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Structure and Corrective Dynamics of Room-temperatutre Ionic Liquids

Research Project

Project/Area Number 22850002
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

FUJII Kenta  The University of Tokyo, 物性研究所, 特任研究員 (20432883)

Project Period (FY) 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥1,508,000 (Direct Cost: ¥1,160,000、Indirect Cost: ¥348,000)
Fiscal Year 2010: ¥1,508,000 (Direct Cost: ¥1,160,000、Indirect Cost: ¥348,000)
Keywordsイオン液体 / 集団的ダイナミクス / X線非弾性散乱実験 / 中性子スピンエコー実験
Research Abstract

We carried out a systematic study on the static and dynamic structures of room-temperature ionic liquids by means of high-energy X-ray scattering, inelastic X-ray scattering and neutron spin echo, to clarify the structure and collective dynamics of aggregated ions in ionic liquids.

Report

(2 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (23 results)

All 2011 2010

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (14 results)

  • [Journal Article] Structural Aspects of the LCST Phase Behavior of Poly(benzyl methacrylate) in Room-temperature Ionic Liquid2011

    • Author(s)
      K.Fujii, T.Ueki, K.Niitsuma, T.Matsunaga, M.Watanabe, M.Shibayama
    • Journal Title

      Polymer 52

      Pages: 1589-1589

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural Aspects of the LCST Phase Behavior of Poly (benzyl methacrylate) in Room-temperature Ionic Liquid2011

    • Author(s)
      K.Fujii, T. Ueki, et. al.
    • Journal Title

      Polymer

      Volume: 52 Pages: 1589-1595

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on the translational and rotational motions of ionic liquids composed of N-methyl-N-propyl-pyrrolidinium (P13) cation and bis(trifluoromethanesulfonyl)-amide and bis(fluorosulfonyl)amide anions and their binary systems including lithium salts2010

    • Author(s)
      K.Hayamizu, S.Tsuzuki, S.Seki, K.Fujii, M.Suenaga, Y.Umebayashi
    • Journal Title

      J.Chem.Phys. 133

      Pages: 194505-194505

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of the Conformational Isomerism in 1-N-Butyl-3-methylimidazolium Ionic Liquids on the Nature of the Halide Anion2010

    • Author(s)
      Y.Umebayashi, H.Hamano, S.Tsuzuki, J.N.C.Lopes, A.A.H.Padua, Y.Kameda, S.Kohara, T.Yamaguchi, K.Fujii, S.Ishiguro
    • Journal Title

      J.Phys.Chem.B 114

      Pages: 11715-11715

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Alkyl-chain Length on Mixing State of Imidazolium-based Ionic Liquid-Methanol Solutions2010

    • Author(s)
      T.Shimomura, K.Fujii, T.Takamuku.
    • Journal Title

      Chem.Phys.Phys.Chem. 12

      Pages: 12316-12316

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Raman Spectroscopic Studies and ab initio Calculations on Conformational Isomerism of TFSA solvated to a Lithium Ion in Ionic Liquis : Effects of the Second Solvation Sphere of the Lithium Ion2010

    • Author(s)
      Y.Umebayashi, S.Tsuzuki, K.Fujii, S.Mori, S.Seki, K.Hayamizu, S.Ishiguro.
    • Journal Title

      J.Phys.Chem.B 114

      Pages: 6513-6513

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dependence of the Conformational Isomerism in l-N-Butyl-3-methylimidazolium Ionic Liquids on the Nature of the Halide Anion2010

    • Author(s)
      Y.Umebayashi, K.Fujii, et. al.
    • Journal Title

      J.Phys. Chen. B

      Volume: 114 Pages: 11715-11724

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Raman Spectroscopic Studies and ab initio Calculations on Conformational Isomerism of TFSA solvated to a Lithium Ion in Ionic Liquis : Effects of the Second Solvation Sphere of the Lithium Ion2010

    • Author(s)
      Y.Umebayashi, K.Fujii, et. al.
    • Journal Title

      J.Phys. Chem. B

      Volume: 114 Pages: 12316-12324

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on the translational and rotational motions of ionic liquids composed of N-methyl-N-propyl-pyrrolidinium (P13) cation and bis (trifluoromethanesulfonyl)-amide and bis(fluorosulfonyl) amide anions and their binary systems including lithium salts2010

    • Author(s)
      K.Hayamizu, K.Fujii, et. al.
    • Journal Title

      J.Chem. Phys.

      Volume: 133 Pages: 194505-194505

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] FSAおよびTFSAからなるイオン液体中のリチウムイオン溶媒和とその温度依存性2011

    • Author(s)
      藤井健太,森脩人,関志朗,都築誠二,梅林泰宏
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 高エネルギーX線回折実験とMDシミュレーションによるプロトン性N-アルキルイミダゾリウム系イオン液体のイオン間相互作用に関する研究2011

    • Author(s)
      浜野洋志,藤井健太,亀田恭男,梅林泰宏
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 高エネルギーX線回折実験およびMDシミュレーションによるイオン液体[C_nH_<2n+1>NH_3^+][NO_3^-](n=2,3,4)の液体構造に関する研究2011

    • Author(s)
      宋雪旦,浜野洋志,神崎亮,藤井健太,亀田恭男,小原真司,梅林泰宏
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 種々の陰イオンからなるプロトン性(N-メチルイミダゾリウム系)イオン液体の自己解離反応2011

    • Author(s)
      土井寛之,宋雪旦,神崎亮,藤井健太,梅林泰宏
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2010 Final Research Report
  • [Presentation] イオン液体中のナノ不均一構造とその温度依存性2010

    • Author(s)
      藤井健太,梅林泰宏,亀田恭男,石黒慎一
    • Organizer
      第33回溶液化学シンポジウム
    • Place of Presentation
      京都大学(招待講演)
    • Related Report
      2010 Final Research Report
  • [Presentation] 1-ブチル-3-メチルイミダゾリウム ビス-(トリフルオロスルホニル)アミドイオン液体へのCO2の溶解 -溶媒和自由エネルギー計算と溶媒和構造-2010

    • Author(s)
      梅林泰宏,吉井未生,金久保光央,亀田恭男,藤井健太,竹内宗孝,狩野康,松林伸幸
    • Organizer
      第33回溶液化学シンポジウム
    • Place of Presentation
      京都大学
    • Related Report
      2010 Final Research Report
  • [Presentation] イオン液体[C_2mIm][FSA]中のリチウムイオン溶媒和の温度依存性と脱溶媒和エンタルピー2010

    • Author(s)
      森脩人,藤井健太,関志朗,都築誠二,梅林泰宏
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 高エネルギーX線回折実験とMDシミュレーションによる、プロトン性N-アルキルイミダゾリウム系イオン液体の液体構造研究2010

    • Author(s)
      浜野洋志,藤井健太,亀田恭男,梅林泰宏
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 高エネルギーX線回折実験とMDシミュレーションによるイオン液体ナノ相分離構造の陽イオン骨格構造依存性2010

    • Author(s)
      吉井未生,藤井健太,亀田恭男,金久保光央,梅林泰宏
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学
    • Related Report
      2010 Final Research Report
  • [Presentation] Solvation structure of Li-ion in low-viscosity ionic liquid, 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide2010

    • Author(s)
      K.Fujii, S.Mori, et. al.
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Phase Behavior and Solvation Structure of Poly(benzyl methacrylate) in Room-temperature Ionic Liquid2010

    • Author(s)
      K.Fujii, T.Ueki, et. al.
    • Organizer
      PACIFICHBM 2010
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオン液体の凝集構造とイオン・分子の溶媒和2010

    • Author(s)
      藤井健太
    • Organizer
      第33回溶液化学シンポジウム
    • Place of Presentation
      京都大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオン液体中のナノ不均一構造とその温度依存性2010

    • Author(s)
      藤井健太
    • Organizer
      第33回溶液化学シンポジウム
    • Place of Presentation
      京都大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオン液体[C_2mIm][FSA]中のリチウムイオン溶媒和の温度依存性と脱溶媒和エンタルピー2010

    • Author(s)
      森脩人、藤井健太, 他
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      京都大学
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-27   Modified: 2016-04-21  

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