Syntheses of helicenes consisted of 2, 3, and 4 condensed benzene rings and their application to high-order structures
| Project/Area Number |
22790003
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | Tokyo Medical and Dental University |
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Principal Investigator |
AIKAWA Haruo 東京医科歯科大学, 生体材料工学研究所, 特任助教 (70547322)
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| Project Period (FY) |
2010 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2010: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 有機化学 / アダマルチル / キラルナフタレン / 分子間相互作用 / 不斉認識 / ラセミ化 / ヘリセン / オルト縮環 / キラル芳香族化合物 / アダマンチル / CD / ラセミ化障壁 / ペリ位 / ベンザイン / フェナントレン |
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| Research Abstract |
Single enantiomers of 1, 8-di(1-adamantyl) naphthalenes and their derivatives having various substituents at C3 and C6 were synthesized. Kinetic studies by CD revealed enantiomerization barriers of ca. 30 kcal/mol for these chiral naphthalenes. For the applications of helicenes to high-order structures, various helicene oligomer SAMswere constructed on the gold suface.
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Report
(3 results)
Research Products
(11 results)
