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Characterization and Analysis of Molecular Configuration in Chiral Smectic Sub-phases by Resonant X-ray Scattering with synchrotron microbeam

Research Project

Project/Area Number 23246007
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

IIDA Atsuo  大学共同利用機関法人高エネルギー加速器研究機構, 加速器科学支援センター, シニアフェロー (10143398)

Co-Investigator(Kenkyū-buntansha) TAKANISHI Yoichi  京都大学, 大学院理学(系)研究科(研究院), 准教授 (80251619)
Project Period (FY) 2011-05-31 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥34,970,000 (Direct Cost: ¥26,900,000、Indirect Cost: ¥8,070,000)
Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2012: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Fiscal Year 2011: ¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Keywords液晶 / 放射光科学 / 結晶工学 / 共鳴X線散乱 / X線マイクロビーム / 相転移 / 分子間相互作用 / 局所解析 / 共鳴X線散乱 / X線マイクロビーム
Research Abstract

By developing the local resonat X-ray scattering technique using a synchrotron X-ray microbeam, novel sub-phases appearing in the chiral smectic liquid crystals were studies and new information about the inter molecular interaction and the phase transition mechanism has been obtained. A sub-phase with a six-layer periodicity which appeared between the ferroelectric and the antiferroelectric phases was found in the chiral smectic liquid crystal mixture and it agreeed well with the theoretical model. During the electric field induced phase transition, a 12-layer periodicity phase appeared. An x-ray intensity analysis suggested that the molecular configuration realized in this phase was the new intermediate phase between the adjacent phases.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (23 results)

All 2014 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 9 results) Presentation (13 results) (of which Invited: 2 results)

  • [Journal Article] Local Orientational Analysis of Helical Filaments and Nematic Director in a Nano-scale Phase Separation Composed of Rod-like and Bent-core Liquid Crystals using Small- and Wide-angle X-ray Microbeam Scattering2014

    • Author(s)
      Takanishi, Yoichi ; Yao, Haruhiko ; Fukasawa, Takuya ; Ema, Kenji ; Ohtsuka, Youko ; Takahashi, Yumiko ; Yamamoto, Jun ; Takezoe, Hideo ; Iida, Atsuo
    • Journal Title

      J. Phys. Chem. B

      Volume: 118 Issue: 14 Pages: 3998-4004

    • DOI

      10.1021/jp410201t

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral smectic transition phases appearing near the electric field-induced phase transition observed by resonant micro-beam X-ray scattering2014

    • Author(s)
      Atsuo Iida, Isa Nishiyama and Yoichi Takanishi
    • Journal Title

      Phys. Rev

      Volume: E 89 Issue: 3

    • DOI

      10.1103/physreve.89.032503

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Layer modulated smectic-C phase in liquid crystals with a terminal hydroxyl group2014

    • Author(s)
      Y.Kimoto, A.Nishizawa, Y.Takanishi, A.Yoshizawa and J.Yamamoto
    • Journal Title

      Phys. Rev. E

      Volume: 89 Issue: 4 Pages: 42503-42503

    • DOI

      10.1103/physreve.89.042503

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Smectic-C* liquid crystals with six-layer periodicity appearing between the ferroelectric and antiferroelectric chiral smectic phases2013

    • Author(s)
      Yoichi Takanishi, Isa Nishiyama, Jun Yamamoto, Youko Ohtsuka, and Atsuo Iida
    • Journal Title

      Phys. Rev.E

      Volume: 87 Issue: 5 Pages: 50503-50503

    • DOI

      10.1103/physreve.87.050503

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synchrotron Radiation X-ray Fluorescence Spectrometry2013

    • Author(s)
      A.Iida
    • Journal Title

      Encyclopedia of Analytical Chemistry, (eds R.A. Meyers, John Wiley : Chichester

      Pages: 1-23

    • DOI

      10.1002/9780470027318.a9329

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Smectic C ast liquid crystals with six-layer periodicity appearing between the ferroelectric and antiferroelectric chiral smectic phases2013

    • Author(s)
      Yoichi TAKANISHI
    • Journal Title

      Physical Review E

      Volume: 印刷中

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Synchrotron X-Ray Microbeam Characterization of Smectic A Liquid Crystals Under Electric Field2012

    • Author(s)
      Atsuo Iida and Yoichi Takanishi
    • Journal Title

      Adv. X-ray Anal. (Eds. T. Blanton and F.Harvilla)

      Volume: Vol.55 Pages: 73-79

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] X-ray waveguide mode in resonance with a periodic structure2012

    • Author(s)
      Kouhei Okamoto
    • Journal Title

      Physical Review Letters

      Volume: 109 Issue: 23

    • DOI

      10.1103/physrevlett.109.233907

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synchrotron X-Ray Microbeam Characterization of Smectic A Liquid Crystals under Electric Field2012

    • Author(s)
      Atsuo Iida
    • Journal Title

      Advances in X-ray Analysis

      Volume: 55 Pages: 73-79

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synchrotron X-Ray Microbeam Characterization of Smectic A Liquid Crystals under Electric Field2012

    • Author(s)
      Atsuo Iida, Yoichi Takanishi
    • Journal Title

      Advance in X-ray Analysis

      Volume: (印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] X 線位置検出器を用いた走査型X 線イメージングシステムの検討2014

    • Author(s)
      向出大平、山川英充、高田一広、長尾昌志、野間 敬、飯田厚夫
    • Organizer
      第27回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      広島国際会議場、広島, 13P096
    • Year and Date
      2014-01-13
    • Related Report
      2013 Final Research Report
  • [Presentation] X線位置検出器と2次元検出器を用いた走査型X線イメージングシステムの検討2014

    • Author(s)
      向出大平、山川英充、高田一広、長尾昌志、野間敬、飯田厚夫
    • Organizer
      第27回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      広島国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 共鳴X 線散乱測定による強誘電・反強誘電相の間に出現する副次相の構造解析―6層周期副次相の発見―2013

    • Author(s)
      高西陽一、西山伊佐、山本潤、大塚洋子、飯田厚夫
    • Organizer
      液晶学会討論会
    • Place of Presentation
      大阪大学 3a10
    • Year and Date
      2013-09-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Structure analysis of smectic C* variant phases appearing between ferroelectric and antiferroelectric phases by resonant X-ray scattering2013

    • Author(s)
      Yoichi Takanishi, Isa Nishiyama, Jun Yamamoto, Youko Ohtsuka, and Atsuo Iida
    • Organizer
      Collaborative Conf. on Materials Research
    • Place of Presentation
      Korea, Jeju
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 共鳴X線散乱測定による強誘電・反強誘電相の間に出現する副次相の構造解析 -6層周期副次相の発見-2013

    • Author(s)
      高西陽一,西山伊佐,山本潤,大塚洋子,飯田厚夫
    • Organizer
      液晶学会討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structure analysis of Smectic C* variant phases appearing between ferroelectric and antiferroelectric phases by resonant X-ray scattering2013

    • Author(s)
      Y.TAKANISHI, I. NISHIYAMA, J.YAMAMOTO, Y. OHTSUKA and A. IIDA
    • Organizer
      CCMR2013(Collaborative Conf. on Materials Research)
    • Place of Presentation
      Korea, Jeju
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Smectic C* variant with six-layer periodicity appearing between ferroelectric and antiferroelectric chiral smectic phases2012

    • Author(s)
      Yoichi Takanisi
    • Organizer
      Asian Liquid Crystal conference
    • Place of Presentation
      富士吉田
    • Year and Date
      2012-12-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 含臭素屈曲型液晶の超構造に関するキラル添加効果-μビーム共鳴X 線散乱による解析-2012

    • Author(s)
      高西陽一、飯田厚夫
    • Organizer
      2012年日本液晶学会
    • Place of Presentation
      千葉大
    • Year and Date
      2012-09-07
    • Related Report
      2013 Final Research Report
  • [Presentation] The effect of lateral substituent on the molecular ordering of chiral smectic phases in a novel bromocontaining dichiral compound2012

    • Author(s)
      Yoichi Takanishi
    • Organizer
      Int. Liquid Crystal conference
    • Place of Presentation
      Mainz, Germany
    • Year and Date
      2012-08-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Synchrotron X-Ray Microbeam Characterization of Smectic A Liquid Crystals under Electric Field2011

    • Author(s)
      Atsuo Iida and Yoichi Takanishi
    • Organizer
      Denver X-ray Conference
    • Place of Presentation
      Colorado Springs, USA
    • Year and Date
      2011-08-01
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] The effect of lateral substituent on the molecular ordering of chiral smectic phases in a novel bromo-containing dichiral compound

    • Author(s)
      Yoichi TAKANISHI
    • Organizer
      International Liquid Crystal Conference, ILCC 2012 Mainz
    • Place of Presentation
      ドイツ、マインツ
    • Related Report
      2012 Annual Research Report
  • [Presentation] Smectic C* variant with six-layer periodicity appearing between ferroelectric and antiferroelectric chiral smectic phases

    • Author(s)
      Yoichi TAKANISHI
    • Organizer
      Asian Liquid Crystal Conference
    • Place of Presentation
      富士吉田
    • Related Report
      2012 Annual Research Report
  • [Presentation] 含臭素 屈曲型液晶の超構造に関するキラル添加効果ーμビーム共鳴X線散乱によ る解析ー

    • Author(s)
      髙西 陽一
    • Organizer
      2012年日本液晶学会討論会
    • Place of Presentation
      千葉大
    • Related Report
      2012 Annual Research Report

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Published: 2011-06-18   Modified: 2019-07-29  

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