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Development of Organic Ferromagnets Based on Transition Metal Phthalocyanines

Research Project

Project/Area Number 22760531
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionSaitama University

Principal Investigator

HONDA Zentaro  埼玉大学, 大学院・理工学研究科, 准教授 (30332563)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords有機磁性体 / フタロシアニン / 機能材料 / 有機磁性 / 高キュリー温度 / 分子磁性体 / 室温強磁 / 室温強磁性
Research Abstract

A series of organic ferromagnetic materials based on transition metal phthalocyanines (MPcs) doped by alkaline metals are synthesized and the magnetic properties and the crystal structures are investigated. All the samples of MPc, where M=Mn, Fe, Co, Ni, doped by sodium or potassium, show ferromagnetic behavior at room temperature. X-ray diffraction patterns and transmission electron microscopy images suggest that the MPc molecules form three-dimensional random networks in the alkaline metal doped MPc samples. Three-dimensional ferromagnetic interactions between transition metal ions in connected MPc molecules via delocalized π-electrons are proposed to explain the high Curie temperature well above room temperature. We also synthesized the MPc polymers and studied its structure and magnetic properties. Ferromagnetic behavior is also observed in the magnetization measurements at room temperature. These experimental results could be a clue to finding high Curie temperature ferromagnetism in organic materials.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (48 results)

All 2013 2012 2011 2010 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (30 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] High-field magnetization of the S =1/2 two-leg spin-ladder antiferromagnets CuAX2 (A=diazine,X=halogen)2013

    • Author(s)
      M. Ikeda, Z. Honda, M. Sakai, S. Kimura, K. Okunishi, M. Hagiwara
    • Journal Title

      Journal of Low Temperature Physics

      Volume: 170 Issue: 5-6 Pages: 296-301

    • DOI

      10.1007/s10909-012-0809-y

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal growth of magnetic dihydride GdxY1-xH2 for generation of spin current2013

    • Author(s)
      T. Sakuraba, H. Hirama, M. Sakai, Z. Honda, M. Hayakawa, T. Okoshi, A. Kitajima, A. Oshima, K. Higuchi, S. Hasegawa
    • Journal Title

      Journal of Crystal Growth

      Volume: 未定 Pages: 351-355

    • DOI

      10.1016/j.jcrysgro.2012.12.156

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Field-Induced Phase Transitions in the S=1/2 Two-Leg Spin-Ladder Material Cu(DEP)Br_22012

    • Author(s)
      Z. Honda, H. A. Katori, M. Ikeda, M.Hagiwara,K. Okunishi, M. Sakai, T. Fukuda, N. Kamata
    • Journal Title

      JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN

      Volume: 81

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Field Magnetization of the S=1/2 Two-Leg Spin-Ladder Antiferromagnets CuAX_2 (A=Diazine, X=Halogen)2012

    • Author(s)
      M. Ikeda, Z. Honda, M. Sakai, S. Kimura, K. Okunishi, M. Hagiwara
    • Journal Title

      JOURNAL OF LOW TEMPERATURE PHYSICS

      Volume: 170 Pages: 296-301

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties of the S=2 Heisenberg Antiferromagnetic Chain Compound MnCl_3(bpy)2012

    • Author(s)
      M. Hagiwara, Y. Idutsu, Z. Honda, and S.Yamamoto
    • Journal Title

      JOURNAL OF PHYSICS: Conf. Ser

      Volume: 400

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferrimagnetic spin-1/2 chain of alternating Ising and Heisenberg spins in arbitrarily oriented magnetic field2012

    • Author(s)
      J. Strecka, M. Hagiwara, Y. Han, T.Kida, Z. Honda, M. Ikeda
    • Journal Title

      Condensed Matter Physics

      Volume: 15

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic field-induced phase transitions in the S=1/2 two-leg spin-ladder material Cu(DEP)Br22012

    • Author(s)
      Z. Honda, H.A. Katori, M. Ikeda, M. Hagiwara, K. Okunishi, M. Sakai, T. Fukuda, N. Kamata
    • Journal Title

      Journal of Physical Society of Japan

      Volume: 81 Issue: 11 Pages: 113710-4

    • DOI

      10.1143/jpsj.81.113710

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties of the S=2 Heisenberg Antiferromagnetic Chain Compound MnCl3(bpy)2012

    • Author(s)
      M. Hagiwara, Y. Idutsu, Z. Honda, and S. Yamamoto
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 400 Issue: 3 Pages: 032014-032014

    • DOI

      10.1088/1742-6596/400/3/032014

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Negative Magnetoresistance Generated by Combination of Spin-Orbit Interaction and Applied Magnetic Field2012

    • Author(s)
      Sakai, M; Kodama, D; Sakuraba, T; Honda, Z; Hasegawa, S; Kitajima, A; Oshima, A; Higuchi, K;Nakamuray, O
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 51 Issue: 2R Pages: 023001-023001

    • DOI

      10.1143/jjap.51.023001

    • NAID

      210000140138

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved Optical Degradation Characteristics of Eu Complex Encapsulated byHigh-Pressure Annealing2011

    • Author(s)
      S. Kato, T. Fukuda, S. Akiyama, Z.Honda, N. Kamata, N. Kijima
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 50

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface morphology of fluorene thin film fabricated by electrospray deposition technique using two organic solvents : Application for organic light-emitting diodes2011

    • Author(s)
      Fukuda, T; Asaki, H; Asano, T; Takagi, K; Honda, Z; Kamata, N; Ju, JM; Yamagata, Y
    • Journal Title

      THIN SOLID FILMS

      Volume: 520 Issue: 1 Pages: 600-605

    • DOI

      10.1016/j.tsf.2011.07.048

    • NAID

      120006386276

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Generation of Spin Current in BipolarConductors2011

    • Author(s)
      M. Sakai, T. Sakuraba, Z. Honda, S. Hasegawa, A. Kitajima, K.Higuchi, A. Oshima, and O.Nakamura
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 50 Issue: 10R Pages: 103002-103002

    • DOI

      10.1143/jjap.50.103002

    • NAID

      40019043750

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bulk heterojunction organic photovoltaic cell fabricated by the electrospray deposition method using mixed organic solvent2011

    • Author(s)
      Fukuda, T; Takagi, K; Asano, T; Honda, Z; Kamata, N; Ueno, K; Shirai, H; Ju, J; Yamagata, Y; Tajima, Y
    • Journal Title

      PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS

      Volume: 5 Issue: 7 Pages: 229-231

    • DOI

      10.1002/pssr.201105232

    • NAID

      120006386274

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New high magnetic field phase of the frustrated S=1/2 chain compound LiCuVO42011

    • Author(s)
      L.E.Svistov, T.Fujita, H.Yamaguchi, S.Kimura, K.Omura, A.Prokofiev, A.I.Smirnov, Z.Honda, M.Hagiwara
    • Journal Title

      JETP LETTERS

      Volume: 93 Pages: 21-25

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved Optical Degradation Characteristics of Eu Complex Encapsulated by High-Pressure Annealing2011

    • Author(s)
      S.Kato, T.Fukuda, S.Akiyama, Z.Honda, N.Kamata, N.Kijima
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 50

    • NAID

      210000138335

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation]2013

    • Author(s)
      本多善太郎,吉田賢広,小原充瑛,武藤祐太,萩原政幸,木田孝則,酒井政道,福田武司,鎌田憲彦
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2013-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation]2012

    • Author(s)
      本多善太郎,小原充瑛,武藤祐太,吉田賢広,萩原政幸,木田孝則,酒井政道,福田武司,鎌田憲彦
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-13
    • Related Report
      2012 Final Research Report
  • [Presentation]2012

    • Author(s)
      本多善太郎,坪谷和彦,萩原政幸,木田孝則,酒井政道,福田武司,鎌田憲彦
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-18
    • Related Report
      2012 Final Research Report
  • [Presentation] マンガンフタロシアニン重合体における室温強磁性2012

    • Author(s)
      本多善太郎, 坪谷和彦, 萩原政幸, 木田孝則, 酒井政道, 福田武司, 鎌田憲彦
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素吸蔵体Y_<1-x>Gd_xH_2(x=0.19)の作製と磁化・ホール測定2012

    • Author(s)
      平間弘晃, 桜庭琢士, 酒井政道, 本多善太郎, 早川昌志, 大越朋哉, 長谷川繁彦, 北島彰, 大島明博, 中村修, 樋口宏二
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation]2011

    • Author(s)
      本多善太郎,福田武司,鎌田憲彦,香取浩子,萩原政幸
    • Organizer
      2011日本物理学会秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 弱く結合した1次元磁性体Cu(diazine)X2,(X=Cl,Br)の磁性2011

    • Author(s)
      本多善太郎, 福田武司, 鎌田憲彦, 香取浩子, 萩原政幸
    • Organizer
      2011日本物理学会秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation]2011

    • Author(s)
      大原和也,岩崎惇,本多善太郎,鎌田憲彦,福田武司
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] 酸素分子を吸着した金属フタロシアニンの磁性2011

    • Author(s)
      大原和也, 岩崎惇, 本多善太郎, 鎌田憲彦, 福田武司
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] CuFeTe2系酸素吸蔵物質の磁性2011

    • Author(s)
      若井拓郎, 江口修太, 本多善太郎, 福田武司, 鎌田憲彦
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] ガドリニウム二水素化物GdHx(x≒2)の磁化測定2011

    • Author(s)
      桜庭琢士, 酒井政道, 本多善太郎, 早川昌志, 大越朋哉, 長谷川繁彦, 北島彰, 大島明博, 樋口宏二, 中村修
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-09-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] ポリフルオレンを用いた有機光電変換素子へのエチルカルバゾール置換したシロール誘導体の添加効果2011

    • Author(s)
      木村翔, 福田武司, 本多善太郎, 鎌田憲彦, 森桂太, 幡野健
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] アセトニトリル・テトラリンを共添加した静電塗布法によるPCBM薄膜の表面平坦化2011

    • Author(s)
      浅野俊, 高木健次, 福田武司, 朱正明, 本多善太郎, 鎌田憲彦, 田島右副, 山形豊
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] 混合溶媒を用いた静電塗布法による有機薄膜の表面平坦化と有機ELへの応用2011

    • Author(s)
      福田武司, 浅木裕隆, 浅野俊, 高木健次, 本多善太郎, 鎌田憲彦, 青山哲也, 朱正明, 山形豊
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation]2011

    • Author(s)
      岩崎惇,松島康介,大原和也,本多善太郎,香取浩子,鎌田憲彦,福田武司
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation]2011

    • Author(s)
      坪谷和彦、花田みなみ、本多善太郎、鎌田憲彦、福田武司、香取浩子、萩原政幸
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 遷移金属フタロシアニンポリマーの磁気特性2011

    • Author(s)
      坪谷和彦、花田みなみ、本多善太郎、鎌田憲彦、福田武司、香取浩子、萩原政幸
    • Organizer
      応用物理学会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルカリ金属ドープ遷移金属フタロシアニンの磁気特性2011

    • Author(s)
      岩崎惇, 松島康介, 大原和也, 本多善太郎, 香取浩子, 鎌田憲彦, 福田武司
    • Organizer
      応用物理学会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation]2010

    • Author(s)
      本多善太郎,香取浩子,萩原政幸,福田武司,鎌田憲彦
    • Organizer
      2010日本物理学会秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-24
    • Related Report
      2012 Final Research Report
  • [Presentation] コバルトカゴメ格子磁性体Co(N_3)_2(bpg)の相転移2010

    • Author(s)
      本多善太郎, 香取浩子, 萩原政幸, 福田武司, 鎌田憲彦
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-24
    • Related Report
      2010 Annual Research Report
  • [Presentation]2010

    • Author(s)
      岩崎惇,松島康介,花田みなみ,大原和也,本多善太郎,香取浩子,鎌田憲彦,福田武司
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学
    • Year and Date
      2010-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation]2010

    • Author(s)
      松島康介,岩崎惇,大原和也,花田みなみ,本多善太郎,香取浩子,鎌田憲彦,福田武司
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学
    • Year and Date
      2010-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 遷移金属フタロシアニンへのカリウムドープに伴う磁気特性の向上に関する研究2010

    • Author(s)
      岩崎惇, 松島康介, 花田みなみ, 大原和也, 本多善太郎, 香取浩子, 鎌田憲彦, 福田武司
    • Organizer
      応用物理学会
    • Place of Presentation
      長崎大学
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルミニウムフタロシアニンラジカルの磁気特性2010

    • Author(s)
      松島康介, 岩崎惇, 大原和也, 花田みなみ, 本多善太郎, 香取浩子, 鎌田憲彦, 福田武司
    • Organizer
      応用物理学会
    • Place of Presentation
      長崎大学
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 遷移金属フタロシアニン重合体における秩序磁性

    • Author(s)
      本多善太郎,小原充瑛,武藤祐太,吉田賢広,萩原政幸,木田孝則,酒井政道,福田武司,鎌田憲彦
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 遷移金属フタロシアニン重合体における秩序磁性II

    • Author(s)
      本多善太郎,吉田賢広,小原充瑛,武藤祐太,萩原政幸,木田孝則,酒井政道,福田武司,鎌田憲彦
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Gd-Y合金二水素化物GdxY1-xH2(0≦x≦1)の磁化測定

    • Author(s)
      桜庭琢士,酒井政道,本多善太郎,平間弘晃,大越朋哉,長谷川繁彦,北島彰,大島明博,樋口宏二
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 静電塗布法による有機薄膜太陽電池へのPCBMバッファ層の挿入効果

    • Author(s)
      福田武司,高木健次,Yingjie Liao,鎌田憲彦,本多善太郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 再沈法を用いた水分散フタロシアニンコロイドの作製

    • Author(s)
      福田武司,秋山真之介,鎌田憲彦,伊瀬谷隆弘,石丸雄大,本多善太郎,松鷹宏,田島右副
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 静電塗布法で噴霧した有機溶媒液滴の帯電量評価

    • Author(s)
      鈴木あすみ,福田武司,鎌田憲彦,本多善太郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.fms.saitama-u.ac.jp/lab/honda/

    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] フタロシアニン重合体およびその製造方法2013

    • Inventor(s)
      本多善太郎
    • Industrial Property Rights Holder
      本多善太郎
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-01-18
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] フタロシアニン重合体およびその製造方法2012

    • Inventor(s)
      本多善太郎、萩原政幸
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      2013-029405
    • Filing Date
      2012-01-18
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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