Study on reactivity of the metal nanoparticles encapsulated in structurally designed hollow carbon sphere
| Project/Area Number |
22760597
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Osaka University |
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Principal Investigator |
HARADA Takashi 大阪大学, 太陽エネルギー化学研究センター, 技術職員 (00379314)
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 触媒調製化学 / コア-シェル構造体 / 触媒 / ナノ材料 / コア-シェル / パラジウム / 多孔性カーボン / ニッケル / 一酸化炭素のメタン化 / 水素化反応 / アルコール酸化反応 / 不均一触媒 / ナノ粒子 / 再利用 |
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| Research Abstract |
Core-hollow shell nanocomposites are expected as the facile structure of heterogeneous catalyst because they can stably immobilized metal nanoparticles inside the shell. In this work, preparations of core-hollow shell structure encapsulating palladium or nickel nanoparticles and effect of the core-hollow shell structure on the catalytic properties were investigated. As a result, core-hollow shell structure provided high thermal stability of metal nanoparticles toward coalescence and/ or aggregation due to the physical isolation of each metal nanoparticle from neighboring nanoparticles. Core-hollow shell nanocomposites with smaller pore volume showed lower catalytic activity because of the inhibition of mass transfer.
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Report
(3 results)
Research Products
(15 results)
