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Fixation mechanism of water in hydrous rock-forming mineral-Relation among oxidation state of the transition elements, cation distribution, and hydrogen-bonding system

Research Project

Project/Area Number 22840029
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionYamaguchi University

Principal Investigator

NAGASHIMA Mariko  山口大学, 大学院・理工学研究科, 講師 (80580274)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2011: ¥1,495,000 (Direct Cost: ¥1,150,000、Indirect Cost: ¥345,000)
Fiscal Year 2010: ¥1,625,000 (Direct Cost: ¥1,250,000、Indirect Cost: ¥375,000)
Keywords結晶構造 / 遷移元素 / 水素結合 / 含水ケイ酸塩鉱物
Research Abstract

Multi-approach to understand the relationship among the oxidation state of the transition elements, cation distribution, and hydrogen-bonding system in hydrous mineral formed by low-grade metamorphism and hydrothermal activity was carried out in this study. As the results of this study, I revealed as follows ; 1) the influence of cation substitution at octahedral sites was not only derived from ionic radius but also topological environment of octahedra, 2) The similarity and difference of pumpellyite and their related minerals, and epidote were systematically understood to focus on the cation substitution and the topology of polyhedra, 3) Relation between the oxidation state of transition elements and hydrogen-bonding system was well investigated, 4) the low-crystallinity of natural clinozoisite, which is not derived from radioactive elements, was newly discovered.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (22 results)

All 2011 2010 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (8 results) Remarks (2 results)

  • [Journal Article] Severe structural damage in Cr-and V-rich clinozoisite : Relics of an epidote-group mineral with Ca_2Al_2Cr^<3+> Si_3O_<12>(OH) composition2011

    • Author(s)
      Nagashima, M., Armbruster, T., Herwegh, M., Pettke, T., Lahti, S. and Grobety, B.
    • Journal Title

      European Journal of Mineralogy

      Volume: vol.23 Pages: 731-743

    • NAID

      10029454629

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal chemistry of Ti-rich ferriallanite-(Ce) from Cape Ashizuri, Shikoku Island, Japan2011

    • Author(s)
      Nagashima, M., Imaoka, T., and Nakashima, K
    • Journal Title

      American Mineralogist

      Volume: vol.96 Pages: 1870-1877

    • NAID

      130005008442

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] sursassite-, and epidote-type structures : common principles-individual features2011

    • Author(s)
      Nagashima, M. Pumpellyite-
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: vol.106 Pages: 211-222

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Severe structural damage in Cr-and V-rich clinozoisite : Relics of an epidote-group mineral with Ca_2Al_2Cr^<3+>Si_3O_<12>(OH)composition?2011

    • Author(s)
      Nagashima, M., Armbruster, T., Herwegh, M., Pettke, T., Lahti, S.
    • Journal Title

      European Journal of Mineralogy

      Volume: 23 Pages: 731-743

    • NAID

      10029454629

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal chemistry of Ti-rich ferriallanite-(Ce) from Cape Ashizuri, Shikoku Island, Japan2011

    • Author(s)
      Nagashima, M., Imaoka, T., Nakashima, K.
    • Journal Title

      American Mineralogist

      Volume: 96 Pages: 1870-1877

    • NAID

      130005008442

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] umpellyite-, sursassite-, and epidote-type structures : common principles-individual feature2011

    • Author(s)
      Nagashima, M.
    • Journal Title

      Mineralogical and Petrological Sciences

      Volume: 106 Pages: 211-222

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-ray Rietveld and 57Fe Mossbauer studies of epidote and piemontite on the join Ca_2Al_2Fe^<3+>Si_3O_<12>(OH)-Ca_2Al_2Mn^<3+>Si_3O_<12>(OH) formed by hydrothermal synthesis.2010

    • Author(s)
      永嶌真理子
    • Journal Title

      American Mineralogist

      Volume: 95 Pages: 1237-1246

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Saneroite : chemical and structural variations of manganese pyroxenoids with hydrogen bonding in the silicate chain.2010

    • Author(s)
      永嶌真理子
    • Journal Title

      European Journal of Mineralogy

      Volume: 22 Pages: 393-402

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The hydrogen-bond system in pumpellyite2010

    • Author(s)
      永嶌真理子
    • Journal Title

      European Journal of Mineralogy

      Volume: 22 Pages: 319-331

    • NAID

      10026666442

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-ray single-crystal and optical spectroscopic study of chromian pumpellyite from Sarani, Urals, Russia.2010

    • Author(s)
      永嶌真理子
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 105 Pages: 187-193

    • NAID

      10026643831

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal chemistry of Mn^<2+>-, Sr-rich and REE-bearing piemontite from the Kamisugai mine in the Sambagawa metamorphic belt, Shikoku, Japan.2010

    • Author(s)
      永嶌真理子
    • Journal Title

      Journal of Mineralogoal and Petrological Sciences

      Volume: 105 Pages: 142-150

    • NAID

      10026449013

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A temperature dependent structure study of gem-quality hibonite from Myanmar2010

    • Author(s)
      永嶌真理子
    • Journal Title

      Mineralogical Magazine

      Volume: 74 Pages: 871-885

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] フィンランドOutokumpu産のCrとVに富む低結晶性クリノゾイサイトの結晶化学的研究2011

    • Author(s)
      永嶌真理子・Thomas Armbruster・Marco Herwegh・Thomas Pettke・Seppo Lahti・Bernard Grobety
    • Organizer
      日本鉱物科学会2011年度年会
    • Place of Presentation
      茨城大学(水戸市)
    • Year and Date
      2011-09-11
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 摺岬産のTiに富むferriallanite-(Ce)の結晶化学的研究2011

    • Author(s)
      永嶌真理子, 今岡照喜, 中島和夫足
    • Organizer
      日本鉱物科学会2011年度年会
    • Place of Presentation
      日茨城大学(水戸市)
    • Year and Date
      2011-09-11
    • Related Report
      2011 Final Research Report
  • [Presentation] 足摺岬産のTiに富むferriallanite-(Ce)の結晶化学的研究2011

    • Author(s)
      永嶌真理子, 今岡照喜, 中島和夫
    • Organizer
      日本鉱物科学会2011年度年会
    • Place of Presentation
      茨城大学(水戸市)
    • Year and Date
      2011-09-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 造岩鉱物における遷移元素の酸化数と水素結合システムの関係2011

    • Author(s)
      永嶌真理子
    • Organizer
      日本地球惑星科学連合2011年大会
    • Place of Presentation
      幕張メッセ(千葉市)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] パンペリー石における水素結合システム2010

    • Author(s)
      永嶌真理子
    • Organizer
      平成22年度 日本鉱物科学会 年会
    • Place of Presentation
      島根大学
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] 上須戒鉱山産のMn^<2+>とSrに富む紅簾石の結晶化学的研究2010

    • Author(s)
      永嶌真理子
    • Organizer
      平成22年度 日本鉱物科学会 年会
    • Place of Presentation
      島根大学
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ardennite, tiragalloite and medaite : Structural control of(As^<5+>.V^<5+>,Si^<4+>)O_4 tetrahedra in silicates2010

    • Author(s)
      永嶌真理子
    • Organizer
      国際鉱物学連合 IMA2010
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2010-08-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] X-ray Rietveld and ^<57>Fe Mossbauer studies of epidote and piemontite on the join Ca_2Al_2Fe^<3+>Si_3O_<12>(OH)-Ca_2Al_2Mn^<3+>Si_3O_<12>(OH) formed by hydrothermal synthesis2010

    • Author(s)
      永嶌真理子
    • Organizer
      国際鉱物学連合 IMA2010
    • Place of Presentation
      Budapest, Hungary
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://web.cc.yamaguchi-u.ac.jp/~nagashim/index.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://web.cc.yamaguchi-u.ac.jp/~nagashim/index.html

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2010-08-27   Modified: 2016-04-21  

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