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Development of in-situ high-pressure and -temperature chemical analysis technique by femto-second laser-induced breakdown spectroscopy

Research Project

Project/Area Number 23244104
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionOkayama University

Principal Investigator

KANZAKI Masami  岡山大学, 地球物質科学研究センター, 教授 (90234153)

Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥43,030,000 (Direct Cost: ¥33,100,000、Indirect Cost: ¥9,930,000)
Fiscal Year 2013: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2011: ¥31,850,000 (Direct Cost: ¥24,500,000、Indirect Cost: ¥7,350,000)
Keywordsgeofluid / chemical analysis / in-situ / LIBS / diamond anvil cell / plasma / spectroscopy / pulse laser / 高温高圧 / 流体 / その場観察 / レーザー誘起プラズマ / ダイヤモンドアンビル / ブレークダウン分光法 / 地殻流体 / マグマ / プラズマ発光分光 / 高圧その場測定 / 元素分配 / 化学分析 / 分光 / その場測定 / 高温高圧実験
Research Abstract

Slab-derived fluids can contain substantial amounts of silicate components, but it is difficult to quench such fluids, and its composition can not be determined precisely. In this study, I proposed a novel in-situ method for chemical analysis of fluid under high pressure and temperature conditions. In this method, pulsed laser beam is focused in small area of sample within diamond anvil cell (DAC). Plasma will be produced, and then plasma cools down to form neutral atoms. Then characteristic wavelength light inherent to atoms will be emitted. By analyzing this light, we can determine chemical composition of the fluid in DAC.
To evaluate this proposed method, externally-heated DAC, monochrometer, gated-intensifier and CCD detector, and pico-second laser are introduced, So far, high-pressure and temperature fluids have been produced using externally heated DAC, but laser induced plasma light in DAC has not been detected yet.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (36 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 5 results) Presentation (20 results) Remarks (4 results)

  • [Journal Article] Pressure-driven liquid-liquid transformations and corresponding bizzare viscosity behavior, ed. H. Eugene Stanley, in "Liquid Polymorphism"2013

    • Author(s)
      Brazhkin, V.V., Katayama, Y., Kanzaki, M. and Lyapin, A.G.
    • Journal Title

      Advances in Chemical Physics (Wiley.)

      Volume: Vol.152 Pages: 29-50

    • Related Report
      2013 Final Research Report
  • [Journal Article] Pressure-driven liquid-liquid transformations and corresponding bizzare viscosity behavior2013

    • Author(s)
      Brazhkin, V.V., Katayama, Y., Kanzaki, M. and Lyapin, A.G.
    • Journal Title

      Advances in Chemical Physics

      Volume: 152 Pages: 29-50

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures of Zn2SiO4 III and IV synthesized at 6.5–8 GPa and 1,273 K2013

    • Author(s)
      X. Liu, M. Kanzaki, X. Xue
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 40 Issue: 6 Pages: 1-12

    • DOI

      10.1007/s00269-013-0584-6

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Raman and NMR spectroscopic characterization of high-pressure K-cymrite (KAlSi3O8.H2O) and its anhydrous form (kokchetavite)2012

    • Author(s)
      Kanzaki, M., X. Xue, J. Amalberti and Q. Zhang
    • Journal Title

      J. Mineral. Petrol. Sci

      Volume: 107 Pages: 114-119

    • Related Report
      2013 Final Research Report
  • [Journal Article] Distinct 29Si MAS NMR peaks from Si-Al permutation on neighboring T sites of unequal Si-O-T angles : Direct evidence from J-resolved experiment on K-cymrite (KAlSi3O8.H2O)2012

    • Author(s)
      Xue, X. and M. Kanzaki
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 10714-10722

    • Related Report
      2013 Final Research Report
  • [Journal Article] Structural characterization of moganite-type AlPO4 by NMR and powder X-ray diffraction2012

    • Author(s)
      Kanzaki, M. and X. Xue
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Pages: 6164-6172

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Journal Article] Separation of supercritial slab-fluids to form aqueous fluid and melt components in subduction zone magmatism2012

    • Author(s)
      Kawamoto, T., M. Kanzaki, K. Mibe, K.N. Matsukage and S. Ono
    • Journal Title

      Proc. Nat. Acad. Sci

      Volume: 109 Pages: 18695-18700

    • Related Report
      2013 Final Research Report
  • [Journal Article] Measurements of density distribution around Vickers indentation on commercial aluminoborosilicate and soda-lime silicate glasses by using micro Raman spectroscopy2012

    • Author(s)
      Kato, Y., H. Yamazaki, S. Yoshida, J. Matsuoka and M. Kanzaki
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 358 Pages: 3473-3480

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Journal Article] Raman and NMR spectroscopic characterization of high-pressure K-cymrite (KAlSi3O8.H2O) and its anhydrous form (kokchetavite)2012

    • Author(s)
      Kanzaki, M., X. Xue, J. Amalberti and Q. Zhang
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 107 Issue: 19 Pages: 114-119

    • DOI

      10.1021/jp3008859

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Separation of supercritial slab-fluids to form aqueous fluid and melt components in subduction zone magmatism2012

    • Author(s)
      Kawamoto, T., Kanzaki, M., Mibe, K., Matsukage, K. N., Ono, S.
    • Journal Title

      Proc. Nat. Acad. Sci. USA

      Volume: 109 Issue: 46 Pages: 18695-18700

    • DOI

      10.1073/pnas.1207687109

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Raman and NMR spectroscopic characterization of high-pressure K-cymrite (KAlSi3O8.H2O)and its anhydrous form (kokchetavite)2012

    • Author(s)
      Kanzaki, M., Xue, X.
    • Journal Title

      J.Mineral.Petrol.Sci.

      Volume: 107(印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure-induced structural transformations and the anomalous behavior of the viscosity in network chalcogenide and oxide melts2011

    • Author(s)
      Brazhkin, V.V., Y. Katayama, M. Kanzaki, M.V. Koudrin and A.G. Lyapin
    • Journal Title

      JETP Letters

      Volume: 94 Pages: 161-170

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] Spectroscopic study of CO_{2}-bearing magmas,Geofluid 32014

    • Author(s)
      Kanzaki, M. and Xue, X
    • Organizer
      Nature and dynamics of fluids in subduction zones
    • Place of Presentation
      Tokyo Inst. Technology
    • Related Report
      2013 Final Research Report
  • [Presentation] Spectroscopic study of CO_{2}-bearing magmas2014

    • Author(s)
      Masami Kanzaki, Xianyu Xue
    • Organizer
      Geofluid 3: Nature and dynamics of fluids in subduction zones
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸素欠損カルシウム・アルミニウム・ケイ酸塩ペロブスカイトの結晶化学2013

    • Author(s)
      神崎正美・薛献宇・Shufang, Nie
    • Organizer
      日本地球惑星科学連合2013年大会
    • Place of Presentation
      幕張(千葉)
    • Related Report
      2013 Final Research Report
  • [Presentation] ケイ酸塩メルトへの二酸化炭素の溶解機構2013

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2013年大会
    • Place of Presentation
      幕張(千葉)
    • Related Report
      2013 Final Research Report
  • [Presentation] ケイ酸塩メルトへの二酸化炭素の溶解機構2013

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2013年大会
    • Place of Presentation
      幕張メッセ
    • Related Report
      2013 Annual Research Report
  • [Presentation] 第一原理計算によるNMRパラメータの予測 : K-cymriteとAlPO4多形2012

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2011年大会
    • Place of Presentation
      幕張(千葉)
    • Related Report
      2013 Final Research Report
  • [Presentation] アルカリケイ酸塩メルト(ガラス)における水の溶解機構2012

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      日本鉱物科学会2012年度年会
    • Place of Presentation
      京都大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Breakdown of a common notion for 29Si NMR of aluminosilicates : Information from J-resolved and CPMG measurements. Nov. 9, oral (L13)2012

    • Author(s)
      Xianyu Xue and Masami Kanzaki
    • Organizer
      第51回NMR 討論会
    • Place of Presentation
      愛知県名古屋市ウインクあいち
    • Related Report
      2013 Final Research Report
  • [Presentation] Water speciation in sodium silicate glasses (quenched melts) : A comprehensive NMR study Dec. 7, oral (V53F-07)2012

    • Author(s)
      Xianyu Xue, Masami Kanzaki and James Eguchi
    • Organizer
      AGU Fall Meeting
    • Place of Presentation
      San Francisco
    • Related Report
      2013 Final Research Report
  • [Presentation] K-cymrite (KAlSi3O8*H2O)とその無水相のラマン分光2011

    • Author(s)
      神崎正美・薛献宇, J.Amalberti, Q.Zhang
    • Organizer
      日本鉱物科学会2011年大会
    • Place of Presentation
      茨城大学(茨城県)
    • Year and Date
      2011-09-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] モガナイト構造を持つ高圧AlPO4相について2011

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2011年大会
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] K-cymrite(KAlSi3O8*H2O)とその無水相のラマン分光2011

    • Author(s)
      神崎正美,薛献宇,J. Amalberti, Q. Zhang
    • Organizer
      日本鉱物科学会2011年大会
    • Place of Presentation
      水戸
    • Related Report
      2013 Final Research Report
  • [Presentation] K-cymriteの構造と特異な29Si NMR特徴2011

    • Author(s)
      薛献宇,神崎正美
    • Organizer
      日本鉱物科学会2011年大会
    • Place of Presentation
      水戸
    • Related Report
      2013 Final Research Report
  • [Presentation] High-Pressure Phase Transitions in AlPO4 from First-Principles

    • Author(s)
      Wang R. and M. Kanzaki
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 第一原理計算によるNMRパラメータの予測:K-cymriteとAlPO4多形

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2012 Annual Research Report
  • [Presentation] The crystal structures of two Zn2SiO4 high-pressure polymorphs

    • Author(s)
      Liu, X., M. Kanzaki, X. Xue
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Ca2AlSiO5.5欠陥ペロブスカイト低圧相の結晶構造

    • Author(s)
      神崎正美・薛献宇・Wu, Ye
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2012 Annual Research Report
  • [Presentation] アルカリケイ酸塩メルト(ガラス)におけ る水の溶解機構

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      鉱物科学会2012年会
    • Place of Presentation
      京都大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Breakdown of a common notion for 29Si NMR of aluminosilicates: Information from J-resolved and CPMG measurements

    • Author(s)
      Xianyu Xue and Masami Kanzaki
    • Organizer
      第51回NMR討論会
    • Place of Presentation
      名古屋市ウインクあいち
    • Related Report
      2012 Annual Research Report
  • [Presentation] Water speciation in sodium silicate glasses (quenched melts): A comprehensive NMR study,

    • Author(s)
      Xianyu Xue, Masami Kanzaki and James Eguchi
    • Organizer
      AGU fall meeting 2012
    • Place of Presentation
      サンフランシスコ
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.misasa.okayama-u.ac.jp/~masami/

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.misasa.okayama-u.ac.jp/~masami/pukiwiki/

    • Related Report
      2013 Final Research Report
  • [Remarks] Kanza-wiki

    • URL

      http://www.misasa.okayama-u.ac.jp/~masami/pukiwiki/index.php?FrontPage

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.misasa.okayama-u.ac.jp/~masami/pukiwiki/

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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