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Tip enhanced Terahertz - Raman for investigating graphene-water interactions at the nanoscale

Research Project

Project/Area Number 22KF0394
Project/Area Number (Other) 21F21033 (2021-2022)
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeMulti-year Fund (2023)
Single-year Grants (2021-2022)
Section外国
Review Section Basic Section 32020:Functional solid state chemistry-related
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

金 有洙  国立研究開発法人理化学研究所, 開拓研究本部, 主任研究員 (50373296)

Co-Investigator(Kenkyū-buntansha) JACULBIA RAFAEL  国立研究開発法人理化学研究所, 開拓研究本部, 外国人特別研究員
Project Period (FY) 2023-03-08 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2023: ¥200,000 (Direct Cost: ¥200,000)
Fiscal Year 2022: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2021: ¥1,000,000 (Direct Cost: ¥1,000,000)
Keywordsgraphene / STM / Raman spectroscopy / defect / strain / tip enhancement
Outline of Research at the Start

This research will concentrate mainly on the development of a new facility that has not been realized previously. This involves extending the capability of the host laboratory’s STM based tip-enhanced Raman spectroscopy setup to allow for investigating THz-Raman modes of graphene.

Outline of Annual Research Achievements

Graphene is one of the most promising two-dimensional material because of its unique properties. Here, we use STM-based tip enhanced Raman spectroscopy (TERS) to investigate graphene samples. Samples were grown on Au(111) substrates using chemical vapour deposition. Then they were studied using STM imaging, scanning tunneling spectroscopy and STM-TERS. The STM imaging showed Moire patterns and honeycomb structures which are signatures of graphene. The STM-TERS spectra showed the D, 2D, 2D’, and G-band of graphene. Both STS and STM-TERS mapping across an impurity on the sample was performed. We found that the intensity map of the D peak corresponds well to the STS map at around the Fermi level.

Report

(3 results)
  • 2023 Annual Research Report
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (9 results)

All 2023 2022 2021 Other

All Int'l Joint Research (1 results) Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results) Presentation (4 results) (of which Int'l Joint Research: 4 results,  Invited: 4 results) Remarks (1 results)

  • [Int'l Joint Research] University of the Philippines(フィリピン)

    • Related Report
      2021 Annual Research Report
  • [Journal Article] Orbital-resolved visualization of single-molecule photocurrent channels2022

    • Author(s)
      Imai-Imada Miyabi、Imada Hiroshi、Miwa Kuniyuki、Tanaka Yusuke、Kimura Kensuke、Zoh Inhae、Jaculbia Rafael B.、Yoshino Hiroko、Muranaka Atsuya、Uchiyama Masanobu、Kim Yousoo
    • Journal Title

      Nature

      Volume: 603 Issue: 7903 Pages: 829-834

    • DOI

      10.1038/s41586-022-04401-0

    • Related Report
      2022 Annual Research Report 2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomically Precise Delineation of As Antisite Defect States from Undoped Gallium Arsenide Host Lattice by Scanning Tunneling Microscopy and Spectroscopy Measurements and Density Functional Theory Calculations2022

    • Author(s)
      Balgos Maria Herminia M.、Esca?o Mary Clare S.、Jaculbia Rafael B.、Quang Nguyen Tien、Prieto Elizabeth Ann P.、Estacio Elmer S.、Salvador Arnel A.、Somintac Armando S.、Tani Masahiko、Hayazawa Norihiko、Kim Yousoo
    • Journal Title

      physica status solidi (b)

      Volume: 1 Issue: 7 Pages: 2100652-2100652

    • DOI

      10.1002/pssb.202100652

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of detection angle and substrate in the polarization analysis of 1D dipole emission2021

    • Author(s)
      Dasallas Lean、Jaculbia Rafael、Balois-Oguchi Maria Vanessa、Garcia Wilson、Hayazawa Norihiko
    • Journal Title

      Journal of the Optical Society of America B

      Volume: 39 Issue: 1 Pages: 307-307

    • DOI

      10.1364/josab.442109

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Single-molecule resonance tip-enhanced Raman spectroscopy2023

    • Author(s)
      Rafael Buan Jaculbia
    • Organizer
      4th IBS Conference on Surface Atomic Wires and 2nd IBS-RIKEN STM Workshop
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single-molecule Tip-Enhanced Resonance Raman spectroscopy2023

    • Author(s)
      Rafael Buan Jaculbia
    • Organizer
      2023 GIST-RIKEN joint symposium on Forefront Chemistry
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Imaging of a single molecule via STM based Tip Enhanced Resonance Raman spectroscopy2023

    • Author(s)
      Rafael Buan Jaculbia
    • Organizer
      Special seminar at Tongji University
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoraman spectroscopy in low temperature and ultrahigh vacuum environments2022

    • Author(s)
      Rafael Buan Jaculbia
    • Organizer
      40th SPP Physics Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 単一分子光電流計測法の開発

    • URL

      https://www.riken.jp/press/2022/20220331_1/

    • Related Report
      2021 Annual Research Report

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Published: 2021-10-22   Modified: 2024-12-25  

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