| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Research Abstract |
In order to demonstrate the enhancement in the chemical reaction caused by the" nonequilibrium local heating", we have constructed a heterogeneous catalytic reaction system containing the ferromagnetic metal particle catalysts such as Ni.
First, we have successfully prepared face-centered cubic(fcc) Ni nanoparticles having long-chain amine ligands within an extremely short time under microwave irradiation. The particle sizes were controlled using several long-chain amine ligands.
We have demonstrated the enhancement in the C-C coupling reaction caused by the" nonequilibrium local heating" of the surface of the Ni particles under microwave irradiation. Dispersed ferromagnetic particles should act as a catalyst and provide with their surface as a reaction field.
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