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Controlling the size and quantity of defects on carbon materials

Research Project

Project/Area Number 22760594
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionChiba University

Principal Investigator

YAMADA Yasuhiro  千葉大学, 大学院・工学研究科, 助教 (90546780)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords炭素材料 / グラフェン / 欠陥 / カーボンナノチューブ / フラーレン / 制御 / 酸素 / エポキシ化 / 黒鉛 / ナノカーボン
Research Abstract

Vacancy defects were introduced by oxidizing nanocarbon materials with oxygen and m-chloroperoxybenzoic acid, followed by heat treatment. To control the size of the vacancy defect, the defect structure was analyzed in detail by transmission electron microscope, X-ray photoelectron spectroscopy, and density functional theory's calculation. As a result, oxidation by oxygen proceeds even below 250 degree C, and carbon monoxide and carbon dioxide and vacancy defects were formed via carbonyl and lactone groups. By epoxidization of fullerene, epoxy, carbonyl, and lactone groups were formed. The amount of epoxy and lactone groups were reduced, and carbonyl and carbone were remained. Vacancy defects were observed using transmission electron microscope, but the proof that the vacancy defects were created by heat treatment is necessary in the future.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (5 results)

All 2011 2010 Other

All Presentation (4 results) Remarks (1 results)

  • [Presentation] Introducing defects on fullerene through epoxidation2011

    • Author(s)
      J. Kim, Y. Yamada, T. Sodesawa, S. Sato
    • Organizer
      Carbon 2011, East China University of Science andTechnology, Shanghai
    • Place of Presentation
      China
    • Year and Date
      2011-07-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Introducing defects on fullerene through epoxidation2011

    • Author(s)
      Jungpil Kim
    • Organizer
      Annual carbon conference (Carbon2011)
    • Place of Presentation
      East China University of Science and Technology(中国)
    • Year and Date
      2011-07-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] ナノカーボンにおける欠陥制御、3C072010

    • Author(s)
      室田和成, 山田泰弘, 袖澤利昭, 佐藤智司
    • Organizer
      第37回炭素材料学会年、姫路
    • Place of Presentation
      姫路市市民会館
    • Year and Date
      2010-12-03
    • Related Report
      2011 Final Research Report
  • [Presentation] ナノカーボンにおける欠陥制御2010

    • Author(s)
      室田和成、山田泰弘, 他2名
    • Organizer
      炭素材料学会年会
    • Place of Presentation
      姫路、姫路市市民会館
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://chem.tf.chiba-u.jp/~y-yamada/index.htm

    • Related Report
      2011 Final Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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