Synthesis of Anion Conductive Polymers Bearing High Carrier Concentrations and Their Fuel Cell Application

• Project/Area Number: 22760536
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Structural/Functional materials
• Research Institution: Tokyo Metropolitan University
• Principal Investigator: TANAKA Manabu 首都大学東京, 都市環境科学研究科, 助教 (00531831)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
• Keywords: 機能性高分子材料 / 高分子電解質 / アニオン伝導 / 燃料電池 / アイオノマー / イオン導電率 / アンモニオ基 / ポリエーテルスルホン / フルオレニル基

Research Abstract

Novel anion conductive polymer electrolytes bearing high carrier concentrations were synthesized to achieve the construction of effective anion transport pathway. Obtained electrolyte membranes showed good chemical, mechanical, and thermal stabilities. The novel block polymer membranes possessed distinguished anion conductivities and cell performances, which promise their potential application to future alkaline fuel cells.

Research Products

• [Journal Article] Durability of sulfonated polyimide membrane in humidity cycling for fuel cell applications (2012)
  • Author(s): K.Miyatakea, H.Furuya, M.Tanaka, M.Watanabe
  • Journal Title: Journal of Power Sources Volume: 204 Pages: 74-78
  • Peer Reviewed
• [Journal Article] Anion Conductive Block Poly(arylene ether) s : Synthesis, Properties, and Application in Alkaline Fuel Cells (2011)
  • Author(s): Manabu Tanaka, Keita Fukasawa, Eriko Nishino, Susumu Yamaguchi, Koji Yamada, Hirohisa Tanaka, Byungchan Bae, Kenji Miyatake, Masahiro Watanabe
  • Journal Title: Journal of the American Chemical Society Volume: 133 Pages: 10646-10654
• [Journal Article] Synthesis and properties of anion conductive ionomers containing fluorenyl groups for alkaline fuel cell applications (2011)
  • Author(s): Manabu Tanaka, Masaki Koike, Kenji Miyatake, Masahiro Watanabe
  • Journal Title: Polymer Chemistry Volume: 2 Pages: 99-106
• [Journal Article] Anion Conductive Block Poly(arylene ether)s : Synthesis, Properties, and Application in Alkaline Fuel Cells (2011)
  • Author(s): M.Tanaka, K.Fukasawa, E.Nishino, S.Yamaguchi, K.Yamada, H.Tanaka, B.Bae, K.Miyatake, M.Watanabe
  • Journal Title: Journal of the American Chemical Society Volume: 133 Issue: 27 Pages: 10646-10654
  • DOI: 10.1021/ja204166e
  • Peer Reviewed
• [Journal Article] Synthesis and Properties of Anion Conductive Ionomers Containing Fluorenyl Groups for Alkaline Fuel Cell Applications (2011)
  • Author(s): M.Tanaka, M.Koike, K.Miyatake, M.Watanabe
  • Journal Title: Polymer Chemistry Volume: 2 Pages: 99-106
  • Peer Reviewed
• [Journal Article] Anion Conductive Aromatic Ionomers Containing Fluorenyl Groups (2010)
  • Author(s): Manabu Tanaka, Masaki Koike, Kenji Miyatake, Masahiro Watanabe
  • Journal Title: Macromolecules Volume: 43 Pages: 2657-2659
• [Presentation] ブロック/グラフト構造を有するスルホン化ポリイミド電解質膜の作製と特性評価 (2011)
  • Author(s): 田中学, 山崎浩太, 川上浩良
  • Organizer: 第52回電池討論会
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2011-10-17
• [Presentation] ブロック/グラフト構造を有するスルホン化ポリイミドの合成と電解質膜特性評価 (2011)
  • Author(s): 田中学, 山崎浩太, 川上浩良
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-28
• [Presentation] 燃料電池応用を目指したスルホン化ポリイミドナノファイバーの作製と評価 (2011)
  • Author(s): 田中学, 竹森諒平, 川上浩良
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: 大阪国際会議場
  • Year and Date: 2011-05-26
• [Presentation] 新規なアニオン交換型芳香族ブロック共重合体膜の合成と物性解析 (2011)
  • Author(s): 深澤啓太,田中学,西野英理子,山口進,山田浩次,田中裕久,裴柄贊,宮武健治,渡辺政廣
  • Organizer: 電気化学会第78回大会
  • Place of Presentation: 横浜国立大学
  • Year and Date: 2011-03-30
• [Presentation] Anion Conductive Aromatic Ionomers Containing Fluorene Groups For Alkaline Fuel Cell Applications (2010)
  • Author(s): Manabu Tanaka, Masaki Koike, Keita Fukasawa, Kenji Miyatake, and Masahiro Watanabe
  • Organizer: 218th ECS Meeting, ECS Preprint
  • Place of Presentation: Las Vegas, USA
  • Year and Date: 2010-10-14
• [Presentation] Anion Conductive Aromatic Ionomers Containing Fluorene Groups For Alkaline Fuel Cell Applications (2010)
  • Author(s): M.Tanaka, M.Koike, K.Fukasawa, K.Miyatake, M.Watanabe
  • Organizer: 218th ECS Meeting
  • Place of Presentation: アメリカ、ラスベガス
  • Year and Date: 2010-10-14
• [Presentation] アンモニオ基を有するアニオン導電性芳香族ポリエーテル電解質膜 (2010)
  • Author(s): 田中学,小池将貴,深澤啓太,宮武健治,渡辺政廣
  • Organizer: 第59回高分子学会討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-17
• [Presentation] アンモニオ基を有するアニオン導電性芳香族ポリエーテル電解質膜 (2010)
  • Author(s): 田中学, 小池将貴, 深澤啓太, 宮武健治, 渡辺政廣
  • Organizer: 第59回高分子学会討論会
  • Place of Presentation: 北海道、札幌
  • Year and Date: 2010-09-17
• [Remarks]
  • URL: http://www.comp.tmu.ac.jp/m-tanaka/index.html
• [Remarks]
  • URL: http://www.comp.tmu.ac.jp/m-tanaka/index.html
• [Patent(Industrial Property Rights)] 陰イオン交換樹脂、および該陰イオン交換樹脂を含む燃料電池 (2010)
  • Inventor(s): 渡辺政廣、宮武健治、田中学、松野宗一
  • Industrial Property Rights Holder: 山梨大学、カネカ
  • Filing Date: 2010-11-29
  • Overseas
• [Patent(Industrial Property Rights)] 陰イオン交換樹脂、および該陰イオン交換樹脂を含む燃料電池 (2010)
  • Inventor(s): 渡辺政廣、宮武健治、田中学、松野宗一
  • Industrial Property Rights Holder: 山梨大学、カネカ
  • Industrial Property Number: 2010-028599
  • Filing Date: 2010-02-12
• [Patent(Industrial Property Rights)] Anion-Exchange Resin and Fuel Cell Containing the Anion-Exchange resin (2010)
  • Inventor(s): 渡辺政廣, 宮武健治, 田中学, 松野宗一
  • Industrial Property Rights Holder: 山梨大学、(株)カネカ
  • Filing Date: 2010-11-29
  • Acquisition Date: 2011-08-18
  • Overseas