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Study on the reactions of the radicals from water radiolysis at the interface between water and solid oxides

Research Project

Project/Area Number 22760677
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Nuclear engineering
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

KUMAGAI Yuta  独立行政法人日本原子力研究開発機構, 原子力基礎工学研究部門, 研究員 (70455294)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords同位体・放射線化学 / 界面反応 / 放射線効果 / 水溶液 / シリカ / 海水 / ゼオライト / OHラジカル / 水和電子 / 水素 / クロム
Research Abstract

The effects of solid ceramic oxides on the radiation-induced reactions in aqueous solutions were studied. The reduction of dichromate ion in the presence of silica gel and the production of hydrogen and hydrogen peroxide in the presence of zeolites were investigated using-radiolysis technique. Based on the results, inhibition of the oxidation by hydroxyl radical was proposed as an important effect of oxides on the radiation-induced reaction. Moreover, the inhibition of the reaction of hydroxyl radical was observed in aqueous solution of nano-sized colloidal silica directly by time-resolved absorption spectroscopy using pulse-radiolysis technique.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (14 results)

All 2012 2011 2010

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (11 results)

  • [Journal Article] Measurement and Evaluation of Hydrogen Production from Mixtures of Seawater and Zeolite in Decontamination of Radioactive Water2011

    • Author(s)
      熊谷友多,永石隆二,木村敦,田口光正,西原健司,山岸功,小川徹
    • Journal Title

      Transactions of the Atomic Energy Society of Japan

      Volume: 10 Issue: 4 Pages: 235-239

    • DOI

      10.3327/taesj.J11.021

    • NAID

      10029980720

    • ISSN
      1347-2879, 2186-2931
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of silica gel on radiation-induced reduction of dichromate ion in aqueous acidic solution2011

    • Author(s)
      Y. Kumagai, R. Nagaishi, R. Yamada, Y. Katsumura
    • Journal Title

      Radiation Physics and Chemistry

      Volume: Vol.80 Issue: 8 Pages: 876-883

    • DOI

      10.1016/j.radphyschem.2011.01.014

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of silica gel on radiation-induced reduction of dichromate ion in aqueous acidic solution2011

    • Author(s)
      Y.Kumagai, R.Nagaishi, R.Yamada, Y.Katsumura
    • Journal Title

      Radiation Physics and Chemistry

      Volume: 80 Pages: 876-883

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 放射性汚染水処理における放射線効果に関する研究:(3)ゼオライト系吸着剤と水溶液との混合物の放射線分解による過酸化水素生成2012

    • Author(s)
      熊谷友多, 永石隆二, 木村敦, 田口光正, 西原健司, 山岸功
    • Organizer
      日本原子力学会2012年春の年会
    • Place of Presentation
      福井,福井大学
    • Year and Date
      2012-03-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Hydrogen production in radiolysis of the mixture of mordenite and seawater2012

    • Author(s)
      Y. Kumagai, R. Nagaishi, A. Kimura, M. Taguchi, K. Nishihara, I. Yamagishi
    • Organizer
      2nd International Workshop on Radiation Effects in Nuclear Technology. to recover Fukushima Nuclear Accident
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2012-02-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 水とモルデナイトとの混合物の放射線分解での水素発生と収量評価2011

    • Author(s)
      熊谷友多, 永石隆二, 山田禮司, 西原健司, 山岸功, 小川徹
    • Organizer
      第54回放射線化学討論会
    • Place of Presentation
      大阪,大阪大学
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 放射性汚染水処理に関わるゼオライト系吸着剤と海水との混合物からの水素発生;(1)ガンマ線照射による水素発生量の測定2011

    • Author(s)
      熊谷友多, 永石隆二, 木村敦, 田口光正, 小川徹
    • Organizer
      日本原子力学会2011年秋の大会
    • Place of Presentation
      福岡,北九州国際会議場
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Hydrogen production in radiolysis of the mixture of mordenite and seawater2011

    • Author(s)
      Y.Kumagai, R.Nagaishi, A.Kimura, M.Taguchi, K.Nishihara, I.Yamagishi, T.Ogawa
    • Organizer
      14th International Congress of Radiation Reseach
    • Place of Presentation
      Warsaw, Poland
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] Transient kinetics of hydroxyl radical and hydrated electron in aqueous solution containing colloidal silica2011

    • Author(s)
      Y. Kumagai, Y. Muroya, R. Yamada, R. Nagaishi, Y. Katsumura
    • Organizer
      International Workshop on Radiation Effects in Nuclear Technology
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2011-03-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Transient kinetics of hydroxyl radical and hydrated electron in aqueous solution containing colloidal silica2011

    • Author(s)
      Y.Kumagai, Y.Muroya, R.Yamada, R.Nagaishi, Y.Katsumura
    • Organizer
      International Workshop on Radiation Effects in Nuclear Technology
    • Place of Presentation
      東京大学(招待講演)
    • Year and Date
      2011-03-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Hydrogen production in radiolysis of the mixture of mordenite and seawater2011

    • Author(s)
      Y.Kumagai, R.Nagaishi, A.Kimura, M.Taguchi, K.Nishihara, I.Yamagishi
    • Organizer
      2nd International Workshop on Radiation Effects in Nuclear Technology-to recover Fukushima Nuclear Accident
    • Place of Presentation
      Tokyo, Japan(Invited talk)
    • Year and Date
      2011-02-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水-シリカ界面における水分解ラジカルの反応と過渡生成物2010

    • Author(s)
      熊谷友多、室屋裕佐、佐伯誠一、山田禮司、永石隆二、勝村庸介
    • Organizer
      第53回放射線化学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水-シリカ界面における放射線誘起ラジカル反応2010

    • Author(s)
      熊谷友多、室屋裕佐、山田禮司、永石隆二、勝村庸介
    • Organizer
      日本原子力学会2010年秋の大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 水-シリカ界面における放射線誘起ラジカル反応2010

    • Author(s)
      熊谷友多、室屋裕佐、山田禮司、永石隆二、勝村庸介
    • Organizer
      日本原子力学会「2010年秋の大会」
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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