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Real-time investigation on the melting dynamics of aromatic molecular crystals by using fast Low-frequency Raman spectroscopy

Research Project

Project/Area Number 22850003
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

HAJIME Okajima  東京大学, 大学院・理学系研究科, 助教 (20582654)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2011: ¥1,495,000 (Direct Cost: ¥1,150,000、Indirect Cost: ¥345,000)
Fiscal Year 2010: ¥1,625,000 (Direct Cost: ¥1,250,000、Indirect Cost: ¥375,000)
Keywords融解過程 / 格子振動 / 実時間追跡 / ラマン分光 / 結晶構造 / 顕微ラマン分光 / 結晶析出 / 磁性イオン液体 / 分子結晶 / 実時間測定
Research Abstract

We showed that a transient crystalline structure of anthracene exists in its melting. Lattice vibrations of the'' super-heated'' crystal, which is only seen during the melting, are different to those of the stationary state. We improved the fast low frequency Raman spectroscopy for simultaneous monitoring the optical image of the sample under microscope. It enables sub-second time-resolved and micrometer space-resolved tracing of the appearance(or disappearance) of lattice vibrations with simultaneous monitoring the morphology changes. It will be a new method for molecular-level and real-time tracing structural change of a small crystal during its phase transitions.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (17 results)

All 2012 2011 2010 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (12 results) Remarks (2 results)

  • [Journal Article] Rotational dynamics of solvated carbon dioxide studied by infrared, Raman, and time-resolved infrared spectroscopies and a molecular dynamics simulation2012

    • Author(s)
      Kaori Watanabe, Hajime Okajima, Takuya Kato and Hiro-o Hamaguchi
    • Journal Title

      J. Chem. Phys.

      Volume: 136 Issue: 1 Pages: 1-7

    • DOI

      10.1063/1.3671998

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unusually Long trans/gauche Conformational Equilibration Time during the Melting Process of BmimC1, a Prototype Ionic Liquid2011

    • Author(s)
      Hajime Okajima and Hiro-o Hamaguchi
    • Journal Title

      Chem. Lett

      Volume: 40 Issue: 11 Pages: 1308-1309

    • DOI

      10.1246/cl.2011.1308

    • NAID

      130004426100

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 目で見るラマン散乱2011

    • Author(s)
      岡島元, 濱口宏
    • Journal Title

      分光研究

      Volume: 60 Pages: 187-188

    • NAID

      10029483421

    • Related Report
      2011 Final Research Report
  • [Presentation] イオン液体bmim[ PF6]中のカチオン/アニオンの異常に遅い熱平衡化と不均一な液体構造2011

    • Author(s)
      岡島元,濱口宏夫
    • Organizer
      第二回イオン液体討論会
    • Place of Presentation
      京都
    • Year and Date
      2011-12-17
    • Related Report
      2011 Final Research Report
  • [Presentation] イオン液体bmim[PF6]中のカチオン/アニオンの異常に遅い熱平衡化と不均一な液体構造2011

    • Author(s)
      岡島元, 濱口宏夫
    • Organizer
      イオン液体討論会
    • Place of Presentation
      京都
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Formation in IonicLiquids : A Study by Stokes/anti-StokesRaman Spectroscopy2011

    • Author(s)
      Non-uniform Thermal Equilibration and Local Structure
    • Organizer
      TheThird Asian Spectroscopy Conference
    • Place of Presentation
      Xiamen
    • Year and Date
      2011-11-30
    • Related Report
      2011 Final Research Report
  • [Presentation] Non-uniform Thermal Equilibration and Local Structure Formation in Ionic Liquids : A Study by Stokes/anti-Stokes Raman Spectroscopy2011

    • Author(s)
      Hajime Okajima, Hiro-o Hamaguchi
    • Organizer
      The Third Asian Spectroscopy Conference
    • Place of Presentation
      Xiamen china
    • Year and Date
      2011-11-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] ストークス・アンチストークスラマン分光によるイオン液体局所熱平衡の動的観測2011

    • Author(s)
      岡島元,濱口宏夫
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 格子振動の動的観察によるアントラセンの"過熱状態"の構造研究2010

    • Author(s)
      岡島元、濱口宏夫
    • Organizer
      分子科学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 格子振動の動的観察によるアントラセンの"過熱状態"の構造研究2010

    • Author(s)
      岡島元、濱口宏夫
    • Organizer
      分子科学討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 低振動数顕微ラマン分光装置の開発と単結晶の空間分解測定への応用2010

    • Author(s)
      富永正治、岡島元、濱口宏夫
    • Organizer
      分子科学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] Sub-Second Tracing of Lattice ModeChanges During the Melting of anAnthracene Crystal2010

    • Author(s)
      Hajime Okajimaand Hiro-o Hamaguchi
    • Organizer
      International Conference on RamanSpectroscopy
    • Place of Presentation
      Boston
    • Year and Date
      2010-08-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Sub-Second Tracing of Lattice Mode Changes During the Melting of an Anthracene Crystal2010

    • Author(s)
      Hajime Okajima, Hiro-o Hamaguchi
    • Organizer
      International Conference on Raman Spectroscopy
    • Place of Presentation
      Boston 米国
    • Year and Date
      2010-08-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fast(second-millisecond) LowFrequency Raman Spectroscopy forReal-time Tracing of Melting Process2010

    • Author(s)
      Hajime Okajima and Hiro-o Hamaguchi
    • Organizer
      International Symposium onAdvanced Spectroscopy and Imaging inMolecular Science
    • Place of Presentation
      Hshinchu
    • Year and Date
      2010-07-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Fast (second!millisecond) Low Frequency Raman Spectroscopy for Real-time Tracing of Melting Process2010

    • Author(s)
      Hajime Okajima, Hiro-o Hamaguchi
    • Organizer
      International Symposium on Advanced Spectroscopy and Imaging in Molecular Science
    • Place of Presentation
      Hshinchu 台湾
    • Year and Date
      2010-07-12
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.s.u-tokyo.ac.jp/02basic/laboFiles/spectrum_j.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/struct/index.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-27   Modified: 2016-04-21  

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