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Studies on the dynamic behavior of quasi-liquid layers on ice crystal surfaces by advanced optical microscopy

Research Project

Project/Area Number 23246001
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionHokkaido University

Principal Investigator

SAZAKI GEN  北海道大学, 低温科学研究所, 教授 (60261509)

Co-Investigator(Kenkyū-buntansha) FURUKAWA Yoshinori  北海道大学, 低温科学研究所, 特任教授 (20113623)
NAGASHIMA Ken  北海道大学, 低温科学研究所, 助教 (60436079)
MURATA Ken-ichiro  北海道大学, 低温科学研究所, 助教 (60646272)
Research Collaborator ASAKAWA Harutoshi  北海道大学, 低温科学研究所, 博士研究員
KIYOTA Tatsuo  北海道大学, 大学院理学研究科宇宙理学専攻
INOMATA Masahiro  北海道大学, 大学院理学研究科宇宙理学専攻
Project Period (FY) 2011-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥49,660,000 (Direct Cost: ¥38,200,000、Indirect Cost: ¥11,460,000)
Fiscal Year 2014: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2013: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2012: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2011: ¥26,260,000 (Direct Cost: ¥20,200,000、Indirect Cost: ¥6,060,000)
Keywords氷 / 表面融解 / 疑似液体層 / 単位ステップ / 高分解光学顕微法 / ラマン分光法 / 原子間力顕微法 / 擬似液体層 / 原子間力顕微鏡法
Outline of Final Research Achievements

We first devised an observation chamber in which temperature of sample ice crystals and supersaturation of water vapor can be controlled separately. Then we obtained the following five findings. 1) Only under supersaturated condition (higher than a critical value), two types of quasi-liquid layer (QLL) phases with drop and thin-layer shapes are formed on ice basal faces. 2) Strain formed around lattice defects in ice crystals significantly induces the formation of the two QLL phases. 3) On prism and other high-index faces, the two QLL phases with the drop and thin-layer shapes are also formed in the temperature ranges similar to those on basal faces. 4) Volume diffusion (in a bulk gas phase) and surface diffusion (on basal faces) of water vapor molecules govern the lateral advancement rate of elementary steps on ice basal faces. 5) On basal faces, spiral steps formed by screw dislocations exhibit a double-spiral structure because of a crystallographic requirement.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (54 results)

All 2015 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 3 results) Presentation (36 results) (of which Invited: 12 results) Book (1 results) Remarks (8 results)

  • [Journal Article] Double spiral steps on Ih ice crystal surfaces grown from water vapor just below the melting point2014

    • Author(s)
      G. Sazaki, H. Asakawa, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 5 Pages: 2133-2137

    • DOI

      10.1021/cg4014448

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Roles of surface/volume diffusion in the growth kinetics of elementary spiral steps on ice basal faces grown from water vapor2014

    • Author(s)
      H. Asakawa, G. Sazaki, E. Yokoyama, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 7 Pages: 3210-3220

    • DOI

      10.1021/cg4014653

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Antifreeze effect of carboxylated e-poly-L-lysine on the growth kinetics of ice crystals2014

    • Author(s)
      D. A. Vorontsov, G. Sazaki, S. H. Hyon, K. Matsumura, Y. Furukawa
    • Journal Title

      J. Phys. Chem. B

      Volume: 118 Issue: 34 Pages: 10240-10249

    • DOI

      10.1021/jp507697q

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The attachment and detachment processes of individual lysozyme molecules on a surface of a monoclinic lysozyme crystal studied by fluorescent single-molecule visualization2014

    • Author(s)
      G. Dai, L. Zhen, G. Sazaki, Y. Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 10 Pages: 5303-5309

    • DOI

      10.1021/cg501122f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 氷ベーサル面上での形態が異なる2種類の擬似液体層の生成過程2014

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Journal Title

      Int. J. Microgravity Sci. Appl.

      Volume: 31 Pages: 100-105

    • NAID

      130007842470

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 高分解光学顕微鏡でみる氷結晶の成長素過程と表面融解2013

    • Author(s)
      佐﨑 元,サルバドール ゼペダ,中坪俊一,古川義純
    • Journal Title

      日本食品科学工学会誌

      Volume: 60 Pages: 445-449

    • NAID

      10031190020

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] How do Quasi-Liquid Layers Emerge from Ice Crystal Surfaces?2013

    • Author(s)
      Gen Sazaki, Harutoshi Asakawa, Ken Nagashima, Shunichi Nakatsubo, and Yoshinori Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 13 (4) Issue: 4 Pages: 1761-1766

    • DOI

      10.1021/cg400086j

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 氷結晶の表面融解過程の光学その場観察2013

    • Author(s)
      佐﨑 元,サルバドール ゼペダ,中坪俊一,古川義純
    • Journal Title

      応用物理

      Volume: 82 Pages: 150-153

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 氷結晶表面での単位ステップと擬似液体層の直接光学観察2013

    • Author(s)
      佐﨑 元,サルバドール ゼペダ,中坪俊一,古川義純
    • Journal Title

      低温科学

      Volume: 71 Pages: 1-13

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 結晶の融解過程における動的階層性2015

    • Author(s)
      村田憲一郎,麻川明俊,長嶋 剣,古川義純,佐﨑 元
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス(東京都新宿区)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 氷結晶表面で生成する2種類の擬似液体層の安定性2015

    • Author(s)
      麻川明俊,佐﨑 元,村田憲一郎,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス(東京都新宿区)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 氷ベーサル面の成長に与える塩化水素ガスの効果2015

    • Author(s)
      長嶋 剣,佐﨑 元,羽馬哲也,麻川明俊,村田憲一郎,中坪俊一,古川義純
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス(東京都新宿区)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] In situ observation of surface melting processes of ice crystals by advanced optical microscopy2015

    • Author(s)
      G. Sazaki, H. Asakawa, K. Murata, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      International Symposium on Semiconductor Materials and Devices
    • Place of Presentation
      Anna University, Chennnai, India
    • Year and Date
      2015-02-02 – 2015-02-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 氷結晶の自励振動成長-国際宇宙ステーション実験の概要-2014

    • Author(s)
      古川義純,長嶋 剣,麻川明俊,中坪俊一,村田憲一郎,佐﨑 元,吉崎 泉,田丸晴香,島岡太郎,曽根武彦,真木孝雄,山本明日桂
    • Organizer
      第44回結晶成長国内会議
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 氷ベーサル面の成長に与える塩化水素ガスの効果2014

    • Author(s)
      長嶋 剣,佐﨑 元,羽馬哲也,麻川明俊,村田憲一郎,中坪俊一,古川義純
    • Organizer
      第44回結晶成長国内会議
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 氷プリズム面上での2種類の擬似液体層の生成過程2014

    • Author(s)
      麻川明俊,佐﨑 元,村田憲一郎,長嶋 剣,中坪俊一,古川義純
    • Organizer
      第44回結晶成長国内会議
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Growth kinetics of elementary steps on ice basal faces grown from saturated water vapor2014

    • Author(s)
      H. Asakawa, G. Sazaki, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      6th Asian Conference on Crystal Growth and Crystal Technology
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-06-11 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Generation of two types of quasi-liquid-layer phases on ice basal faces2014

    • Author(s)
      H. Asakawa, G. Sazaki, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      6th Asian Conference on Crystal Growth and Crystal Technology
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-06-11 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Growth of ice crystals in the presence of carboxylated e-poly-L- lysine2014

    • Author(s)
      D. Vorontsov, G. Sazaki, S.H. Hyon, K. Matsumura, Y. Furukawa
    • Organizer
      6th Asian Conference on Crystal Growth and Crystal Technology
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-06-11 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 結晶成長実験のための画像定量解析技術の最前線2014

    • Author(s)
      横峰 誠,佐藤久夫,塚本勝男,佐﨑 元
    • Organizer
      日本地球惑星科学連合2014年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉県千葉市美浜区)
    • Year and Date
      2014-04-28 – 2014-05-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] How do quasi-liquid layers emerge from ice crystal surfaces?2014

    • Author(s)
      G. Sazaki, H. Asakawa, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      13th International Conference on the Physics and Chemistry of Ice
    • Place of Presentation
      Dartmouth University, Hanover, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Double spiral steps on Ih ice crystal surfaces grown from water vapor just below the melting point2014

    • Author(s)
      G. Sazaki, H. Asakawa, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      13th International Conference on the Physics and Chemistry of Ice
    • Place of Presentation
      Dartmouth University, Hanover, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Thermodynamic stabilities of two types of quasi-liquid layer phases on ice basal faces2014

    • Author(s)
      H. Asakawa, G. Sazaki, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      13th International Conference on the Physics and Chemistry of Ice
    • Place of Presentation
      Dartmouth University, Hanover, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Growth kinetics of elementary steps on ice basal faces grown from supersaturated water vapor2014

    • Author(s)
      H. Asakawa, G. Sazaki, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      13th International Conference on the Physics and Chemistry of Ice
    • Place of Presentation
      Dartmouth University, Hanover, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 氷結晶表面の擬似液体 層の生成機構と 熱力学的安定性2014

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパ ス,神奈川県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 気相から成長する氷結晶の単位ステップの成長カイネティクス2014

    • Author(s)
      麻川明俊,佐﨑 元,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパ ス,神奈川県
    • Related Report
      2013 Annual Research Report
  • [Presentation] Thermodynamic stabilities of quasi-liquid layers on ice basal faces2013

    • Author(s)
      G. Sazaki, H. Asakawa, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      2nd Fusion Materials Special Meeting
    • Place of Presentation
      Arcadia Ichigaya, Tokyo, Japan
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] n-situ observation of emergeneces of quasi-liquid layers from ice basal faces by advanced optical microscopy2013

    • Author(s)
      G. Sazaki, H. Asakawa, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      The 17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      The University of Warsaw, Warsaw, Poland
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Thermodynamic stabilities of two types of quasi-liquid layers on basal faces of ice crystals2013

    • Author(s)
      H. Asakawa, G. Sazaki, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Organizer
      The 17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      The University of Warsaw, Warsaw, Poland
    • Related Report
      2013 Annual Research Report
  • [Presentation] Atomic or molecular resolution investigation of soluble crystals in liquid by frequency-modulation (non-contat) AFM2013

    • Author(s)
      K Nagashima, G. Sazaki, H. Asakawa, Y. Furukawa
    • Organizer
      The 17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      The University of Warsaw, Warsaw, Poland
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of carboxylated e-poly-L-lysine on crystallization of ic2013

    • Author(s)
      D. Vorontsov, G. Sazaki, S.H. Hyon, K. Matsumura, Y. Furukawa
    • Organizer
      The 17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      The University of Warsaw, Warsaw, Poland
    • Related Report
      2013 Annual Research Report
  • [Presentation] 氷結晶表面上の渦巻ステップの構造について2013

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      第43回結晶成長国内会議
    • Place of Presentation
      長野市生涯学習センター,長野県
    • Related Report
      2013 Annual Research Report
  • [Presentation] 氷ベーサル面上での単位ステップの成長カイネティクス2013

    • Author(s)
      麻川明俊,佐﨑 元,長嶋 剣,中坪俊一,古川義純
    • Organizer
      第43回結晶成長国内会議
    • Place of Presentation
      長野市生涯学習センター,長野県
    • Related Report
      2013 Annual Research Report
  • [Presentation] 氷結晶の表面融解過程の高分解光学観察2013

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本化学会有機結晶部会第22回有機結晶シンポジウム
    • Place of Presentation
      北海道大学札幌キャンパス,北海道
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 氷ベーサル面上での渦巻ステップの構造について2013

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス,徳島県
    • Related Report
      2013 Annual Research Report
  • [Presentation] 氷結晶表面の光学その場観察:表面融解による擬似液体層の生成2013

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      第40回食品の物性に関するシンポジウム
    • Place of Presentation
      ルポール讃岐,香川県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 氷結晶表面での擬似液体層生成過程の光学その場観察2013

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      資源・素材学会
    • Place of Presentation
      北海道大学札幌キャンパス,北海道
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 氷結晶底面での表面液体相(擬似液体層)の生成と歪みの効果2013

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      2013年日本結晶成長学会特別講演会
    • Place of Presentation
      キャンパスイノベーションセンター東京国際会議室,東京都
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 氷ベーサル面上での単位ステップの成長カイネティクス2013

    • Author(s)
      麻川明俊,佐﨑 元,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会2013年年次大会
    • Place of Presentation
      広島大学東広島キャンパス (東広島市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 高分解光学顕微鏡でみる氷結晶の成長素過程と表面融解2012

    • Author(s)
      佐﨑 元,サルバドール・ゼペダ,中坪俊一,古川義純
    • Organizer
      第4回研究小集会:食品と水,日本食品科学工学会第59回大会
    • Place of Presentation
      藤女子大学 (札幌市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 歪みにより誘起される氷結晶表面での疑似液体層の生成2012

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学 (横浜市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 氷表面上での疑似液体層の生成挙動に対するガスの影響2012

    • Author(s)
      麻川明俊,佐崎 元,長嶋 剣,中坪俊一,古川義純
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学 (横浜市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 氷結晶底面での表面液体相の生成と歪みの効果2012

    • Author(s)
      佐﨑 元,麻川明俊,長嶋 剣,中坪俊一,古川義純
    • Organizer
      シンポジウム:結晶表面---最近の理論とその場観察,第42回結晶成長国内会議
    • Place of Presentation
      九州大学筑紫キャンパス (福岡県春日市)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 氷表面で生成する擬似液体層の安定性2012

    • Author(s)
      麻川明俊,佐﨑 元,長嶋 剣,中坪俊一,古川義純
    • Organizer
      第42回結晶成長国内会議
    • Place of Presentation
      九州大学筑紫キャンパス (福岡県春日市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 非接触原子間力顕微鏡による原子・分子レベルでの溶液成長観察2012

    • Author(s)
      長嶋 剣,阿部真之,森田清三,大田昌弘,粉川良平,佐﨑 元,古川義純
    • Organizer
      第42回結晶成長国内会議
    • Place of Presentation
      九州大学筑紫キャンパス (福岡県春日市)
    • Related Report
      2012 Annual Research Report
  • [Book] Surface and Interface Science2014

    • Author(s)
      Y. Furukawa, G. Sazaki, H. Nada
    • Publisher
      WILEY-VCH Verlag & Co. KGaA
    • Related Report
      2013 Annual Research Report
  • [Remarks] 北海道大学 低温科学研究所 相転移ダイナミクス研究グループ

    • URL

      http://www.lowtem.hokudai.ac.jp/ptdice/

    • Related Report
      2014 Annual Research Report
  • [Remarks] Well come to the home page of Sazaki Project

    • URL

      http://www7b.biglobe.ne.jp/%7Esazaki/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 北海道大学低温科学研究所相転移ダイナミクス研究グループ

    • URL

      http://www.lowtem.hokudai.ac.jp/ptdice/

    • Related Report
      2013 Annual Research Report
  • [Remarks] Well come to the home page of Sazaki project!

    • URL

      http://www7b.biglobe.ne.jp/~sazaki/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 相転移ダイナミクス研究分野

    • URL

      http://www.lowtem.hokudai.ac.jp/ptdice/

    • Related Report
      2012 Annual Research Report
  • [Remarks] 寒冷圏非平衡科学

    • URL

      http://www.lowtem.hokudai.ac.jp/soshiki/noneq.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] Well come to the home page of Sazaki Project!

    • URL

      http://www7b.biglobe.ne.jp/~sazaki/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.lowtem.hokudai.ac.jp/soshiki/noneq.html

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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