Reaction and assembly processes of gas-phase clusters in solvents

• Project/Area Number: 23245006
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Physical chemistry
• Research Institution: Kyushu University
• Principal Investigator: TERASAKI Akira 九州大学, 理学(系)研究科(研究院), 教授 (60222147)
• Co-Investigator(Kenkyū-buntansha): ARAKAWA Masashi 九州大学, 大学院理学研究院, 助教 (10610264)
• Research Collaborator: ITO Tomonori ; SARUGAKU Shun ; KOHARA Kei ; ANDO Kota
• Project Period (FY): 2011-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥50,310,000 (Direct Cost: ¥38,700,000、Indirect Cost: ¥11,610,000); Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000); Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2012: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000); Fiscal Year 2011: ¥26,260,000 (Direct Cost: ¥20,200,000、Indirect Cost: ¥6,060,000)
• Keywords: 金属クラスター / 真空中液体 / イオン－分子反応 / 分子吸着 / 溶媒和 / 溶液物理化学 / ナノ材料 / アルミニウム / 銀 / イオン-分子反応

Outline of Final Research Achievements

This research project was conducted for development of novel experimental techniques, which allow gas-phase metal clusters to meet wet chemistry in liquids. The project focused on the following three topics. (1) We have developed an experimental setup for capture of metal clusters into a molecular cluster, which models a liquid solvent. (2) We have succeeded in trapping a liquid droplet generated in a vacuum, which prepares a flask for gas-phase molecules and clusters. Evaporative cooling processes of water and ethylene glycol droplets were observed for tens of seconds, where their thermodynamical features were analyzed. (3) Reaction processes of metal clusters were investigated in solvent molecular gases. For example, formation processes of hydrated-alumina clusters were elucidated for aluminum cluster ions upon reaction with coexisting oxygen and water molecules. These achievements present a milestone toward assembly of clusters for crystalization and functionalization.

Research Products

• [Journal Article] Reaction of aluminum cluster cations with a mixture of O2 and H2O gases: Formation of hydrated-alumina clusters (2015)
  • Author(s): M. Arakawa, K. Kohara, and A. Terasaki
  • Journal Title: J. Phys. Chem. C Volume: 印刷中 Issue: 20 Pages: 10981-10986
  • DOI: 10.1021/jp511293g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Water-Induced Adsorption of Carbon Monoxide and Oxygen on the Gold Dimer Cation (2014)
  • Author(s): T. Ito, et al.
  • Journal Title: The Journal of Physical Chemistry A Volume: (印刷中) Issue: 37 Pages: 8293-8297
  • DOI: 10.1021/jp501111f
  • Peer Reviewed
• [Journal Article] Size-dependent reactivity of aluminum cluster cations toward water molecules (2013)
  • Author(s): M. Arakawa, K. Kohara, T. Ito, and A. Terasaki
  • Journal Title: Eur. Phys. J. D Volume: 67 Issue: 4
  • DOI: 10.1140/epjd/e2013-30677-5
  • Peer Reviewed
• [Journal Article] Coordination-driven magnetic-to-nonmagnetic transition in manganese doped silicon clusters (2013)
  • Author(s): V. Zamudio-Bayer, L. Leppert, K. Hirsch, A. Langenberg, J. Rittmann, M. Kossick, M. Vogel, R. Richter, A. Terasaki, T. Moeller, B. von Issendorff, S. Kuemmel, and J. T. Lau
  • Journal Title: Phys. Rev. B Volume: 88 Issue: 11
  • DOI: 10.1103/physrevb.88.115425
  • Peer Reviewed
• [Journal Article] Build-up processes of an optical cavity enclosing an absorbent thin film : Computational study by the CIP method (2012)
  • Author(s): K.Egashira, et al
  • Journal Title: Eur.Phys.J.D Volume: (印刷中) Issue: 4
  • DOI: 10.1140/epjd/e2012-20587-5
  • Peer Reviewed
• [Journal Article] Spatial distribution of ions in a linear octopole radio-frequency ion trap in the space-charge limit (2012)
  • Author(s): T. Majima, G. Santambrogio, C. Bartels, A. Terasaki, T. Kondow, J. Meinen, and T. Leisner
  • Journal Title: Phys. Rev. A Volume: 85 Issue: 5
  • DOI: 10.1103/physreva.85.053414
  • Peer Reviewed
• [Journal Article] Oxidation processes of chromium dimer and trimer cations in an ion trap (2012)
  • Author(s): T. Ito
  • Journal Title: Chem. Phys. Lett. Volume: 538 Pages: 19-23
  • DOI: 10.1016/j.cplett.2012.04.040
  • Peer Reviewed
• [Journal Article] Spin coupling and orbital angular momentum quenching in free iron clusters (2012)
  • Author(s): M.Niemeyer, et al
  • Journal Title: Phys.Rev.Lett. Volume: 108 Issue: 5
  • DOI: 10.1103/physrevlett.108.057201
  • Peer Reviewed
• [Journal Article] Spatial distribution of ions in a linear octopole radio-frequency ion trap in the space-charge limit (2012)
  • Author(s): T.Majima, et al
  • Journal Title: Phys.Rev.A Volume: (印刷中)
  • Peer Reviewed
• [Journal Article] 原子分子クラスターの生成・捕捉・冷却と分光計測・反応実験 (2012)
  • Author(s): 寺嵜亨
  • Journal Title: 九州大学低温センターだより Volume: 2012年3月(印刷中)
  • NAID: 40019327357
• [Journal Article] Probing structures of small gold cluster cations with dinitrogen (2011)
  • Author(s): G.Naresh Patwari, et al
  • Journal Title: Chemistry-An Asian Journal Volume: 6 Issue: 7 Pages: 1834-1838
  • DOI: 10.1002/asia.201000901
  • Peer Reviewed
• [Journal Article] Optical absorption spectrum of the silver dimer ion : Temperature dependence measured by photodissociation and photon-trap spectroscopy (2011)
  • Author(s): K.Egashira, et al
  • Journal Title: Eur.Phys.J.D Volume: 63 Issue: 2 Pages: 183-187
  • DOI: 10.1140/epjd/e2011-10525-6
  • Peer Reviewed
• [Journal Article] Precise determination of Mg/Fe ratio applicable to terrestrial olivine using Raman spectroscopy (2011)
  • Author(s): Kagi H.
  • Journal Title: Journal of Raman Spectroscopy Volume: 43 Issue: 2 Pages: 331-337
  • DOI: 10.1002/jrs.3024
  • Peer Reviewed
• [Journal Article] The existence of memory effect on hydrogen ordering in ice : The effect makes ice attractive (2011)
  • Author(s): Masahi Arakawa
  • Journal Title: Geophysical Research Letters Volume: 38 Issue: 16 Pages: n/a-n/a
  • DOI: 10.1029/2011gl048217
  • Peer Reviewed
• [Journal Article] 中性子回折による氷結晶の構造解明と惑星科学への応用 (2011)
  • Author(s): 荒川雅, et al
  • Journal Title: 日本惑星科学会誌遊星人 Volume: 20 Pages: 309-316
  • Peer Reviewed
• [Presentation] X-ray spectroscopy of size-selected free clusters for chemical and magnetism analyses (2015)
  • Author(s): 寺嵜 亨
  • Organizer: 東京大学理学部化学教室 第1561回 雑誌会セミナー
  • Place of Presentation: 東京
  • Year and Date: 2015-03-30
  • Invited
• [Presentation] 真空下における液滴トラップ法の開発 (2015)
  • Author(s): 安東航太、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第95春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] 銀クラスター正イオン(8-35 量体)の光解離分光 : サイズ増加にともなう２光子吸収の発現 (2015)
  • Author(s): 飛田健一朗、伊藤智憲、清村侑矢、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第95春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] 銀-コバルト合金クラスターと酸素分子との反応におけるサイズ依存性 (2015)
  • Author(s): 猿楽 峻、村上遼平、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第95春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] Formation of hydrated-alumina clusters toward elucidation of chemical processes on mineral surfaces (2014)
  • Author(s): M. Arakawa, K. Kohara, and A. Terasaki
  • Organizer: Workshop on Interstellar Matter 2014
  • Place of Presentation: 札幌
  • Year and Date: 2014-10-16 – 2014-10-18
• [Presentation] 酸素・水共存環境でのアルミニウムクラスターの反応：ボーキサイト組成クラスターの生成 (2014)
  • Author(s): 荒川 雅、小原 佳、寺嵜 亨
  • Organizer: 第８回分子科学討論会
  • Place of Presentation: 東広島
  • Year and Date: 2014-09-21 – 2014-09-24
• [Presentation] 銀クラスター正イオン8－20量体の光解離分光：サイズ増大によるスペクトルおよび解離過程の変化 (2014)
  • Author(s): 伊藤智憲、飛田健一朗、荒川 雅、寺嵜 亨
  • Organizer: 第８回分子科学討論会
  • Place of Presentation: 東広島
  • Year and Date: 2014-09-21 – 2014-09-24
• [Presentation] 真空中に発生した液滴の蒸発速度と凍結過程 (2014)
  • Author(s): 安東航太、荒川 雅、寺嵜 亨
  • Organizer: 第８回分子科学討論会
  • Place of Presentation: 東広島
  • Year and Date: 2014-09-21 – 2014-09-24
• [Presentation] Reaction of aluminum cluster cations with a mixture of O2 and H2O gases: Formation of hydrated-alumina clusters (2014)
  • Author(s): M. Arakawa, K. Kohara, and A. Terasaki
  • Organizer: Seventeenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 17)
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-07 – 2014-09-12
• [Presentation] Photodepletion spectroscopy of silver cluster cations in a temperature-controlled ion trap (2014)
  • Author(s): T. Ito, K. Tobita, M. Arakawa, and A. Terasaki
  • Organizer: Seventeenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 17)
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-07 – 2014-09-12
• [Presentation] Space-focusing of spatially spread ions in time-of-flight mass spectrometer (2014)
  • Author(s): S. Sarugaku, R. Murakami, M. Arakawa, and A. Terasaki
  • Organizer: Seventeenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 17)
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-07 – 2014-09-12
• [Presentation] Generation of a liquid droplet in a vacuum (2014)
  • Author(s): K. Ando, M. Arakawa, and A. Terasaki
  • Organizer: Seventeenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 17)
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-07 – 2014-09-12
• [Presentation] X-ray absorption spectroscopy of free, size selected, singly metal doped silicon clusters (2014)
  • Author(s): V. Zamudio-Bayer, L. Leppert, K. Hirsch, A. Ławicki, A. Langenberg, J. Rittmann, M. Kossick, M. Vogel, R. Richter, T. Möller, A. Terasaki, S. Kümmel, B. von Issendorff, and J. T. Lau
  • Organizer: Seventeenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 17)
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-07 – 2014-09-12
• [Presentation] Magnetic moments of chromium-doped gold clusters: The Anderson impurity model in finite systems (2014)
  • Author(s): K. Hirsch, V. Zamudio-Bayer, A. Langenberg, M. Niemeyer, B. Langbehn, T. Möller, A. Terasaki, B. von Issendorff, and J. T. Lau
  • Organizer: Seventeenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 17)
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-07 – 2014-09-12
• [Presentation] 水和アルミナクラスターの生成過程：鉱物表面での有機物生成反応の解明を目指して (2014)
  • Author(s): 荒川 雅
  • Organizer: 九重分光関連セミナー
  • Place of Presentation: 大分・九重町
  • Year and Date: 2014-07-25 – 2014-07-26
  • Invited
• [Presentation] Photodissociation spectra of isolated silver cluster cations: size and temperature dependence (2014)
  • Author(s): T. Ito, K. Tobita, M. Arakawa, and A. Terasaki
  • Organizer: 30th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: 姫路
  • Year and Date: 2014-06-04 – 2014-06-06
• [Presentation] 真空中に孤立した金属クラスターの磁性に現れるサイズ効果：Ｘ線磁気円二色性分光と磁気光学分光 (2014)
  • Author(s): 寺嵜 亨
  • Organizer: 第58回日本磁気学会ナノマグネティックス研究会
  • Place of Presentation: 東京
  • Year and Date: 2014-05-23
  • Invited
• [Presentation] イオントラップに蓄積したサイズ選別クラスターのＸ線吸収分光 (2014)
  • Author(s): 早川鉄一郎、江頭和宏、荒川 雅、伊藤智憲、猿楽 峻、安東航太、寺嵜 亨
  • Organizer: ナノ学会第１２回大会
  • Place of Presentation: 宇治
  • Year and Date: 2014-05-22 – 2014-05-24
• [Presentation] アルミニウムクラスター正イオンの解離、酸化、水酸化および水和過程：水・酸素混合気体との反応 (2014)
  • Author(s): 荒川 雅、小原 佳、寺嵜 亨
  • Organizer: ナノ学会第１２回大会
  • Place of Presentation: 宇治
  • Year and Date: 2014-05-22 – 2014-05-24
• [Presentation] Dissociation, oxidation, hydroxylation, and hydration of aluminum cluster cations upon reaction with H2O and O2 (2014)
  • Author(s): M. Arakawa, K. Kohara, and A. Terasaki
  • Organizer: International Bunsen Discussion Meeting: Gas Phase Model Systems for Catalysis (GPMC-2014)
  • Place of Presentation: Ulm, Germany
  • Year and Date: 2014-04-07 – 2014-04-09
  • Invited
• [Presentation] X-ray absorption spectroscoy of size-selected free metal-oxide cluster ions for chemical analysis (2014)
  • Author(s): A. Terasaki, T. Hayakawa, K. Egashira, M. Arakawa, T. Ito, S. Sarugaku, and K. Ando
  • Organizer: Trombay Symposium on Radiation and Photochemistry
  • Place of Presentation: Mumbai, India
  • Invited
• [Presentation] Formation of stable aluminum hydroxide clusters in aluminum-cluster ion beam exposed to O2 and H2O (2014)
  • Author(s): M. Arakawa, K. Kohara, and A. Terasaki
  • Organizer: Trombay Symposium on Radiation and Photochemistry
  • Place of Presentation: Mumbai, India
  • Invited
• [Presentation] 酸化セリウムクラスター(Ce3O4+, Ce3O6+)のＸ線吸収分光 (2014)
  • Author(s): 早川鉄一郎、江頭和宏、荒川 雅、伊藤智憲、猿楽 峻、安東航太、寺嵜 亨
  • Organizer: 第27回日本放射光学会年会
  • Place of Presentation: 広島
• [Presentation] サイズ選別した酸化セリウムクラスター（Ce2O3+, Ce2O5+）のＸ線吸収分光 (2014)
  • Author(s): 早川鉄一郎、江頭和宏、荒川 雅、伊藤智憲、猿楽 峻、安東航太、寺嵜 亨
  • Organizer: 日本物理学会 第69回年次大会
  • Place of Presentation: 平塚
• [Presentation] サイズ選別された金属酸化物クラスターイオンのＸ線吸収分光：酸化セリウムの局在電荷測定 (2014)
  • Author(s): 荒川 雅、早川鉄一郎、江頭和宏、伊藤智憲、 猿楽 峻、安東航太、寺嵜亨
  • Organizer: 日本化学会 第94春季年会
  • Place of Presentation: 名古屋
• [Presentation] アルミニウムクラスター正イオンと酸素／水混合気体の反応：水和化合物の生成過程 (2014)
  • Author(s): 小原 佳、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第94春季年会
  • Place of Presentation: 名古屋
• [Presentation] 真空中における液滴の生成と蒸発冷却 (2014)
  • Author(s): 安東航太、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第94春季年会
  • Place of Presentation: 名古屋
• [Presentation] クロム２量体正イオンの光吸収スペクトル (2014)
  • Author(s): 江頭和宏、山田裕里佳、北 幸海、立川仁典、寺嵜 亨
  • Organizer: 日本化学会 第94春季年会
  • Place of Presentation: 名古屋
• [Presentation] X-ray spectroscopy of size-selected free metal-oxide clusters for oxidation-state analysis (2013)
  • Author(s): T. Hayakawa, K. Egashira, M. Arakawa, T. Ito, S. Sarugaku, K. Ando, and A. Terasaki
  • Organizer: Asian Consortium on Computational Materials Science
  • Place of Presentation: 仙台
• [Presentation] Reaction of size-selected aluminum cluster cations toward H2O and O2: Formation of stable products (2013)
  • Author(s): K. Kohara, M. Arakawa, T. Ito, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 岡崎
• [Presentation] Sequential adsorption of nitrogen molecules on size-selected silver cluster cations (2013)
  • Author(s): T. Ito, Y. Taniguchi, M. Arakawa, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 岡崎
• [Presentation] Improvement of Wiley-McLaren-type time-of-flight mass spectrometer for continuous ion beam (2013)
  • Author(s): S. Sarugaku, M. Arakawa, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 岡崎
• [Presentation] Liquid micro-droplet formation in a vacuum (2013)
  • Author(s): K. Ando, M. Arakawa, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 岡崎
• [Presentation] Spin and orbital magnetic moments, magnetic-to-nonmagnetic transitions, and the Anderson impurity model in finite systems: XMCD studies on free size-selected clusters (2013)
  • Author(s): K. Hirsch, V. Zamudio-Bayer, L. Leppert, A. Langenberg, A. Terasaki, T. Moeller, S. Kuemmel, B. von Issendorff, and J. T. Lau
  • Organizer: The Sixth International Symposium “Atomic Cluster Collisions”
  • Place of Presentation: Wuhan, China
• [Presentation] H2OおよびO2との反応によるアルミニウムクラスター正イオンの解離、酸化、水和 (2013)
  • Author(s): 荒川 雅、小原 佳、伊藤智憲、寺嵜 亨
  • Organizer: ナノ学会第１１回大会
  • Place of Presentation: 東京
• [Presentation] 銀クラスター正イオンへの窒素分子の逐次吸着：イオントラップを用いた反応測定 (2013)
  • Author(s): 伊藤智憲、谷口祐樹、荒川 雅、寺嵜 亨
  • Organizer: ナノ学会第１１回大会
  • Place of Presentation: 東京
• [Presentation] 不均一な加速電場を用いた連続イオンビームの飛行時間型質量分析 (2013)
  • Author(s): 猿楽 峻、荒川 雅、寺嵜 亨
  • Organizer: ナノ学会第１１回大会
  • Place of Presentation: 東京
• [Presentation] 真空中への液滴導入法の開発 (2013)
  • Author(s): 安東航太、荒川 雅、寺嵜 亨
  • Organizer: ナノ学会第１１回大会
  • Place of Presentation: 東京
• [Presentation] クロム２量体正イオンの電子基底状態：対称性に基づいた考察 (2013)
  • Author(s): 江頭和宏、山田裕里佳、北 幸海、立川仁典、寺嵜 亨
  • Organizer: 第７回分子科学討論会
  • Place of Presentation: 京都
• [Presentation] 線形イオントラップに捕捉した銀クラスター正イオンの光解離分光 (2013)
  • Author(s): 伊藤智憲、荒川 雅、寺嵜 亨
  • Organizer: 第７回分子科学討論会
  • Place of Presentation: 京都
• [Presentation] アルミニウムクラスター正イオンと酸素・水混合気体との反応で生じる安定化学種の構造 (2013)
  • Author(s): 小原 佳、荒川 雅、寺嵜 亨
  • Organizer: 第７回分子科学討論会
  • Place of Presentation: 京都
• [Presentation] イオントラップに蓄積した酸化セリウムクラスターのＸ線吸収測定 (2013)
  • Author(s): 早川鉄一郎、江頭和宏、荒川 雅、伊藤智憲、猿楽 峻、安東航太、寺嵜 亨
  • Organizer: 第７回分子科学討論会
  • Place of Presentation: 京都
• [Presentation] Solvation and reaction of metal clusters: Toward cluster assembly (2013)
  • Author(s): A. Terasaki
  • Organizer: Symposium on Size Selected Clusters 2013
  • Place of Presentation: Davos, Switzerland
  • Invited
• [Presentation] Selectivity in the reaction channels of aluminum cluster cations toward H2O (2013)
  • Author(s): M. Arakawa, K. Kohara, T. Ito, and A. Terasaki
  • Organizer: Symposium on Size Selected Clusters 2013
  • Place of Presentation: Davos, Switzerland
• [Presentation] Water-promoted molecular adsorption of O2 and CO on the gold dimer cation (2013)
  • Author(s): T. Ito, M. Arakawa, and A. Terasaki
  • Organizer: Symposium on Size Selected Clusters 2013
  • Place of Presentation: Davos, Switzerland
• [Presentation] Magnetic moments of chromium-doped gold clusters: The Anderson impurity model in finite systems (2013)
  • Author(s): K. Hirsch, V. Zamudio-Bayer, A. Langenberg, M. Niemeyer, B. Langbehn, T. Moller, A. Terasaki, B. von Issendorff, and J. T. Lau
  • Organizer: Symposium on Size Selected Clusters 2013
  • Place of Presentation: Davos, Switzerland
• [Presentation] Spin and orbital magnetic moments of size-selected free iron, cobalt, and nickel clusters from x-ray magnetic circular dichroism spectroscopy (2013)
  • Author(s): A. Langenberg, K. Hirsch, V. Zamudio-Bayer, A. Lawicki, M. Niemeyer, P. Chmiela, B. Langbehn, A. Terasaki, T. Moller, B. von Issendorff, and J. T. Lau
  • Organizer: Symposium on Size Selected Clusters 2013
  • Place of Presentation: Davos, Switzerland
• [Presentation] Coordination-driven magnetic-to-nonmagnetic transition in manganese doped silicon clusters (2013)
  • Author(s): L. Leppert, V. Zamudio-Bayer, K. Hirsch, A. Langenberg, J. Rittmann, M. Kossick, M. Vogel, R. Richter, A. Terasaki, T. Moller, B. von Issendorff, S. Kummel, and J. T. Lau
  • Organizer: Symposium on Size Selected Clusters 2013
  • Place of Presentation: Davos, Switzerland
• [Presentation] アルミニウムクラスター正イオンと酸素および水分子との反応にける安定化学種の生成とその同定 (2013)
  • Author(s): 小原 佳、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第93春季年会
  • Place of Presentation: 滋賀県草津市
• [Presentation] セリウム窒化物クラスター正イオンの生成と反応性の研究 (2013)
  • Author(s): 伊藤圭樹、伊藤智憲、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第93春季年会
  • Place of Presentation: 滋賀県草津市
• [Presentation] 共吸着水分子による金２量体正イオンへのO2およびCO分子吸着の促進 (2013)
  • Author(s): 伊藤智憲、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第93春季年会
  • Place of Presentation: 滋賀県草津市
• [Presentation] 連続クラスターイオンビームのリアルタイムなサイズ分布分析を目的とした飛行時間型質量分析計 (2013)
  • Author(s): 猿楽 峻、荒川 雅、寺嵜 亨
  • Organizer: 日本化学会 第93春季年会
  • Place of Presentation: 滋賀県草津市
• [Presentation] Reaction of size-selected aluminum cluster cations toward H2O and O2: Formation of stable products (2013)
  • Author(s): K. Kohara, M. Arakawa, T. Ito, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 愛知県岡崎市
• [Presentation] Sequential adsorption of nitrogen molecules on size-selected silver cluster cations (2013)
  • Author(s): T. Ito, Y. Taniguchi, M. Arakawa, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 愛知県岡崎市
• [Presentation] Improvement of Wiley-McLaren-type time-of-flight mass spectrometer for continuous ion beam (2013)
  • Author(s): S. Sarugaku, M. Arakawa, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 愛知県岡崎市
• [Presentation] Liquid micro-droplet formation in a vacuum (2013)
  • Author(s): K. Ando, M. Arakawa, and A. Terasaki
  • Organizer: Workshop on "Fundamentals and Applications of Laser Filaments"
  • Place of Presentation: 愛知県岡崎市
• [Presentation] サイズ選別された鉄クラスターイオンのX線磁気円二色性分光 (2012)
  • Author(s): 寺嵜亨
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-25
• [Presentation] クロム2量体正イオンの電子状態:可視吸収及びX線磁気円二色性分光法による測定 (2012)
  • Author(s): 江頭和宏
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-25
• [Presentation] 質量選別したアルミニウムクラスター正イオンと水分子との反応 (2012)
  • Author(s): 荒川雅
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-25
• [Presentation] 銀クラスター正イオンへの窒素分子の吸着過程 (2012)
  • Author(s): 伊藤智憲
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-25
• [Presentation] Advanced spectroscopic studies of size-selected free metal clusters (2012)
  • Author(s): A.Terasaki
  • Organizer: Asian Consortium on Computational Materials Science-Virtual Organization (ACCMS-VO)
  • Place of Presentation: 仙台
  • Year and Date: 2012-02-10
• [Presentation] Progress in spectroscopic studies of free metal clusters toward materials science (2012)
  • Author(s): A.Terasaki
  • Organizer: GRI Symposium III on Cluster Science : Functionality of Clusters (GRIS 3)
  • Place of Presentation: 名古屋
  • Year and Date: 2012-02-01
• [Presentation] Magnetism of size-selected free metal cluster ions studied by X-ray magnetic circular dichroism (XMCD) spectroscopy (2012)
  • Author(s): A.Terasaki
  • Organizer: GRI Symposium III on Cluster Science : Functionality of Clusters (GRIS 3)
  • Place of Presentation: 名古屋
  • Year and Date: 2012-02-01
• [Presentation] Photon-trap absorption spectroscopy of the chromium dimer cation toward elucidation of its magnetic properties (2012)
  • Author(s): K.Egashira
  • Organizer: GRI Symposium III on Cluster Science : Functionality of Clusters (GRIS 3)
  • Place of Presentation: 名古屋
  • Year and Date: 2012-02-01
• [Presentation] Oxidation processes of chromium dimer and trimer cations in an ion trap (2012)
  • Author(s): T.Ito
  • Organizer: GRI Symposium III on Cluster Science : Functionality of Clusters (GRIS 3)
  • Place of Presentation: 名古屋
  • Year and Date: 2012-02-01
• [Presentation] Water-induced high reactivity of the gold dimer cation with carbon monoxide (2012)
  • Author(s): T.Ito
  • Organizer: GRI Symposium III on Cluster Science : Functionality of Clusters (GRIS 3)
  • Place of Presentation: 名古屋
  • Year and Date: 2012-02-01
• [Presentation] Magnetism study of size-selected free metal clusters by laser and X-ray spectroscopy (2012)
  • Author(s): A.Terasaki
  • Organizer: Trombay Symposium on Radiation and Photochemistry (TSRP-2012)
  • Place of Presentation: Mumbai, India(招待講演)
  • Year and Date: 2012-01-04
• [Presentation] Magnetic properties of size-selected free cluster ions studied by X-ray magnetic circular dichroism spectroscopy (2012)
  • Author(s): A. Terasaki, K. Egashira, M. Niemeyer, K. Hirsch, A. Langenberg, V. Zamudio-Bayer, M. Vogel, M. Kossick, C. Ebrecht, T. Moller, B. von Issendorff, J. T. Lau
  • Organizer: 28th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: 福岡県春日市
• [Presentation] Structural and kinetics studies of nitrogen adsorption on silver cluster cations (2012)
  • Author(s): Y. Taniguchi, T. Ito, M. Arakawa, and A. Terasaki
  • Organizer: 28th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: 福岡県春日市
• [Presentation] Reaction of size-selected aluminum cluster cations with water molecules (2012)
  • Author(s): K. Kohara, T. Ito, M. Arakawa, and A Terasaki
  • Organizer: 28th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: 福岡県春日市
• [Presentation] Design of a TOF spectrometer for a continuous cluster ion beam (2012)
  • Author(s): S. Sarugaku, M. Arakawa, and A. Terasaki
  • Organizer: 28th Symposium on Chemical Kinetics and Dynamics
  • Place of Presentation: 福岡県春日市
• [Presentation] Ｘ線磁気円二色性分光によるサイズ選別された鉄クラスターの磁性研究 (2012)
  • Author(s): A. Terasaki, K. Egashira, M. Niemeyer, K. Hirsch, A. Langenberg, V. Zamudio-Bayer, M. Vogel, M. Kossick, C. Ebrecht, T. Moller, B. von Issendorff, and J. T. Lau
  • Organizer: ナノ学会第１０回大会
  • Place of Presentation: 大阪
• [Presentation] アルミニウムクラスター正イオンと水分子との反応におけるサイズ依存性 (2012)
  • Author(s): 荒川 雅、小原 佳、伊藤智憲、寺嵜 亨
  • Organizer: ナノ学会第１０回大会
  • Place of Presentation: 大阪
• [Presentation] Advances in high-sensitivity laser spectroscopy for clusters and nanostructures (2012)
  • Author(s): A. Terasaki
  • Organizer: Sixteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 16)
  • Place of Presentation: Leuven, Belgium
  • Invited
• [Presentation] Size-dependent reactivity and stability of aluminum cluster cations toward water molecules (2012)
  • Author(s): M. Arakawa, K. Kohara, T. Ito, and A. Terasaki
  • Organizer: Sixteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 16)
  • Place of Presentation: Leuven, Belgium
• [Presentation] Light modulation by an ultrathin absorbent in an optical cavity: a computational study (2012)
  • Author(s): K. Egashira and A. Terasaki
  • Organizer: Sixteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 16)
  • Place of Presentation: Leuven, Belgium
• [Presentation] Electronic structure and magnetic properties of doped gold clusters (2012)
  • Author(s): K. Hirsch, A. Lawicki, M. Niemeyer, A. Langenberg, V. Zamudio-Bayer, M. Vogel, M. Kossick, C. Ebrecht, K. Egashira, A. Terasaki, T. Moller, B. von Issendorff, T. Lau
  • Organizer: Sixteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 16)
  • Place of Presentation: Leuven, Belgium
• [Presentation] Electronic and magnetic propertiesof pure manganese and of manganese doped silicon clusters (2012)
  • Author(s): V. Zamudio-Bayer, K. Hirsch, A. Langenberg, A. Lawicki, J. Rittmann, M. Kossick, M. Niemeyer, A. Terasaki, T. Moller, B. von Issendorff, T. Lau
  • Organizer: Sixteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 16)
  • Place of Presentation: Leuven, Belgium
• [Presentation] Spin coupling and orbital angular momentum quenching in size selected free iron and cobalt clusters: XMCD study (2012)
  • Author(s): A. Lawicki, M. Niemeyer, K. Hirsch, A. Langenberg, V. Zamudio-Bayer, M. Vogel, M. Kossick, C. Ebrecht, K. Egashira, A. Terasaki, T. Moller, B. von Issendorff, T. Lau
  • Organizer: Sixteenth International Symposium on Small Particles and Inorganic Clusters (ISSPIC 16)
  • Place of Presentation: Leuven, Belgium
• [Presentation] Spin coupling, orbital angular momentum quenching, and electron localization in size-selected free transition metal clusters (2012)
  • Author(s): K. Hirsch, M. Niemeyer, V. Zamudio-Bayer, A. Langenberg, A. Lawicki, B. Langbehn, M. Kossick, A. Terasaki, T. Moller, B. von Issendorff, and J. T. Lau
  • Organizer: 19th International Conference on Magnetism
  • Place of Presentation: Busan, Korea
• [Presentation] イオントラップを用いた微量イオン種の超高感度分光：吸収分光、磁気光学分光、Ｘ線磁気円二色性分光 (2012)
  • Author(s): 寺嵜 亨
  • Organizer: 九重分光関連セミナー
  • Place of Presentation: 大分県九重町
  • Invited
• [Presentation] Spin coupling, orbital angular momentum quenching, and electron localization in size-selected free transition metal clusters (2012)
  • Author(s): J. T. Lau, K. Hirsch, V. Zamudio-Bayer, A. Langenberg, M. Niemeyer, M. Kossick, B. Langbehn, A. Terasaki, T. Moller, and B. von Issendorff
  • Organizer: Joint European Magnetic Symposia
  • Place of Presentation: Parma, Italy
• [Presentation] X-ray magnetic circular dichroism spectroscopy of size-selected molecules, clusters, and complexes in a cryogenic linear ion trap (2012)
  • Author(s): J. T. Lau, K. Hirsch, V. Zamudio-Bayer, A. Langenberg, M. Niemeyer, M. Kossick, B. Langbehn, A. Terasaki, T. Moller, and B. von Issendorff
  • Organizer: Joint European Magnetic Symposia
  • Place of Presentation: Parma, Italy
• [Presentation] アルミニウムクラスターの反応性と安定性：エッチング反応によるAl7+の生成 (2012)
  • Author(s): 荒川 雅、小原 佳、伊藤智憲、寺嵜 亨
  • Organizer: 第６回分子科学討論会
  • Place of Presentation: 東京
• [Presentation] 共吸着効果による金クラスター正イオンへの酸素分子吸着の誘発 (2012)
  • Author(s): 伊藤智憲、伊藤圭樹、安東航太、荒川 雅、寺嵜 亨
  • Organizer: 第６回分子科学討論会
  • Place of Presentation: 東京
• [Presentation] 連続的なイオンビームの分析を目的とする飛行時間型質量分析計の開発 (2012)
  • Author(s): 猿楽 峻、荒川 雅、寺嵜 亨
  • Organizer: 第６回分子科学討論会
  • Place of Presentation: 東京
• [Presentation] Atomic and molecular clusters: Novel material properties in finite-size regime (2012)
  • Author(s): A. Terasaki
  • Organizer: The 2nd International Congress on Natural Sciences with Sisterhood Universities (ICNS2012)
  • Place of Presentation: Kaohsiung, Taiwan
  • Invited
• [Presentation] 強誘電性氷の生成を促すメモリー効果の発見と惑星科学への応用 (2011)
  • Author(s): 荒川雅
  • Organizer: 第29回Grain Formation Workshop/平成23年度銀河のダスト研究会
  • Place of Presentation: 神戸(招待講演)
  • Year and Date: 2011-11-11
• [Presentation] Magnetism study of size-selected free cluster ions by magneto-optical spectroscopy and XMCD (2011)
  • Author(s): A.Terasaki
  • Organizer: International Workshop DyNano-2011 : "Structure and Dynamics of Nano-Objects Using Short Wavelength Radiation"
  • Place of Presentation: 京都(招待講演)
  • Year and Date: 2011-10-03
• [Presentation] XAS, XPS, and XMCD of size-selected cluster ions : from electronic and geometric structure to magnetic phase transitions (2011)
  • Author(s): T.Lau
  • Organizer: International Workshop DyNano-2011 : "Structure and Dynamics of Nano-Objects Using Short Wavelength Radiation"
  • Place of Presentation: 京都(招待講演)
  • Year and Date: 2011-10-03
• [Presentation] Ideal Heisenberg coupling in small ferromagnetic manganese clusters (2011)
  • Author(s): V.Zamudio-Bayer
  • Organizer: International Workshop DyNano-2011: "Structure and Dynamics of Nano-Objects Usine Short Wavelength Radiation"
  • Place of Presentation: 京都
  • Year and Date: 2011-10-03
• [Presentation] X線磁気円二色性分光による気相サイズ選別クラスターの磁気特性研究 (2011)
  • Author(s): 寺嵜亨
  • Organizer: 第5回分子科学討論会
  • Place of Presentation: 札幌
  • Year and Date: 2011-09-20
• [Presentation] フォトントラップ分光法によるクロム2量体イオンの光吸収測定 (2011)
  • Author(s): 江頭和宏
  • Organizer: 第5回分子科学討論会
  • Place of Presentation: 札幌
  • Year and Date: 2011-09-20
• [Presentation] 水分子付加による金2量体イオンの結合エネルギーの変化 (2011)
  • Author(s): 伊藤智憲
  • Organizer: 第5回分子科学討論会
  • Place of Presentation: 札幌
  • Year and Date: 2011-09-20
• [Presentation] Water induced CO adsorption on gold dimer cation (2011)
  • Author(s): 伊藤智憲
  • Organizer: 第27回化学反応討論会
  • Place of Presentation: 東京
  • Year and Date: 2011-06-08
• [Presentation] X線磁気円二色性分光による孤立クラスターの磁性研究 (2011)
  • Author(s): 寺嵜亨
  • Organizer: ナノ学会第9回大会
  • Place of Presentation: 札幌
  • Year and Date: 2011-06-02
• [Book] Physics and Chemistry of Ice 2010 (2011)
  • Author(s): M.Arakawa, et al
  • Publisher: Hokkaido University Press
• [Book] Physics and Chemistry of Ice 2010 (2011)
  • Author(s): H.Fukazawa, et al
  • Publisher: Hokkaido University Press
• [Remarks] 量子化学研究室ホームページ
  • URL: http://www.scc.kyushu-u.ac.jp/quantum/index_j.php
• [Remarks] 量子化学研究室ホームページ
  • URL: http://www.scc.kyushu-u.ac.jp/quantum/index_j.php
• [Remarks] 九州大学大学院理学研究院化学部門量子化学研究室
  • URL: http://www.scc.kyushu-u.ac.jp/quantum/index_j.php
• [Remarks]
  • URL: http://www.scc.kyushu-u.ac.jp/quantum/index_j.php