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Research of decomposition mechanism of mixed cation-anionic metal halide perovskite material

Research Project

Project/Area Number 22KF0363
Project/Area Number (Other) 21F21754 (2021-2022)
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeMulti-year Fund (2023)
Single-year Grants (2021-2022)
Section外国
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionOkinawa Institute of Science and Technology Graduate University

Principal Investigator

MARIOTTI Silvia (2023)  沖縄科学技術大学院大学, エネルギー材料と表面科学ユニット, ポストドクトラルスカラー (30993977)

Qi Yabing (2021-2022)  沖縄科学技術大学院大学, エネルギー材料と表面科学ユニット, 教授 (10625015)

Co-Investigator(Kenkyū-buntansha) MARIOTTI SILVIA  沖縄科学技術大学院大学, エネルギー材料と表面科学ユニット, 外国人特別研究員
Project Period (FY) 2023-03-08 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 2023: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2022: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2021: ¥400,000 (Direct Cost: ¥400,000)
Keywordsperovskite / solar cells / 2PACz / PEAI / Perovskite / self-assembly monolayers / perovskite solar modules / surface passivation / Perovskite passivation / bifacial solar cells
Outline of Research at the Start

継続課題のため、記入しない。

Outline of Annual Research Achievements

The JSPS fellow mentored two PhD students in Prof. Qi’s lab and together they have worked on several projects. One scientific paper has been submitted to a high impact factor journal, in which it is explained how to deposit a common hole transporting material used in p-i-n perovskite solar cells (2PACz) with alternative methods, for the fabrication of solar cells with small and large area. The characterization of the material and in particular, the determination of its thickness which was never presented in the literature before is shown. The second project, which will be submitted very soon to a high impact factor journal, focuses on understanding the chemical mechanism between the perovskite layer and a common additive that is used in perovskite solar cells, phenetylammonium salt.

Report

(3 results)
  • 2023 Annual Research Report
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (12 results)

All 2024 2023 2022 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 6 results,  Open Access: 8 results) Presentation (1 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Int'l Joint Research] NTU(シンガポール)

    • Related Report
      2023 Annual Research Report
  • [Journal Article] Self‐Assembled Monolayer Hole‐Selective Contact for Up‐Scalable and Cost‐Effective Inverted Perovskite Solar Cells2024

    • Author(s)
      Wu Tianhao、Mariotti Silvia、Ji Penghui、Ono Luis K.、Guo Ting、Rabehi Ilhem‐Nadia、Yuan Shuai、Zhang Jiahao、Ding Chenfeng、Guo Zhanglin、Qi Yabing
    • Journal Title

      Advanced Functional Materials

      Volume: "-" Issue: 32

    • DOI

      10.1002/adfm.202316500

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Bandgap Pairing in Three-Terminal Tandem Solar Cells: From Limiting Efficiency to Voltage-Matched Device Performance2024

    • Author(s)
      Philipp Wagner, Philipp Tockhorn, Lea Zimmermann, Eike Koehnen, Silvia Mariotti, Florian Scheler, Marlene Haertel, Steve Albrecht, Lars Korte
    • Journal Title

      Solar RRL

      Volume: 8 Issue: 5 Pages: 2300963-2300963

    • DOI

      10.1002/solr.202300963

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Local Built‐In Field at the Sub‐nanometric Heterointerface Mediates Cascade Electrochemical Conversion of Lithium?sulfur Batteries2023

    • Author(s)
      Ding Chenfeng、Niu Mang、Cassidy Cathal、Kang Hyung‐Been、Ono Luis K.、Wang Hengyuan、Tong Guoqing、Zhang Congyang、Liu Yuan、Zhang Jiahao、Mariotti Silvia、Wu Tianhao、Qi Yabing
    • Journal Title

      Small

      Volume: 50 Issue: 37 Pages: 2301755-2301755

    • DOI

      10.1002/smll.202301755

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Holistic Strategies Lead to Enhanced Efficiency and Stability of Hybrid Chemical Vapor Deposition Based Perovskite Solar Cells and Modules2023

    • Author(s)
      Tong Guoqing、Zhang Jiahao、Bu Tongle、Ono Luis K.、Zhang Congyang、Liu Yuqiang、Ding Chenfeng、Wu Tianhao、Mariotti Silvia、Kazaoui Said、Qi Yabing
    • Journal Title

      Advanced Energy Materials

      Volume: / Issue: 21 Pages: 2300153-2300153

    • DOI

      10.1002/aenm.202300153

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Controllable Anion Exchange on Perovskite Nanocrystal Solid-State Thin Films2023

    • Author(s)
      Congyang Zhang, Chenfeng Ding, Shuai Yuan, Luis K Ono, Caiyi Zhang, Tianhao Wu, Silvia Mariotti, Penghui Ji, Tongtong Li, Jiahao Zhang, Yabing Qi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 127 Issue: 20 Pages: 9947-9956

    • DOI

      10.1021/acs.jpcc.3c02281

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphene‐Like Conjugated Molecule as Hole‐Selective Contact for Operationally Stable Inverted Perovskite Solar Cells and Modules2023

    • Author(s)
      Tianhao Wu, Xiushang Xu, Luis K Ono, Ting Guo, Silvia Mariotti, Chenfeng Ding, Shuai Yuan, Congyang Zhang, Jiahao Zhang, Kirill Mitrofanov, Qizheng Zhang, Saurav Raj, Xiao Liu, Hiroshi Segawa, Penghui Ji, Tongtong Li, Ryota Kabe, Liyuan Han, Akimitsu Narita, Yabing Qi
    • Journal Title

      Advanced Materials

      Volume: 35 Issue: 21 Pages: 2300169-2300169

    • DOI

      10.1002/adma.202300169

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A hole injection monolayer enables cost-effective perovskite light-emitting diodes2023

    • Author(s)
      Zhang Congyang、Mariotti Silvia、Ono Luis K.、Ding Chenfeng、Mitrofanov Kirill、Zhang Caiyi、Yuan Shuai、Ji Penghui、Zhang Jiahao、Wu Tianhao、Kabe Ryota、Qi Yabing
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 11 Issue: 8 Pages: 2851-2862

    • DOI

      10.1039/d2tc05491d

    • Related Report
      2022 Annual Research Report
    • Open Access
  • [Journal Article] Elimination of light-induced degradation at the nickel oxide-perovskite heterojunction by aprotic sulfonium layers towards long-term operationally stable inverted perovskite solar cells2022

    • Author(s)
      Wu Tianhao、Ono Luis K.、Yoshioka Rengo、Ding Chenfeng、Zhang Congyang、Mariotti Silvia、Zhang Jiahao、Mitrofanov Kirill、Liu Xiao、Segawa Hiroshi、Kabe Ryota、Han Liyuan、Qi Yabing
    • Journal Title

      Energy & Environmental Science

      Volume: 15 Issue: 11 Pages: 4612-4624

    • DOI

      10.1039/d2ee01801b

    • Related Report
      2022 Annual Research Report
    • Open Access / Int'l Joint Research
  • [Journal Article] Ion-regulating Hybrid Electrolyte Interface for Long-life and Low N/P Ratio Lithium Metal Batteries2022

    • Author(s)
      Ding Chenfeng、Liu Yuan、Ono Luis K.、Tong Guoqing、Zhang Congyang、Zhang Jiahao、Lan Jinle、Yu Yunhua、Chen Bingbing、Qi Y.B.
    • Journal Title

      Energy Storage Materials

      Volume: 50 Pages: 417-425

    • DOI

      10.1016/j.ensm.2022.05.035

    • Related Report
      2022 Annual Research Report
    • Open Access / Int'l Joint Research
  • [Presentation] Piperazinium iodide as perovskite treatment for high-performance perovskite/silicon tandem solar cells2023

    • Author(s)
      Silvia Mariotti
    • Organizer
      ISOS-14 Yokohama
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] PCT, Taiwan2023

    • Inventor(s)
      Yabing Qi et al.
    • Industrial Property Rights Holder
      Yabing Qi et al.
    • Industrial Property Rights Type
      特許
    • Filing Date
      2023
    • Related Report
      2023 Annual Research Report
    • Overseas

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Published: 2022-02-08   Modified: 2024-12-25  

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