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Machine learning-driven preparation of high-performance bio-derived carbon catalyst for conversion of cellulose

Research Project

Project/Area Number 22K14713
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 34030:Green sustainable chemistry and environmental chemistry-related
Research InstitutionNagoya University

Principal Investigator

CHOKRADJAROEN CHAYANAPHAT  名古屋大学, 工学研究科, 助教 (00850314)

Project Period (FY) 2022-04-01 – 2025-03-31
Project Status Granted (Fiscal Year 2023)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2024: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2023: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2022: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsnatural resources / carbon materials / database / catalytic activity / chitosan / cellulose conversion / bio-derived carbon / conversion / cellulose / catalyst
Outline of Research at the Start

This study will apply ML to identify relationship of raw materials, process, properties, and performance and develop generic prediction models to find key factors for achieving high-performance catalysts for cellulose conversion, which will provide solid ideas for development to commercial scale.

Outline of Annual Research Achievements

In year 2023, 26 raw materials were converted into carbon materials by three different pyrolysis temperatures, i.e., 500, 700, and 900 °C, which resulted in 78 carbon materials. The raw materials which were converted to carbon last year are Coffee ground, Orange peel powder, Mangosteen peel powder, Lemongrass, Walnut shell, Orange peel powder, Apple peel, Orange peel, Longkong peel, Banana peel, Watermelon peel, Paddy type 1, Pomelo peel type 1, Durian thorn, Durian peel (white area), Pineapple peel fiber, Pineapple peel fiber, Paddy type 2, Pomelo peel type 2, Coffee bean, Green onion, Carrot, Lotus root, Burdock root, Spinach, and Bamboo.
Their measurement of XRD and SEM have been done, respectively. The selection of descriptors and data pre-processing is still in progress. For the catalytic evaluation for conversion of cellulose, the setting of reactors and HLPC have been completed. The obtained carbon will be evaluated and further modify to achieve the good catalytic activity. Moreover, chitosan was chosen to use to study and modify to obtained Fe-Chitosan complex which was expected to use as anticancer agents. In addition, chitosan was also investigated to produce a N-doped graphene and composite with graphite and carbon black, aiming to increase the electrical conductivity that can be used as to improve the performance of lithium-ion battery.

Current Status of Research Progress
Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

The pretreatment (i.e. drying process) and characterization of some raw materials was needed to be redo, because it was difficult to obtain the products. XRD and FTIR were broken in the middle of year 2023 for several months.

Strategy for Future Research Activity

In the Fiscal Year 2024, the data collection will continue and the catalytic evaluation for conversion of cellulose will be conducted. The characterization, such as XRD and SEM, is planned to redo, as well as FTIR, BET, etc. are planned to do to increase the quality of database. The prediction models are also planned to demonstrate. Moreover, the research which are completed, are planned to complete the analysis of the experimental data and proceed to prepare the manuscript to publish in Q1 journal, such as Carbohydrate Polymers and Carbon.

Report

(2 results)
  • 2023 Research-status Report
  • 2022 Research-status Report
  • Research Products

    (4 results)

All 2023 Other

All Int'l Joint Research (2 results) Presentation (2 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Int'l Joint Research] Chulalongkorn University/Mahidol University/Thammasat University(タイ)

    • Related Report
      2023 Research-status Report
  • [Int'l Joint Research] Mahidol University/Chulalongkorn University(タイ)

    • Related Report
      2022 Research-status Report
  • [Presentation] Direct Synthesis of Amorphous Iron Oxide Nanoparticles Incorporated on Chitosan Oligomer via Solution Plasma2023

    • Author(s)
      Chayanapat Chokradjaroen
    • Organizer
      13th Asian-European International Conference on Plasma Surface Engineering (Busan, Korea)
    • Related Report
      2023 Research-status Report
    • Int'l Joint Research
  • [Presentation] Solution plasma in aqueous solution and their application in modification of nature-derived polymers2023

    • Author(s)
      Chayanapat Chokradjaroen
    • Organizer
      Campus Asia Workshop: The 3rd Symposium on Socio-technical Innovation for Zero Carbon in Asian Countries (Bangkok, Thailand)
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2022-04-19   Modified: 2024-12-25  

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