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Development and Application of Selective Transformations for Diols by Multimetallic Catalysts

Research Project

Project/Area Number 22790013
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Chemical pharmacy
Research InstitutionNagasaki University

Principal Investigator

KURIYAMA Masami  長崎大学, 大学院・医歯薬学総合研究科, 准教授 (40411087)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords合成化学 / ジオール / 化学変換 / 触媒反応 / 遷移金属 / 銅 / パラジウム / スズ / アリール化 / アリル化 / 複合機能 / バイメタリック / 銅触媒 / カルベン / ハイブリッド型配位子
Research Abstract

The development of selective transformations for diols was conducted. Aryl and allyl groups were successfully introduced to diols by catalytic methods. In these reactions, high chemoselectivity and regioselectivity were achieved in addition to broad scope of substrates. The appropriate select of characteristics in metal catalyses realized high efficiency in these catalytic transformations.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (22 results)

All 2012 2011 2010

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (6 results) Patent(Industrial Property Rights) (5 results)

  • [Journal Article] Synthesis of Optically Active Oxazoline Derivatives via Catalytic Asymmetric Desymmetrization of 1, 3-Diols2012

    • Author(s)
      Tsuda, Y.; Kuriyama, M.; Onomura, O.
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Pages: 2481-2483

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Monoallylation of 1, 2-Diols by Pd/ Sn Bimetallic Catalysis2012

    • Author(s)
      Kuriyama, M.; Takeichi, T.; Ito, M.; Yamasaki, N.; Yamamura, R.; Demizu, Y.; Onomura, O.
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Pages: 2477-2480

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II)-Catalyzed Monoarylation of Vicinal Diols with Diaryliodonium Salts2012

    • Author(s)
      Kuriyama, M.; Hamaguchi, N.; Onomura, O.
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Pages: 1591-1594

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Optically Active Oxazoline Derivatives via Catalytic Asymmetric Desymmetrization of 1,3-Diols2012

    • Author(s)
      Tsuda, Y.; Kuriyama, M.; Onomura, O.
    • Journal Title

      Chem.Eur.J.

      Volume: 18 Issue: 9 Pages: 2481-2483

    • DOI

      10.1002/chem.201103800

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Monoallylation of 1,2-Diols by Pd/Sn Bimetallic Catalysis2012

    • Author(s)
      Kuriyama, M.; Takeichi, T.; Ito, M.; Yamasaki, N.; Yamamura, R.; Demizu, Y.; Onomura, O.
    • Journal Title

      Chem.Eur.J.

      Volume: 18 Issue: 9 Pages: 2477-2480

    • DOI

      10.1002/chem.201102709

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II)-Catalyzed Monoarylation of Vicinal Diols with Diaryliodonium Salts2012

    • Author(s)
      Kuriyama, M.; Hamaguchi, N.; Onomura, O.
    • Journal Title

      Chem.Eur.J.

      Volume: 18 Issue: 6 Pages: 1591-1594

    • DOI

      10.1002/chem.201102770

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic monosilylation of 1, 2-diols2011

    • Author(s)
      Takeichi, T.; Kuriyama, M.; Onomura, O.
    • Journal Title

      Tetrahedron Lett.

      Volume: 52 Pages: 6646-6648

    • NAID

      120006985211

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic monosilylation of 1,2-diols2011

    • Author(s)
      Takeichi, T.; Kuriyama, M.; Onomura, O.
    • Journal Title

      Tetrahedron Lett.

      Volume: 52 Issue: 49 Pages: 6646-6648

    • DOI

      10.1016/j.tetlet.2011.10.016

    • NAID

      120006985211

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis of optically active oxindols by copper-catalyzed asymmetric monotosylation of prochiral 1, 3-diols2010

    • Author(s)
      Kuriyama, M.; Tanigawa, S.; Kubo, Y.; Demizu, Y.; Onomura, O.
    • Journal Title

      Tetrahedron : Asymmetry

      Volume: 21 Pages: 1370-1373

    • NAID

      120006984560

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Imidazolinium Carbene-Catalyzed Arylation of Aldehydes with Arylboronic Acids in Water2010

    • Author(s)
      Kuriyama, M.; Ishiyama, N.; Shimazawa, R.; Onomura, O.
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 6814-6819

    • NAID

      120006984284

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis of optically active oxindols by copper-catalyzed asymmetric monotosylation of prochiral 1,3-diols2010

    • Author(s)
      Kuriyama, M.; Tanigawa, S.; Kubo, Y.; Demizu, Y.; Onomura, O.
    • Journal Title

      Tetrahedron : Asymmetry

      Volume: 21 Pages: 1370-1373

    • NAID

      120006984560

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 準安定型配位を基盤とする配位子開発と触媒反応への適用2012

    • Author(s)
      栗山正巳
    • Organizer
      日本薬学会第132年会
    • Place of Presentation
      北海道大学
    • Year and Date
      2012-03-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 準安定型配位を基盤とする配位子開発と触媒反応への適用2012

    • Author(s)
      栗山正巳
    • Organizer
      日本薬学会第132年会
    • Place of Presentation
      札幌
    • Related Report
      2011 Final Research Report
  • [Presentation] 準安定二座型配位子を用いた効率的アリール化反応の開発2011

    • Author(s)
      栗山正巳
    • Organizer
      日本薬学会第131年会
    • Place of Presentation
      静岡
    • Related Report
      2011 Final Research Report
  • [Presentation] Palladium-Imidazolinium Carbene-Catalyzed Arylation of Aldehydes with Arylboronic Acids in Water2010

    • Author(s)
      Kuriyama, M.; Ishiyama, N.; Shimazawa, R.; Onomura, O.
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawaii
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Palladium-Imidazolinium Carbene-Catalyzed Arylation of Alde-hydes with Arylboronic Acids in Water2010

    • Author(s)
      Kuriyama, M.; Ishiyama, N.; Shimazawa, R.; Onomura, O.
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawaii, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] C-S二座型配位子-パラジウム錯体を用いたアルデヒドのジアステレオ選択的不斉アリール化反応2010

    • Author(s)
      栗山正巳
    • Organizer
      第1回有機分子構築法夏の勉強会
    • Place of Presentation
      蔵王
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 光学活性化合物又はその塩の製造方法2011

    • Inventor(s)
      尾野村治,津田悠太朗,栗山正巳,柳俊治,児玉和也
    • Industrial Property Rights Holder
      長崎大学,ナガセケムテックス株式会社
    • Filing Date
      2011-07-12
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 新規化合物とその錯体並びに錯体の製造方法2011

    • Inventor(s)
      尾野村治,栗山正巳,松尾星来,高瀬一郎
    • Industrial Property Rights Holder
      長崎大学,ダイセル化学工業株式会社
    • Filing Date
      2011-03-31
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 光学活性化合物又はその塩の製造方法2011

    • Inventor(s)
      尾野村治, 津田悠太朗, 栗山正巳, 柳俊治, 児玉和也
    • Industrial Property Rights Holder
      長崎大学,ナガセケムテックス株式会社
    • Industrial Property Number
      2011-153692
    • Filing Date
      2011-07-12
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] ジオールのモノアリール化体の製造方法2010

    • Inventor(s)
      尾野村治,栗山正巳,山崎則次,伊藤雅章
    • Industrial Property Rights Holder
      長崎大学,ダイセル化学工業株式会社
    • Filing Date
      2010-04-23
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] ジオールのモノアリール化体の製造方法2010

    • Inventor(s)
      尾野村治, 栗山正巳, 山崎則次, 伊藤雅章
    • Industrial Property Rights Holder
      長崎大学,ダイセル化学工業株式会社
    • Industrial Property Number
      2010-099631
    • Filing Date
      2010-04-23
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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