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Investigation of donor/acceptor interactions toward high-performance organic near-infrared (NIR) lasers beyond 900 nm

Research Project

Project/Area Number 22K20536
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeMulti-year Fund
Review Section 0501:Physical chemistry, functional solid state chemistry, organic chemistry, polymers, organic materials, biomolecular chemistry, and related fields
Research InstitutionKyushu University

Principal Investigator

TANG XUN  九州大学, 工学研究院, 学術研究員 (70961754)

Project Period (FY) 2022-08-31 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2023: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2022: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
KeywordsOrganic electronics / Organic lasers / D/A interactions / Near-infrared / organic lasers / near-infrared (NIR)
Outline of Research at the Start

Near-infrared (NIR) lasers own tremendous value in communication and surgery. Our research is aimed at manipulating interactions between the electon donating and accepting moieties in molecules, to reduce the NIR laser thresholds, and further extend the lasing wavelength beyond 900 nm.

Outline of Final Research Achievements

This research is focusing on the understanding and manipulating the electronic donor (D) and acceptor (A) interactions for realizing organic lasers with longer wavelength. By incorporating strong donor and acceptor moieties, the emission can be shifted to near-infrared (NIR) region. Furthermore, after rationally inserting the functional spacers between D and A moieties, the molecules can obtain large gain coefficient. In general, this research proposes stable organic laser cores with multiple-resonance effect, which has a low lasing threshold and the triplet upconversion property. Furthermore, this research achieved high performance organic distributed feedback lasers with the wavelength exceeding 900 nm. During this research, three papers have been published on Angew. Chem., Adv. Mater., and Nat. Commun., also, three oral (including one invited presentation) and one poster presentation have been taken in the international conferences.

Academic Significance and Societal Importance of the Research Achievements

The research achievement clarifies the underlying mechanism of electron donating and accepting interactions to achieve high efficiency and radiative rate. Thus, potential strategies are proposed to realize high performance organic light emitting devices and near-infrared organic lasers.

Report

(2 results)
  • 2023 Final Research Report ( PDF )
  • 2022 Research-status Report
  • Research Products

    (4 results)

All 2023

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (1 results)

  • [Journal Article] Progress and Perspective toward Continuous-Wave Organic Solid-State Lasers2023

    • Author(s)
      Xun Tang, Chathuranganie A. M. Senevirathne, Toshinori Matsushima, Atula S. D. Sandanayaka, Chihaya Adachi
    • Journal Title

      Advanced Materials

      Volume: / Issue: 20

    • DOI

      10.1002/adma.202211873

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Donor-Acceptor Cage for Thermally Activated Delayed Fluorescence: toward a New Kind of TADF Exciplex Emitters2023

    • Author(s)
      Lihua Chen, Chuanlong Li, Enguang Fu, Mengyang Li, Yoshiaki Kuboi, Zi-Ying Li, Zhenghong Chen, Jiaolong Chen, Xuelong Liu, Xun Tang, Lucas Frederic, Francois Maurel, Chihaya Adachi, Fabrice Mathevet, Shaodong Zhang
    • Journal Title

      ACS Materials Letters

      Volume: 5 Issue: 5 Pages: 1450-1455

    • DOI

      10.1021/acsmaterialslett.3c00310

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Artificial p-n‐like Junction Based on Pure 2D Organic-Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moieties2023

    • Author(s)
      Zhao Feng, Xuelong Liu, Kentaro Imaoka, Tomohiro Ishii, Ganbaatar Tumen‐Ulzii, Xun Tang, George F Harrington, Benoit Heinrich, Jean‐Charles Ribierre, Lise‐Marie Chamoreau, Lydia Sosa Vargas, David Kreher, Kenichi Goushi, Toshinori Matsushima, Guijiang Zhou, Fabrice Mathevet, Chihaya Adachi
    • Journal Title

      Advanced Optical Materials

      Volume: 2202734 Issue: 10 Pages: 1-8

    • DOI

      10.1002/adom.202202734

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Molecular Interactions in Donor-Acceptor-Donor Skeletons Toward Near-Infrared Organic Lasers2023

    • Author(s)
      Xun Tang, Chihaya Adachi
    • Organizer
      The 70th JSAP Spring Meeting 2023
    • Related Report
      2022 Research-status Report

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Published: 2022-09-01   Modified: 2025-01-30  

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