| Budget Amount *help |
¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
|
|---|
| Research Abstract |
In this research, I successfully obtained the reactions of esters by using reagents havingdual silicon atoms in one molecule for reductive alkylations shown below
Reductive alkylations of electron-rich aromatic rings with ester as an alkylatingreagent in the presence of disiloxane and ruthenium-cluster catalyst.
Under the similar conditions of 1), reductive alkylations of tosylamides were accomplished.
During the course of the research, I unexpectedly obtained rearrangement products(RCH2CHO) of vinyl ethers(CH2=CHOR) under silane and ruthenium-cluster catalystconditions.
|
