li_3(NH_2)_2I with double-layered structure2010

    • Author(s)
      M.Matsuo, T.Sato, Y.Miura, H.Oguchi, Y.Zhou, H.Maekawa, H.Takamura, S.Orimo
    • Journal Title

      Chemistry of Materials

      Volume: Vol.22 Pages: 2702-2704

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium-ion conduction in complex hydrides LiAlH_4 and Li_3AlH_62010

    • Author(s)
      H.Oguchi, M.Matsuo, T.Sato, H.Takamura, H.Maekawa, H.Kuwano, S.Orimo
    • Journal Title

      Journal of Applied Physics

      Volume: Vol.107

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anharmonicity in LiBH_4-LiI induced by anion exchange and temperature2010

    • Author(s)
      A.Borgschulte, R.Gremaud, S.Kato, N.P.Stadie, A.Remhof, A.Zuttel, M.Matsuo, S.Orimo
    • Journal Title

      Applied Physics Letters

      Volume: Vol.97

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Complex hydrides : a new category of solid-state lithium fast-ion conductors2010

    • Author(s)
      M.Matsuo, H.Oguchi, H.Maekawa, H.Takamura, S.Orimo
    • Journal Title

      Materials Matter

      Volume: Vol.5 Pages: 105-107

    • Related Report
      2010 Annual Research Report
  • [Presentation] Al-H系錯体水素化物のナトリウムイオン伝導2012

    • Author(s)
      大口裕之, 松尾元彰, 黒本晋吾, 桑野博喜, 折茂慎一
    • Organizer
      日本金属学会2012年春期大会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2012-03-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属|固体電解質界面でのイオンの挙動-Li|LiBH_4の第一原理分子動力学-2012

    • Author(s)
      池庄司民夫, 高木成幸, 松尾元彰, 川添良幸, 折茂慎一
    • Organizer
      日本金属学会2012年春期大会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Fast ionic conduction in complex hydrides2012

    • Author(s)
      M. Matsuo, S. Orimo
    • Organizer
      EMPA 6th Symposium Hydrogen and Energy
    • Place of Presentation
      Stoos, Switzerland
    • Year and Date
      2012-01-26
    • Related Report
      2011 Final Research Report
  • [Presentation] Fast ionic conduction in complex hydrides2012

    • Author(s)
      M.Matsuo, S.Orimo
    • Organizer
      EMPA 6th Symposium Hydrogen and Energy
    • Place of Presentation
      Seminar und Wellnesshotel(スイス)
    • Year and Date
      2012-01-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Hydride-based Li ion conductor for all solid-state lithium battery2011

    • Author(s)
      K.Takahashi, K.Hattori, T.Yamazaki, K.Takada, H.Takamura, M.Matsuo, S.Orimo, H.Maekawa
    • Organizer
      The 2nd International Symposium on Advanced Synthesis and Processing Technology for Materials
    • Place of Presentation
      高揚グランドホテル(仙台市)
    • Year and Date
      2011-12-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素化物固体電解質LiBH_4を用いた全固体リチウム二次電池の試作2011

    • Author(s)
      高橋邦彰, 服部和人, 山崎敏広, 高村仁, 折茂慎一, 松尾元彰, 高田和典, 前川英己
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄コンベンションセンター(宜野湾市)
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] LiBH_4における高Liイオン伝導機構とLi金属との界面挙動2011

    • Author(s)
      池庄司民夫, 土田英二, 森下徹也, 池田一貫, 松尾元彰, 川添良幸, 折茂慎一
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄コンベンションセンター(宜野湾市)
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] LiBH_4-LiI-RbI系固体電解質のリチウムイオン伝導とその機構2011

    • Author(s)
      熊谷直樹, 菅野公貴, 宮崎怜雄奈, 高村仁, 松尾元彰, 折茂慎一, 前川英己
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄コンベンションセンター(宜野湾市)
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] 岩塩型構造を有するLiBH_4のリチウムイオン伝導特性2011

    • Author(s)
      高村仁, 黒沼洋太, 松尾元彰, 折茂慎一, 前川英己
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄コンベンションセンター(宜野湾市)
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] B-H系およびN-H系錯体水素化物でのナトリウムイオン伝導2011

    • Author(s)
      黒本晋吾, 松尾元彰, 折茂慎一, 大口裕之, 前川英己, 高村仁
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄コンベンションセンター(宜野湾市)
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] LiNH_2-LiI系錯体水素化物でのリチウム高速イオン伝導2011

    • Author(s)
      斉藤郁彦, 平田匠弥, 松尾元彰, 折茂慎一, 佐藤豊人, 大口裕之, 前川英己, 高村仁
    • Organizer
      日本金属学会2011年秋期大会
    • Place of Presentation
      沖縄コンベンションセンター(宜野湾市)
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] 錯体水素化物のリチウム高速イオン伝導機能2011

    • Author(s)
      松尾元彰, 折茂慎一
    • Organizer
      第9回水素量子アトミクス研究会
    • Place of Presentation
      東北大学金属材料研究所(仙台市)
    • Year and Date
      2011-08-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Lithium fast-ion conductivities in complex hydrides2010

    • Author(s)
      S.Orimo, M.Matsuo, H.Oguchi, H.Maekawa, H.Takamura, T.Vegge, A.Eemhof, A.Borgschulte, A.Zuttel
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawaii convention center (アメリカ)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高圧下におけるハライド添加LiBH_4のリチウムイオン伝導特性2010

    • Author(s)
      黒沼洋太, 松尾元彰, 折茂慎一, 前川英己, 高村仁
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ(仙台市)
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] LiBH_4の高いイオン伝導性の起源2010

    • Author(s)
      池庄司民夫, 土田英二, 森下徹也, 池田一貴, 松尾元彰, 川添良幸, 折茂慎一
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ(仙台市)
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 超イオン伝導体LiBH_4におけるリチウムイオンの移動経路2010

    • Author(s)
      池庄司民夫, 土田英二, 池田一貴, 松尾元彰, 川添良幸, 折茂慎一
    • Organizer
      第51回電池討論会
    • Place of Presentation
      愛知県産業労働センター(名古屋市)
    • Year and Date
      2010-11-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規錯体水素化物Li_3N_2H_4Iの結晶構造とリチウム高速イオン伝導2010

    • Author(s)
      松尾元彰, 周宇, 黒本晋吾, 折茂慎一, 佐藤豊人, 大口裕之, 前川英己, 高村仁
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Lithium ion conduction in double-anion complex hydrides before and after melting2010

    • Author(s)
      周宇, 松尾元彰, 大口裕之, 折茂慎一, 前川英己, 高村仁
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] LiBH_4の高温相におけるリチウムイオン伝導機構のRMC解析2010

    • Author(s)
      宮崎怜雄奈, 及川格, 高村仁, 前川英己, 松尾元彰, 折茂慎一, Laszlo Temleitner, 尾原幸治, 川北至信
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高速リチウムイオン伝導体の活性化体積2010

    • Author(s)
      黒沼洋太, 前川英己, 高村仁, 松尾元彰, 折茂慎一
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] LiNH_2-LiI系錯体水素化物のリチウム高速イオン伝導2010

    • Author(s)
      黒本晋吾, 周宇, 松尾元彰, 折茂慎一, 佐藤豊人, 大口裕之, 前川英己, 高村仁
    • Organizer
      日本金属学会2010年秋期大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Lithium fast-ionic conduction in LiBH_4 and its derivatives2010

    • Author(s)
      M.Matsuo, S.Orimo
    • Organizer
      CIMTEC2010 5th Forum on New Materials
    • Place of Presentation
      Montecatini Terme(イタリア)
    • Year and Date
      2010-06-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Microwave absorption and lithium super-ionic conduction in lithium borohydride LiBH_42010

    • Author(s)
      M. Matsuo, S. Orimo
    • Organizer
      CIMTEC2010 5th Forum on New Materials
    • Place of Presentation
      Montecatini Terme, Italy(invited)
    • Year and Date
      2010-06-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Microwave absorption and lithium super-ionic conduction in lithium borohydride LiBH_42010

    • Author(s)
      M.Matsuo, S.Orimo
    • Organizer
      CIMTEC2010 5th Forum on New Materials
    • Place of Presentation
      Montecatini Terme(イタリア)
    • Year and Date
      2010-06-15
    • Related Report
      2010 Annual Research Report
  • [Remarks] 報道関連情報(1)「室温で高速ナトリウムイオン電導」化学工業日報(2012年5月17日)

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/

    • Related Report
      2011 Final Research Report
  • [Remarks] (2)「全固体電池材料を開発」日経産業新聞(2012年5月25日)など

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/

    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] ナトリウムイオン伝導体2012

    • Inventor(s)
      折茂慎一, 松尾元彰, 黒本晋吾, 佐藤豊人, 大口弘之, 前川英己, 高村仁
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-032575
    • Filing Date
      2012-02-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Patent(Industrial Property Rights)] 個体電気二重層キャパシタ2012

    • Inventor(s)
      池庄司民夫, 松尾元彰, 折茂慎一, 大谷実, 土田英二
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2012-057714
    • Filing Date
      2012-03-14
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 固体電解質、その製造方法、および固体電解質を備える二次電池2010

    • Inventor(s)
      前川英己, 高村仁, 折茂慎一, 松尾元彰, 中森裕子, 安東真理子, 野田泰斗, 唐橋大樹
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2010-511984
    • Filing Date
      2010-10-28
    • Related Report
      2011 Final Research Report 2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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