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Clarification of reaction behavior in effective cellulose hydrolysis by novel vapor catalyst method

Research Project

Project/Area Number 22760600
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionKochi University

Principal Investigator

ONDA Ayumu  高知大学, 教育研究部・総合科学系, 助教 (80335918)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsセルロース / グルコース / 触媒 / 再生可能資源 / バイオマス / 水蒸気 / 化学変換 / 加水分解 / 水熱 / 非食用バイオマス
Research Abstract

The novel vapor method gave 40 C-% yield of glucose in hydrolysis of crystalline cellulose. Investigation of effects of crystallinity of polysaccharides on the hydrolysis revealed that the vapor method is significantly effective for the hydrolysis of crystalline polysaccharides. The catalytic effect of various molecules was examined as vapor catalyst. Formic acid accelerated the yield of glucose, whereas acetic acid and methanol inhibited the reaction, and it was suggested that the molecular size and polarity have affected the catalyst activity.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (18 results)

All 2012 2011 2010

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (9 results) Book (1 results)

  • [Journal Article] Selective Hydrolysis of Cellulose and Polysaccharides into Sugars by Catalytic Hydrothermal Method Using Sulfonated Activated-carbon2012

    • Author(s)
      A. Onda
    • Journal Title

      J. Jpn, Petroleum Inst

      Volume: 55 Pages: 73-86

    • NAID

      10030934578

    • Related Report
      2011 Final Research Report
  • [Journal Article] Solvothermal One-Step Synthesis and Effect of Carbon on Properties of Ruthenium Sulfide Catalysts2011

    • Author(s)
      Zhang, C., Yanagisawa, K., Tao, H., Onda, A., Shou, T., Kamiya, S
    • Journal Title

      Catal. Lett

      Volume: 141 Pages: 1311-1315

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide2011

    • Author(s)
      Kozawa, T., Onda, A., Yanagisawa, K., Kishi, A., Masuda, Y.
    • Journal Title

      J. Solid State Chem

      Volume: 184 Pages: 589-596

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective synthesis of 1-butanol from ethanol over strontium phosphate hydroxyapatite catalysts2011

    • Author(s)
      Ogo, S., Onda, A., Yanagisawa, K
    • Journal Title

      Appl. Catal. A

      Volume: 102 Pages: 188-195

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective synthesis of 1-butanol from ethanol over strontium phosphate hydroxyapatite catalysts2011

    • Author(s)
      S.Ogo, A.Onda, K.Yanagisawa
    • Journal Title

      Appl.Catal.A

      Volume: 402 Pages: 188-195

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of water vapor on the thermal decomposition process of zinchydroxide chloride and crystal growth of zinc oxide2011

    • Author(s)
      T.Kozawa, A.Onda, K.Yanagisawa, A.Kishi, Y.Masuda
    • Journal Title

      J.Solid State Chem.

      Volume: 184 Pages: 589-596

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvothermal One-Step Synthesis and Effect of Carbon on Properties of Ruthenium Sulfide Catalysts2011

    • Author(s)
      Chuanxiang Zhang, Kazumichi Yanagisawa, Haijun Tao, Aymu Onda, Tatsuo Shou, Sumio Kamiya
    • Journal Title

      Catal Lett

      Volume: 141 Pages: 1311-1315

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New direct production of gluconic acid from polysaccharides using a bifunctional catalyst in hot water2011

    • Author(s)
      Ayumu Onda, Takafumi Ochi, Kazumichi Yanagisawa
    • Journal Title

      Catalysis Communications

      Volume: 12 Pages: 421-425

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 触媒による多糖類バイオマスの分解反応2011

    • Author(s)
      恩田歩武
    • Organizer
      第8回バイオマス変換触媒セミナー
    • Place of Presentation
      高知
    • Year and Date
      2011-07-01
    • Related Report
      2011 Final Research Report
  • [Presentation] 触媒による多糖類バイオマスの分解反応2011

    • Author(s)
      恩田歩武
    • Organizer
      第8回バイオマス変換触媒セミナー
    • Place of Presentation
      高知大学(招待講演)
    • Year and Date
      2011-07-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] バイオマスおよびバイオマス由来化合物の化学変換プロセスの開発2011

    • Author(s)
      恩田歩武
    • Organizer
      新化学発展協会ライフサイエンス部会講演会
    • Place of Presentation
      新化学発展協会(東京)
    • Year and Date
      2011-01-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水蒸気法によるセルロースからグルコースへの選択的加水分解2011

    • Author(s)
      飯田祐己,恩田歩武,柳澤和道
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見
    • Related Report
      2011 Final Research Report
  • [Presentation] 水蒸気法によるセルロースからグルコースへの選択的加水分解2011

    • Author(s)
      飯田祐己, 恩田歩武, 柳澤和道
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Related Report
      2011 Annual Research Report
  • [Presentation] セルロースからグルコースへの加水分解に対する水蒸気の効果2010

    • Author(s)
      飯田祐己,恩田歩武,木下晶太,柳澤和道
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府
    • Related Report
      2011 Final Research Report
  • [Presentation] Selective Hydrolysis of Seaweed Including Carrageenan into Galactose under Hydrothermal Conditions2010

    • Author(s)
      A.Onda, K.Morizane, K.Yanagisawa, M.Tsuda, M.Hiraoka, S.Nagata, K.Ohnishi
    • Organizer
      The 2nd International Solvothermal & Hydrothermal Assosciation (ISHA2010)
    • Place of Presentation
      Beijing北京国際交流センター(中国)
    • Related Report
      2010 Annual Research Report
  • [Presentation] セルロースからグルコースへの加水分解に対する水蒸気の効果2010

    • Author(s)
      飯田祐己, 恩田歩武, 木下晶太, 柳澤和道
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学(甲府)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水熱法による海藻(キリンサイ)のモノマー化2010

    • Author(s)
      恩田歩武, 森實慧, 柳沢和道, 津田正史, 平岡雅規
    • Organizer
      第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場(兵庫県)
    • Related Report
      2010 Annual Research Report
  • [Book] スルホン化活性炭, 触媒調製ハンドブック2011

    • Author(s)
      恩田歩武, 炭素固体酸
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2011 Final Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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