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Development of separation method for secondary copper and arsenic minerals using flotation

Research Project

Project/Area Number 22K14636
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 31020:Earth resource engineering, Energy sciences-related
Research InstitutionKyushu University

Principal Investigator

Suyantara Gde Pandhe Wisnu  九州大学, 工学研究院, 特任助教 (70932367)

Project Period (FY) 2022-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2023: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2022: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
KeywordsFlotation / Enargite / Chalcocite / Copper arsenic / Oxidation treatment / Hydrogen peroxide / enargite / chalcocite / hydrogen peroxide / potassium amyl xanthate / selective flotation / mineral separation / Secondary copper sulfide / Arsenic bearing minerals / Selective flotation / Surface properties
Outline of Research at the Start

Selective oxidation treatment is proposed for the separation of secondary copper sulfides (i.e., chalcocite and covellite) and arsenic-bearing copper minerals (i.e., enargite and tennantite) using flotation in this study. The underlying surface mechanism is studied to explain the flotation behavior.

Outline of Final Research Achievements

This study successfully demonstrated the process of separating copper from minerals containing arsenic via flotation and oxidation treatment using hydrogen peroxide. The research included the basic investigation and practical implementation of the oxidation treatment on copper-arsenic concentrate, ranging from small-scale laboratory experiments to larger-scale bench experiments. This research demonstrated the ability to decrease the arsenic level in the final copper concentrate to a value lower than the threshold for processing copper concentrate with arsenic, which is set at 0.2%. Moreover, this research proposes a method for generating a purified copper concentrate from copper concentrate that contains arsenic.

Academic Significance and Societal Importance of the Research Achievements

This research developed a process to separate arsenic from copper concentrate using flotation and oxidation treatment, producing a clean copper concentrate that contains a minimal amount of arsenic. This will decrease arsenic emissions and minimize the pollution of the environment with arsenic.

Report

(3 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • Research Products

    (33 results)

All 2024 2023 2022 Other

All Journal Article (6 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 6 results,  Open Access: 3 results) Presentation (26 results) (of which Int'l Joint Research: 16 results) Remarks (1 results)

  • [Journal Article] Selective Flotation of Copper Concentrates Containing Arsenic Minerals Using Potassium Amyl Xanthate and Oxidation Treatment2024

    • Author(s)
      Suyantara Gde Pandhe Wisnu、Miki Hajime、Hirajima Tsuyoshi、Sasaki Keiko、Ochi Daishi、Aoki Yuji
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 65 Issue: 1 Pages: 27-36

    • DOI

      10.2320/matertrans.M-M2023811

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2024-01-01
    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Effect of oxidation treatment on the selective separation of molybdenite from chalcocite using flotation2024

    • Author(s)
      Berdakh Daniyarov、Miki Hajime、Hirajima Tsuyoshi、Sasaki Keiko、Ulmaszoda Akbarshokh、Nakao Ryota、Ochi Daishi、Aoki Yuji、Suyantara Gde Pandhe Wisnu
    • Journal Title

      Powder Technology

      Volume: 431 Pages: 119078-119078

    • DOI

      10.1016/j.powtec.2023.119078

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of pH and Precipitations on Copper–Molybdenum Rougher Flotation in Seawater2023

    • Author(s)
      Tanaka Yoshiyuki、Miki Hajime、Suyantara Gde Pandhe Wisnu、Aoki Yuji、Okamoto Hideyuki、Ura Kumika、Hirajima Tsuyoshi
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 64 Issue: 6 Pages: 1225-1231

    • DOI

      10.2320/matertrans.M-M2023805

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2023-06-01
    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Sodium metabisulfite as a copper depressant in the selective flotation of copper-molybdenum concentrate using seawater2023

    • Author(s)
      Suyantara Gde Pandhe Wisnu、Miki Hajime、Ochi Daishi、Aoki Yuji、Ura Kumika、Berdakh Daniyarov、Ulmaszoda Akbarshokh、Dwitama Eska Putra、Sasaki Keiko、Hirajima Tsuyoshi
    • Journal Title

      Advanced Powder Technology

      Volume: 34 Issue: 12 Pages: 104258-104258

    • DOI

      10.1016/j.apt.2023.104258

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of goethite (α-FeOOH) nanoparticles on the surface properties and flotation behavior of chalcopyrite2023

    • Author(s)
      Suyantara Gde Pandhe Wisnu、Rizki Intan Nurul、Ulmaszoda Akbarshokh、Miki Hajime、Sasaki Keiko
    • Journal Title

      Journal of Environmental Chemical Engineering

      Volume: 11 Issue: 3 Pages: 110006-110006

    • DOI

      10.1016/j.jece.2023.110006

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of hydrogen peroxide on selective flotation of chalcocite and enargite2023

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Daniyarov Berdakh, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Daishi Ochi, Yuji Aoki
    • Journal Title

      International Journal of Mining Science and Technology

      Volume: in press Issue: 6 Pages: 703-716

    • DOI

      10.1016/j.ijmst.2023.01.002

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Selective separation of molybdenite from chalcocite using flotation under oxidizing condition2024

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Daniyarov Berdakh, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Akbarshokh Ulmaszoda, Ryota Nakao, Daishi Ochi, Yuji Aoki
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2023 Annual Research Report
  • [Presentation] the effect and mechanism of depressant on selective flotation of copper and molybdenum minerals2024

    • Author(s)
      Hajime Miki, Gde Pandhe Wisnu Suyantara, Ryota Nakao, Kazuto Satomura, Keiko Sasaki, Daishi Ochi, Yuji Aoki
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2023 Annual Research Report
  • [Presentation] Utilizing Oxidation Treatment for Arsenic Mineral Removal in Producing a Cleaner Copper Concentrate using Flotation2023

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Hajime Miki, Keiko Sasaki, Yuji Aoki, Daishi Ochi, Tsuyoshi Hirajima
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of Chalcopyrite Floatability in the Presence of Goethite Nanoparticles2023

    • Author(s)
      Akbarshokh Ulmaszoda, Gde Pandhe Wisnu Suyantara, Intan Nurul Rizki, Keiko Sasaki, Hajime Miki
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preliminary Evaluation of the Impact of Nanoparticles on Enargite Flotation2023

    • Author(s)
      Eska Putra Dwitama, Akbarshokh Ulmaszoda, Gde Pandhe Wisnu Suyantara, Keiko Sasaki, Hajime Miki
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of micro powder electrode on sulfide mineral leaching for hydrometallurgical process2023

    • Author(s)
      Hajime Miki, Tsuyoshi Hirajima, Gde Pandhe Wisnu Suyantara, Keiko Sasaki
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Arsenic removal with heat treatment - magnetic separation from dirty copper conc.2023

    • Author(s)
      Hajime Miki, Gde Pandhe Wisnu Suyantara, Keiko Sasaki
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on the Effect of Iron Oxide-Hydroxide Nanoparticles on Mixed Flotation of Bornite and Molybdenite2023

    • Author(s)
      Kazuto Satomura, Gde Pandhe Wisnu Suyantara, Hajime Miki, Keiko Sasaki
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The Effect Of Various Reagents On Selective Flotation Of Molybdenite And Chalcocite2023

    • Author(s)
      Ryota Nakao, Hajime Miki, Eska Putra Dwitama, Keiko Sasaki, Daishi Ochi, Yuji Aoki, Gde Pandhe Wisnu Suyantara
    • Organizer
      International Symposium on Metallurgical and Materials Engineering- The 18th International Conference on Quality in Research
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of the Effect of Goethite Nananoparticles on Chalcopyrite Floatability2023

    • Author(s)
      Akbarshokh Ulmaszoda, Gde Pandhe Wisnu Suyantara, Intan Nurul Rizki, Keiko Sasaki and Hajime Miki
    • Organizer
      International Symposium on Earth Science and Technology
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of the Effect of Nanoparticles on the Flotation of Enargite2023

    • Author(s)
      Eska Putra Dwitama, Akbarshokh Ulmaszoda, Gde Pandhe Wisnu Suyantara, Keiko Sasaki, Hajime Miki
    • Organizer
      International Symposium on Earth Science and Technology
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study of pyrite depression for producing a high-grade copper concentrate from a complex copper ore2023

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Akbarshokh Ulmaszoda, Hajime Miki, Keiko Sasaki, Taisuke Sakakibara, Hisatoshi Furuya, Satoru Okubo
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2023 Annual Research Report
  • [Presentation] Effects of Sodium Metabisulfite and various collectors on selective flotation of Chalcocite and Molybdenite2023

    • Author(s)
      Ryota Nakao, Gde Pandhe Wisnu Suyantara, Hajime Miki, Keiko Sasaki, Yuji Aoki, Daishi Ochi, Satoru Yanagisawa, Eri Takida, Kumika Ura
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2023 Annual Research Report
  • [Presentation] Study on the Effect of Iron Oxide Nanoparticles on the Mixed Flotation Sorting of Mottled Copper Ore and Brilliant Lead Ore2023

    • Author(s)
      Kazuto Satomura, Gde Pandhe Wisnu Suyantara, Hajime Miki, Keiko Sasaki
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2023 Annual Research Report
  • [Presentation] Investigation of sodium sulfite as a depressant for selective flotation of copper sulfide minerals from arsenic-bearing copper mineral2023

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Daishi Ochi, Yuji Aoki
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2022 Research-status Report
  • [Presentation] Selective Flotation of Fluorite from Calcite using Sodium Humate as a Depressant2023

    • Author(s)
      Rihan Efendi, Farahat Mohsen, Hajime Miki, Gde Pandhe Wisnu Suyantara, Keiko Sasaki
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2022 Research-status Report
  • [Presentation] Study on the Effect of Sodium Metabisulfite on Selective Flotation of Chalcopyrite and Molybdenite with Seawater2022

    • Author(s)
      Ryoji Ogi, Gde Pandhe Wisnu Suyantara, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Yuji Aoki, Daishi Ochi
    • Organizer
      International Symposium on Earth Science and Technology
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Separation of enargite and chalcocite with H2O2 oxidation treatment using flotation method2022

    • Author(s)
      Daniyarov Berdakh, Gde Pandhe Wisnu Suyantara, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Daishi Ochi, Yuji Aoki
    • Organizer
      International Symposium on Earth Science and Technology
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Separation of enargite and chalcocite with H2O2 oxidation treatment using flotation method2022

    • Author(s)
      Daniyarov Berdakh, Gde Pandhe Wisnu Suyantara, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Daishi Ochi, Yuji Aoki
    • Organizer
      The 16th International Symposium on East Asian Resources Recycling Technology
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of sodium sulphite on flotation behavior of bornite and tennantite2022

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Hajime Miki, Keiko Sasaki, Yoshiyuki Tanaka, Yuji Aoki
    • Organizer
      International Mineral Processing Congress (IMPC) Asia Pacific
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] The estimation of microgram powder electrode system on sulfide mineral oxidation for mineral processing2022

    • Author(s)
      Hajime Miki, Hiroki Fukuda, Berdakh Daniyarov, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki
    • Organizer
      Copper 2022
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Investigation of sodium sulfite as a selective depressant in the flotation of chalcopyrite and enargite2022

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Hajime Miki, Keiko Sasaki, Yoshiyuki Tanaka, Yuji Aoki
    • Organizer
      Copper 2022
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Arsenic removal from arsenic containing copper concentrate with heat treatment and magnetic separation2022

    • Author(s)
      Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki, Yuji Aoki, Hiroki Kukuda
    • Organizer
      Copper 2022
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Study on the Effect of Sodium Metabisulfite on Selective Flotation of Chalcopyrite and Molybdenite with Seawater2022

    • Author(s)
      Ryoji Ogi, Gde Pandhe Wisnu Suyantara, Hajime Miki, Tsuyoshi Hirajima, Keiko Sasaki, Yuji Aoki, Daishi Ochi
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2022 Research-status Report
  • [Presentation] Oxidation treatment for separation of copper sulfide minerals and arsenic-bearing copper minerals using flotation2022

    • Author(s)
      Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Hajime Miki, Keiko Sasaki, Yoshiyuki Tanaka, Eri Takida
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2022 Research-status Report
  • [Presentation] Selective flotation of Copper Mineral and Enargite with PAX and Hydrogen Peroxide2022

    • Author(s)
      Daniyarov Berdakh, Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki
    • Organizer
      The Mining and Materials Processing Institute of Japan Conference
    • Related Report
      2022 Research-status Report
  • [Remarks] 資源処理・環境修復工学研究室

    • URL

      https://process.mine.kyushu-u.ac.jp/

    • Related Report
      2022 Research-status Report

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Published: 2022-04-19   Modified: 2025-01-30  

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