Study on the reactions of the radicals from water radiolysis at the interface between water and solid oxides
Project/Area Number |
22760677
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Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Single-year Grants |
Research Field |
Nuclear engineering
|
Research Institution | Japan Atomic Energy Agency |
Principal Investigator |
KUMAGAI Yuta 独立行政法人日本原子力研究開発機構, 原子力基礎工学研究部門, 研究員 (70455294)
|
Project Period (FY) |
2010 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
Keywords | 同位体・放射線化学 / 界面反応 / 放射線効果 / 水溶液 / シリカ / 海水 / ゼオライト / OHラジカル / 水和電子 / 水素 / クロム |
Research Abstract |
The effects of solid ceramic oxides on the radiation-induced reactions in aqueous solutions were studied. The reduction of dichromate ion in the presence of silica gel and the production of hydrogen and hydrogen peroxide in the presence of zeolites were investigated using-radiolysis technique. Based on the results, inhibition of the oxidation by hydroxyl radical was proposed as an important effect of oxides on the radiation-induced reaction. Moreover, the inhibition of the reaction of hydroxyl radical was observed in aqueous solution of nano-sized colloidal silica directly by time-resolved absorption spectroscopy using pulse-radiolysis technique.
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Report
(3 results)
Research Products
(14 results)