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Development of prototype fluidized bed reactor for solar hydrogen production

Research Project

Project/Area Number 22760689
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Energy engineering
Research InstitutionNiigata University

Principal Investigator

GOKON Nobuyuki  新潟大学, 研究推進機構超域学術院, 准教授 (20361793)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords水素 / 再生可能エネルギー / フェライト / 高温太陽熱 / 流動層 / 水熱分解サイクル / 湿式酸化法 / 反応器
Research Abstract

With regards to solar thermochemical two-step water splitting cycle using reactive ceramic as a highly-active redox material for producing hydrogen from water, prototype fluidized bed reactor was developed and tested for hydrogen production from water using high-temperature solar heat. This reactor allows that oxygen and hydrogen are simultaneously produced and separated inside the reactor. Thus, the reactor can realize a single-process of successive two-step reactions in a single fluidized bed reactor. An irradiation test by 5kW sun-simulator showed that oxygen and hydrogen were simultaneously produced in the single-process. I did an application for a domestic patent for method and device using this reaction system for solar thermochemical water splitting to produce hydrogen.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (59 results)

All 2012 2011 2010 Other

All Journal Article (16 results) (of which Peer Reviewed: 13 results) Presentation (34 results) Remarks (6 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Journal Article] 高温太陽集熱によるソーラー水素製造技術2011

    • Author(s)
      郷右近展之, 児玉竜也
    • Journal Title

      日本エネルギー学会誌

      Volume: 90 Pages: 339-350

    • NAID

      40018818288

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Journal Article] Thermochemical two-step water splitting by internally circulating fluidized bed of NiFe_2O_4 particles : Successive reaction of thermal-reduction and water-decomposition steps2011

    • Author(s)
      Nobuyuki Gokon, Tetsuro Mataga, Nobuyuki Kondo and Tatsuya Kodama
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36(8) Pages: 4757-4767

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferrite/Zirconia coated foam device prepared by spin coating for a solar demonstration of thermochemical water-splitting2011

    • Author(s)
      Nobuyuki Gokon, Tatsuya Kodama, Nobuki Imaizumi, Jun Umeda, Taebeom Seo
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36[3] Pages: 2014-2028

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高温太陽集熱によるソーラー水素製造技術2011

    • Author(s)
      郷右近展之
    • Journal Title

      季報エネルギー総合工学

      Volume: 34 Pages: 1-13

    • NAID

      40018818288

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Kinetics of methane reforming over Ru/γ-Al_2O_3 catalyzed metallic foam at 650-900℃ for solar receiver-absorbers2011

    • Author(s)
      郷右近展之
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36 Pages: 203-215

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferrite/Zirconia coated foam device prepared by spin coating for a solar demonstration of thermochemical water-splitting2011

    • Author(s)
      郷右近展之
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36 Pages: 2014-2028

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermochemical two-step water splitting by internally circulating fluidized bed of NiFe_2O_4 particles : Successive reaction of thermal-reduction and water-decomposition steps2011

    • Author(s)
      郷右近展之
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36 Pages: 4757-4767

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高温太陽集熱による水熱分解水素製造2011

    • Author(s)
      児玉竜也
    • Journal Title

      化学工学

      Volume: 75 Pages: 1-4

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Two-Step Thermochemical Cycles for High-Temperature Solar Hydrogen Production2010

    • Author(s)
      Tatsuya Kodama, Nobuyuki Gokon
    • Journal Title

      Advances in Science and Technology

      Volume: 72 Pages: 119-128

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparative study of the activity of nickel ferrites for solar hydrogen production by two-step thermochemical cycles2010

    • Author(s)
      Fernando Fresno, Tomoaki Yoshida, Nobuyuki Gokon, Rocio Fernandez-Saavedra and Tatsuya Kodama
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 35[16] Pages: 8503-8510

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Coal Coke gasification in a windowed solar chemical reactor for beam-down optics2010

    • Author(s)
      Tatsuya Kodama, Nobuyuki Gokon, Shu-ich Enomoto, Shouta Itoh, Tsuyoshi Hatamachi
    • Journal Title

      ASME Journal of Solar Energy Engineering

      Volume: 132[4]

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ni/MgO-Al_2O_3 and Ni-Mg-O catalyzed SiC foam absorbers for high temperature solar reforming of methane2010

    • Author(s)
      Nobuyuki Gokon, Yuhei Yamawaki, Nakazawa Daisuke and Tatsuya Kodama
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 35[14] Pages: 7441-7453

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ni/MgO-Al_2O_3 and Ni-Mg-O catalyzed SiC foam absorbers for high temperature solar reforming of methane2010

    • Author(s)
      郷右近展之
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 35 Pages: 7441-7453

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coal Coke gasification in a windowed solar chemical reactor for beam-down optics2010

    • Author(s)
      児玉竜也
    • Journal Title

      ASME Journal of Solar Energy Engineering

      Volume: 132

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparative study of the activity of nickel ferrites for solar hydrogen production by two-step thermochemical cycles2010

    • Author(s)
      Fernando Fresno Garcia
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 35 Pages: 8503-8510

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of methane reforming over Ru/〓-Al_2O_3 catalyzed metallic foam at 650-900℃for solar receiver-absorbers

    • Author(s)
      Nobuyuki Gokon, Yuhei Yamawaki, Nakazawa Daisuke and Tatsuya Kodama
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36[1] Pages: 203-215

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] 反応性セラミックによる水の熱分解(22)二段階水熱分解サイクルの熱還元反応におけるセシウム酸化物のリートベルト解析2012

    • Author(s)
      田中良樹
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      日本・神奈川・慶応大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 反応性セラミックによる水の熱分解(23)二段階水熱分解サイクルにおけるCeO_2の熱還元反応の速度解析2012

    • Author(s)
      佐藤祐輔
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      日本・神奈川・慶応大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 反応性セラミックによる水の熱分解(24)二段階熱化学サイクルにおけるセリウム酸化物の水熱分解活性2012

    • Author(s)
      佐川幸
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      日本・神奈川・慶応大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 反応性セラミックによる水の熱分解(25)内循環流動層の光照射による新型反応システム-VI2012

    • Author(s)
      大森圭
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      日本・神奈川・慶応大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 反応性セラミックによる水の熱分解(19)二段階水分解サイクルにおけるフェライトのリートベルト解析2011

    • Author(s)
      近藤建
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 反応性セラミックによる水の熱分解(20)NiFe_2O_4/m-ZrO_2発泡体反応デバイスの太陽炉試験2011

    • Author(s)
      佐藤直樹
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 反応性セラミックによる水の熱分解(21)CeO_2粒子による二段階水熱分解サイクル2011

    • Author(s)
      青柳大樹
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 太陽熱化学反応によるメタンのソーラー改質(23)セラミック発泡体触媒デバイスによる高温下でのCO_2改質の速度論解析2011

    • Author(s)
      嶋脇一賢
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 太陽熱化学反応によるメタンのソーラー改質(24)アルカリ炭酸塩/セラミックコンポジット蓄熱体を用いた二重壁改質管-V2011

    • Author(s)
      高橋将吾
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 太陽光照射による石炭ガス化(11)3kWビーム照射による石炭コークス流動層のソーラーガス化2011

    • Author(s)
      小野龍太
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本・神奈川・神奈川大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 3kWth Internally circulating fluidized bed reactor for solar gasification of coal cokes2011

    • Author(s)
      Nobuyuki Gokon, Ryuta Ono, Tsuyoshi Hatamachi, Li Liuyun, Hee Joon Kim, Atsushi Sakurai, Koji Matsubara, Tatsuya Kodama
    • Organizer
      Solar PACES 2011
    • Place of Presentation
      Granada, Spain
    • Related Report
      2011 Final Research Report
  • [Presentation] Continuous hydrogen production by an internally-curcurating fluidized particle bed reactor for thermochemical water splitting2011

    • Author(s)
      Tatsuya Kodama, Tetsuro Mataga, Nobuki Imaizumi, Tsuyoshi Hatamachi and Nobuyuki Gokon
    • Organizer
      Solar PACES 2011
    • Place of Presentation
      Granada, Spain
    • Related Report
      2011 Final Research Report
  • [Presentation] Activity test of a ferrite foam device reactor for solar thermochemical two-step water-splitting2011

    • Author(s)
      Nobuki Imaizumi, Naoki Sato, Tsuyoshi Hatamachi, Taebeom Seo, Nobuyuki Gokon, Tatsuya Kodama
    • Organizer
      Solar PACES 2011
    • Place of Presentation
      Granada, Spain
    • Related Report
      2011 Final Research Report
  • [Presentation] FUNDAMENTAL STUDY OF RADIATIVE TRANSFER ANALYSIS OF INTERNALLY CIRCULATING FLUIDIZED BED SOLAR REACTOR2011

    • Author(s)
      Atsushi Sakurai, So Sakuma, Nobuyuki Gokon, Koji Matsubara, and Tatsuya Kodama
    • Organizer
      Solar PACES 2011
    • Place of Presentation
      Granada, Spain
    • Related Report
      2011 Final Research Report
  • [Presentation] Compar Ison Studies of reactivity on nickel-ferrite and cerium-oxide redox materials for two-step thermochemical water splitting below 1400℃2011

    • Author(s)
      Tatsuya Kodama, Nobuki Imaizumi, Nobuyuki Gokon, Tsuyoshi Hatamachi, Daiki Aoyagi, Ken Kondo
    • Organizer
      2011 Energy Sustainability Conference & Fuel Cell Conference
    • Place of Presentation
      Washington DC, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] Comparison studies of reactivity on nickel-ferrite and cerium-oxide redox materials for two-step thermochemical water splitting below 1400℃2011

    • Author(s)
      児玉竜也
    • Organizer
      2011 Energy Sustainability Conference & Fuel Cell Conference
    • Place of Presentation
      アメリカ・カリフォルニア州・ワシントン
    • Related Report
      2011 Annual Research Report
  • [Presentation] 3kW_<th> Internally circulating fluidized bed reactor for solar gasification of coal cokes2011

    • Author(s)
      郷右近展之
    • Organizer
      SolarPACES 2011
    • Place of Presentation
      スペイン・グラナダ
    • Related Report
      2011 Annual Research Report
  • [Presentation] Continuous hydrogen production by an internally-circulating fluidized particle bed reactor for thermochemical water splitting2011

    • Author(s)
      児玉竜也
    • Organizer
      SolarPACES 2011
    • Place of Presentation
      スペイン・グラナダ
    • Related Report
      2011 Annual Research Report
  • [Presentation] Activity test of a ferrite foam device reactor for solar thermochemical two-step water-splitting2011

    • Author(s)
      今泉伸樹
    • Organizer
      SolarPACES 2011
    • Place of Presentation
      スペイン・グラナダ
    • Related Report
      2011 Annual Research Report
  • [Presentation] FUNDAMENTAL STUDY OF RADIATIVE TRANSFER ANALYSIS OF INTERNALLY CIRCULATING FLUIDIZED BED SOLAR REACTOR2011

    • Author(s)
      櫻井篤
    • Organizer
      SolarPACES 2011
    • Place of Presentation
      スペイン・グラナダ
    • Related Report
      2011 Annual Research Report
  • [Presentation] リートベルト解析による二段階水分解セラミックの反応性向上に関する研究2011

    • Author(s)
      近藤建
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      日本・大阪・関西大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] セリウム酸化物による二段階水分解サイクル2011

    • Author(s)
      青柳大樹
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      日本・大阪・関西大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 内循環流動層反応器による二段階水分解サイクルの一段階システム化に関する研究2011

    • Author(s)
      又賀哲郎
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      日本・大阪・関西大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 二段階水熱分解セラミックの高活性化に関する研究2010

    • Author(s)
      青柳大樹
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      日本・東京・工学院大学
    • Year and Date
      2010-08-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 5kW太陽集光器によるフェライト担持発泡体デバイスの水熱分解試験2010

    • Author(s)
      今泉伸樹
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      日本・東京・工学院大学
    • Year and Date
      2010-08-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 石英窓型ソーラー改質器のためのNi系触媒デバイスの開発2010

    • Author(s)
      山脇悠平
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      日本・東京・工学院大学
    • Year and Date
      2010-08-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] Molten-salt tubular absorber/reformer(MoSTAR) project : NaCl/MgO composite thermal storage for double-walled reactor tubes2010

    • Author(s)
      Nobuyuki Gokon, Shingo Yamashita, Shogo Takahashi, Tatsuya Kodama and Taebeom Seo
    • Organizer
      Solar PACES2010
    • Place of Presentation
      Perpinan, France
    • Related Report
      2011 Final Research Report
  • [Presentation] 5kWth-solar demonstration of a ferrite foam device reactor for thermochemical two-step water-splitting2010

    • Author(s)
      Tatsuya Kodama, Taebeom Seo, Nobuyuki Gokon, Ju Han Lee, Sang Joon Oh, Koichi Sakai, Nobuki Imaizumi
    • Organizer
      Solar PACES2010
    • Place of Presentation
      Perpinan, France
    • Related Report
      2011 Final Research Report
  • [Presentation] Molten-salt tubular absorber/reformer(MoSTAR) project : Reforming performance of reactor tubes during intermittent heating2010

    • Author(s)
      Nobuyuki Gokon, Tatsuya Kodama, Shingo Yamashita, Tsuyoshi Hatamachi and Taebeom Seo
    • Organizer
      ASME 2010 4th International Conference of Energy Sustainability(ES2010)
    • Place of Presentation
      Phoenix, Arizona, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] Two-Step Thermochemical Cycles for High-Temperature Solar Hydrogen Production2010

    • Author(s)
      Tatsuya Kodama and Nobuyuki Gokon
    • Organizer
      CIMTEC2010 12th International ceramic congress
    • Place of Presentation
      Montecatini Terme, Tuscany, Italy
    • Related Report
      2011 Final Research Report
  • [Presentation] Molten-salt tubular absorber/reformer (MoSTAR) project : Reforming performance of reactor tubes during intermittent heating2010

    • Author(s)
      郷右近展之
    • Organizer
      ASME 2010 4^<th> International Conference of Energy Sustainability(ES2010)
    • Place of Presentation
      アメリカ・アリゾナ州・フェニックス
    • Related Report
      2010 Annual Research Report
  • [Presentation] Two-Step Thermochemical Cycles for High-Temperature Solar Hydrogen Production2010

    • Author(s)
      児玉竜也
    • Organizer
      CIMTEC2010 12^<th> International ceramic congress
    • Place of Presentation
      イタリア・トスカーナ州・モンテカティニテルメ
    • Related Report
      2010 Annual Research Report
  • [Presentation] Molten-salt tubular absorber/reformer (MoSTAR) project : NaCl/MgO composite thermal storage for double-walled reactor tubes2010

    • Author(s)
      郷右近展之
    • Organizer
      SolarPACES2010
    • Place of Presentation
      フランス・ペルピニャン
    • Related Report
      2010 Annual Research Report
  • [Presentation] 5kW_<th>-solar demonstration of a ferrite foam device reactor for thermochemical two-step water-splitting2010

    • Author(s)
      児玉竜也
    • Organizer
      SolarPACES2010
    • Place of Presentation
      フランス・ペルピニャン
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.niigata-u.ac.jp/department/che/class.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.eng.niigata-u.ac.jp/~chem/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.eng.niigata-u.ac.jp/department/che/class.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.niigata-u.ac.jp/~chem/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.niigata-u.ac.jp/department/che/class.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.niigata-u.ac.jp/~chem/

    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 内循環流動層を用いた水熱分解装置及び水熱分解法2012

    • Inventor(s)
      児玉竜也,郷右近展之,櫻井篤,松原幸治
    • Industrial Property Rights Holder
      新潟大学
    • Industrial Property Number
      2012-018199
    • Filing Date
      2012-01-31
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 内循環流動層を用いた水熱分解装置及び水熱分解法2012

    • Inventor(s)
      児玉竜也, 郷右近展之, 櫻井篤, 松原幸治
    • Industrial Property Rights Holder
      新潟大学
    • Industrial Property Number
      2012-018199
    • Filing Date
      2012-01-31
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 水熱分解による水素製造法及び水素製造装置2010

    • Inventor(s)
      児玉竜也, 郷右近展之
    • Industrial Property Rights Holder
      新潟大学
    • Filing Date
      2010-12-01
    • Related Report
      2010 Annual Research Report
    • Overseas

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Published: 2010-08-23   Modified: 2016-04-21  

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