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Development of novel thermoelectric chalcogenides and investigation of their physical properties

Research Project

Project/Area Number 22840021
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Condensed matter physics II
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

SUEKUNI Koichiro  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 助教 (10582926)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,887,000 (Direct Cost: ¥2,990,000、Indirect Cost: ¥897,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥1,937,000 (Direct Cost: ¥1,490,000、Indirect Cost: ¥447,000)
Keywords熱電変換 / カルコゲナイド / 硫化物 / スピネル / テトラへドライト / 可変領域ホッピング / テトラヘドライト
Research Abstract

We have synthesized the materials with cubic complex crystal structure ; spinels Cu_yFe_4Sn_<12> X_<32>(X=S, Se) and tetrahedrites Cu_<12-x> Tr_xSb_4S_<13>(Tr : Transition metal) and have investigated their thermoelectric properties. The result of study for spinels gave us information that the variable-range hopping conductors have a potential to be a good high-temperature thermoelectric material. Furthermore, we newly demonstrated that the tetrahedrites exhibit high thermoelectric performance due to the quite low lattice thermal conductivity.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (20 results)

All 2012 2011

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (14 results)

  • [Journal Article] Thermoelectric Properties of Mineral Tetrahedrites Cu_<10> Tr_2Sb_4S_<13> with Low Thermal Conductivity2012

    • Author(s)
      K. Suekuni, K. Tsuruta, T. Ariga, M. Koyano
    • Journal Title

      Appl Phys Express

      Volume: 5

    • NAID

      10030593351

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric Properties of Selenospinel Cu_6Fe_4Sn_<12> Se_<32>2012

    • Author(s)
      K. Suekuni, M. Kunii, H. Nishiate, M. Ohta, A. Yamamoto, and M. Koyano
    • Journal Title

      J. Electron Mater

      Volume: 41 Pages: 1130-1133

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric Properties of Selenospinel Cu_6Fe_4Sn_<12>Se_<32>2012

    • Author(s)
      K.Suekuni, M.Kunii, H.Nishiate, M.Ohta, A.Yamamoto, M.Koyano
    • Journal Title

      Journal of Electronic Materials

      Volume: 2011(印刷中) Issue: 6 Pages: 1130-1133

    • DOI

      10.1007/s11664-011-1842-3

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric Properties of Mineral Tetrahedrites Cu_<10>Tr_2Sb_4Si_<13> with Low Thermal Conductivity2012

    • Author(s)
      K.Suekuni, K.Tsuruta, T.Ariga, M.Koyano
    • Journal Title

      Applied Physics Express

      Volume: 5 Issue: 5 Pages: 051201-051201

    • DOI

      10.1143/apex.5.051201

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Variable-range-hopping conduction and low thermal conductivity in chalcogenide spinel Cu_yFe_4Sn_<12> X_<32>(X=S, Se)2011

    • Author(s)
      K. Suekuni, K. Tsuruta, T. Ariga, and M. Koyano
    • Journal Title

      J. Appl. Phys

      Volume: 109

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Variable-range-hopping conduction and low thermal conductivity in chalcogenide spinel Cu Fe_4Sn_<12>X_<32>2011

    • Author(s)
      K.Suekuni, K.Tsuruta, T.Ariga, M.Koyano
    • Journal Title

      Journal of Applied Physics

      Volume: 109

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] スピネル化合物Cu_yFe_4Sn_<12> Se_<32>の電子輸送現象2012

    • Author(s)
      末國晃一郎,鶴田光次郎,有賀智紀,小矢野幹夫
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学,西宮市,兵庫県
    • Year and Date
      2012-03-25
    • Related Report
      2011 Final Research Report
  • [Presentation] スピネル化合物Cu_yFe_4Sn_<12>Se_<32>の電子輸送現象2012

    • Author(s)
      末國晃一郎, 鶴田光次郎, 有賀智紀, 小矢野幹夫
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学,上ヶ原キャンパス
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of Novel Multicomponent Chalcogenides2012

    • Author(s)
      K. Suekuni
    • Organizer
      Japan-Finland March Meeting for the future in thermoelectrics
    • Place of Presentation
      Faculty of Science, Nagoya University, Nagoya
    • Year and Date
      2012-03-14
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of Novel Multicomponent Chalcogenides2012

    • Author(s)
      K.Suekuni
    • Organizer
      Japan-Finland March Meeting for the future in thermoelectrics
    • Place of Presentation
      Faculty of Science, Nagoya University(Invited talk)
    • Year and Date
      2012-03-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] スピネル化合物Cu_y(Fe_<1-x> Co_x)_4Sn_<12> Se_<32>の可変領域ホッピング伝導と熱電物性2011

    • Author(s)
      末國晃一郎,鶴田光次郎,有賀智紀,小矢野幹夫
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学,富山市,富山
    • Year and Date
      2011-09-22
    • Related Report
      2011 Final Research Report
  • [Presentation] スピネル化合物Cu_y(Fe_<1-x>Co_x)Sn_<12>Se_<32>の可変領域ホッピング伝導と熱電物性2011

    • Author(s)
      末國晃一郎, 鶴田光次郎, 有賀智紀, 小矢野幹夫
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学,五福キャンパス
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] カルコゲナイドスピネルCu_yT_4Sn_<12> S_<32>(T=Fe, Co)のp, n制御2011

    • Author(s)
      鶴田光次郎,末國晃一郎,有賀智紀,小矢野幹夫
    • Organizer
      第八回日本熱電学会学術講演会(TSJ2011)
    • Place of Presentation
      北海道大学,札幌市,北海道
    • Year and Date
      2011-08-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 可変領域ホッピング伝導体Cu_yFe_4Sn_<12> Se_<32>の熱電物性2011

    • Author(s)
      末國晃一郎,鶴田光次郎,有賀智紀,國井勝,太田道広,山本淳,小矢野幹夫
    • Organizer
      第八回日本熱電学会学術講演会(TSJ2011)
    • Place of Presentation
      北海道大学,札幌市,北海道
    • Year and Date
      2011-08-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 可変領域ホッピング伝導体Cu_yFe_4Sn_<12>Se_<32>の熱電物性2011

    • Author(s)
      末國晃一郎, 鶴田光次郎, 有賀智紀, 國井勝, 太田道広, 山本淳, 小矢野幹夫
    • Organizer
      第八回日本熱電学会学術講演会(TSJ2011)
    • Place of Presentation
      北海道大学,学術交流会館
    • Year and Date
      2011-08-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] カルコゲナイドスピネルCu_yFe_4Sn_<12>Se_<32>(T=Fe,Co)のp,n制御2011

    • Author(s)
      鶴田光次郎, 末國晃一郎, 有賀智紀, 小矢野幹夫
    • Organizer
      第八回日本熱電学会学術講演会(TSJ2011)
    • Place of Presentation
      北海道大学,学術交流会館
    • Year and Date
      2011-08-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Thermoelectric properties of Cu_<8-x> Fe_4Sn_<12> Se_<32>2011

    • Author(s)
      K. Suekuni, M. Kunii, H. Nishiate, M. Ohta, A. Yamamoto, and M. Koyano
    • Organizer
      30^<th> International Conference on Thermoelectrics(ICT2011)
    • Place of Presentation
      Traverse City, Michigan, USA
    • Year and Date
      2011-07-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Thermoelectric Properties of Selenospinel CU_<8-x>Fe_4Sn_<12>Se_<32>2011

    • Author(s)
      K.Suekuni, M.Kunii, H.Nishiate, M.Ohta, A.Yamamoto, M.Koyano
    • Organizer
      30^<th> International Conference on Thermoelectrics
    • Place of Presentation
      Traverse City, Michigan, USA
    • Year and Date
      2011-07-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] カルコゲナイドスピネルCu_yFe_4Sn_<12> X_<32>(X=S, Se)の可変領域ホッピング伝導と低熱伝導率2011

    • Author(s)
      末國晃一郎,鶴田光次郎,有賀智紀,小矢野幹夫
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学,厚木市,神奈川県
    • Year and Date
      2011-03-25
    • Related Report
      2011 Final Research Report
  • [Presentation] カルコゲナイドスピネルCu Fe_4Sn_<12>X_<32>(X=S, Se)の可変領域ホッピング伝導と低熱伝導率2011

    • Author(s)
      末國晃一郎, 鶴田光次郎, 有賀智紀, 小矢野幹夫
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学(神奈川)
    • Year and Date
      2011-03-25
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-27   Modified: 2020-05-15  

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