| Budget Amount *help |
¥50,180,000 (Direct Cost: ¥38,600,000、Indirect Cost: ¥11,580,000)
Fiscal Year 2014: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2012: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2011: ¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
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| Outline of Final Research Achievements |
In this research project, we promoted (a) the establishment of construction method of the interaction space having flexible structure and electronic state by reasonable controlling the organized structure of functional metal complexes and the placement of interaction parts, (b) the expression of specific guest-responsivity by cooperative coupling between framework and guest molecules, and (c) the elucidation of the mechanism of guest responsivity by in situ physical property measurements under the guest atmosphere. We mainly focused on the responsivity to chemical stimulation, and succeeded in (1) the control of spin state through host-guest interaction and the elucidation of its mechanism, (2) the improvement of responsivity by meso-crystallization, (3) the creation of guest-responsive luminescent porous frameworks, and (4) the creation of composites between coordination polymers and liposome by introducing lipophilicity into the building unit.
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