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Construction of Organic Semiconductor Superlattices by soft solution process

Research Project

Project/Area Number 23310078
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionKumamoto University

Principal Investigator

KUNITAKE Masashi  熊本大学, 自然科学研究科, 教授 (40205109)

Co-Investigator(Kenkyū-buntansha) UEMURA Shinobu  香川大学, 工学部, 講師 (60423498)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2012: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
KeywordsSTM / 化学液相成長 / 有機半導体 / 超薄膜 / 超格子 / COF / ソフト溶液プロセス / 自己組織化 / 高分子合成 / 高分子構造・物性 / 走査ブローブ顕微鏡 / 表面・界面物性 / 電子・電気材料 / 結晶性π共役高分子 / 表面反応 / 高次構造 / その場反応
Research Abstract

Colorful p-conjugated nanofilms with unique mesostructures formed spontaneously on hydrophobic substrates from aqueous solutions in the presence of simple aromatic building block molecules under ambient conditions. We thus report the results of surface-mediated polycondensation and chemical liquid deposition. The Schiff base coupling reaction applied for this soft solution process is a dynamic reversible covalent coupling reaction that can be managed by careful changes in solution conditions based on adsorption and polymerization equilibria. This low-cost and eco-friendly bottom-up method allows great diversity in terms of the design of primary polymeric chemical structures by the selection of building blocks without the need to consider the solubility of the polymer. This paves the way to a true bottom-up assembly of a vast array of solid-supported, designer supramolecular nanoarchitectures with potential use as functional materials for next-generation organic electronics.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (46 results)

All 2014 2013 2012 2011 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (29 results) (of which Invited: 8 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Self-assembled π -conjugated macromolecular architectures - A soft solution process based on Schiff-base coupling2014

    • Author(s)
      Kunitake, M. ; Higuchi, R. ; Tanoue, R. ; Uemura, S.
    • Journal Title

      Current Opinion in Colloid & Interface Science

      Volume: (印刷中) Issue: 2 Pages: 140-154

    • DOI

      10.1016/j.cocis.2014.03.003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Positional selectivity of reversible azomethine condensation reactions at solid/liquid interfaces leading to supramolecule formation2014

    • Author(s)
      Tanoue, R. ; Higuchi, R. ; Ikebe, K. ; Uemura, S. ; Kimizuka, N. ; Stieg, A. Z. ; Gimzewski, J. K. ; Kunitake
    • Journal Title

      Journal of Electroanalytical Chemistry

      Volume: 716 Pages: 145-149

    • DOI

      10.1016/j.jelechem.2013.11.022

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Self-Assembly of Two-Dimensional π-Conjugated Metal-Porphyrin Covalent Organic Frameworks by "On-Site" Equilibrium Polymerization2013

    • Author(s)
      R. Tanoue, R. Higuchi, K. Ikebe, S. Uemura, N. Kimizuka, A. Z. Stieg, J. K. Gimzewski, M. Kunitake
    • Journal Title

      J. Nanosci/Nanotechnol

      Volume: 13 Issue: 3 Pages: 1-6

    • DOI

      10.1166/jnn.2014.8540

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Vertically standing nanowalls of pristine poly (azomethine) on a graphite by chemicalliquid deposition2013

    • Author(s)
      R. Higuchi, R. Tanoue, K. Sakaguchi, K. Yanai, S. Uemura, M. Kunitake
    • Journal Title

      Polymers

      Volume: 54(14) Issue: 14 Pages: 3452-3457

    • DOI

      10.1016/j.polymer.2013.04.065

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Control of 2D Bicomponent Porous Networks of Melamine and Melem : Diverse Hydrogen-Bonded Networks2013

    • Author(s)
      S. Uemura, M. Aono, K. Sakata, T. Komatsu, M. Kunitake
    • Journal Title

      The Journal of Physical Chemistry

      Volume: 117(47) Issue: 47 Pages: 24815-24821

    • DOI

      10.1021/jp406810c

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 界面で作る規則構造性高分子超分子からナノデバイスを目指して2013

    • Author(s)
      國武雅司
    • Journal Title

      高分子,高分子の新展開

      Volume: 62(9) Pages: 519-523

    • NAID

      10031193302

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 界面で作る規則構造性高分子 超分子からナノデバイスを目指して2013

    • Author(s)
      國武雅司
    • Journal Title

      高分子, 高分子の新展開

      Volume: 62(9) Pages: 519-523

    • NAID

      10031193302

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Self-Assembly of Two-Dimensional π-Conjugated Metal–Porphyrin Covalent Organic Frameworks by “On-Site” Equilibrium Polymerization2013

    • Author(s)
      R. Tanoue, R. Higuchi, K. Ikebe, S. Uemura1, N. Kimizuka, A. Z. Stieg, J. K. Gimzewski and M. Kunitake
    • Journal Title

      J. Nanosci/ Nanotechnol.

      Volume: 未定

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemically-Controlled 2D Assembly of Paddle-wheel Diruthenium Complexes on the Au(111) Surface and Identification of their Redox States2012

    • Author(s)
      S. Yoshimoto, K. Sakata, R. Kuwahara, K. Kuroiwa, N. Kimizuka, M. Kunitake
    • Journal Title

      The Journal of Physical Chemistry

      Volume: 116(33) Issue: 33 Pages: 17729-17733

    • DOI

      10.1021/jp305951d

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ STM Investigation of Aromatic Poly(azomethine) Arrays Constructed by "On-Site"Equilibrium Polymerization2012

    • Author(s)
      Tanoue, R. Higuchi, R. Ikebe, K. Uemura, S.Kimizuka, N. Stieg, A. Z. Gimzewski, J. K. Kunitake, M.
    • Journal Title

      Langmuir

      Volume: 28 Issue: 39 Pages: 13844-13851

    • DOI

      10.1021/la302863h

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Liquid Deposition of π-Conjugated Polymers onto Graphite by Spontaneous On-Site Polycondensation in Aqueous Solution2012

    • Author(s)
      R. Higuchi, R. Tanoue, N. Enoki, S. Katahira, Y. Miyasato, K. Sakaguchi, S. Uemura, N. Kimizuka, M. Kunitake
    • Journal Title

      Chem. Commun

      Volume: 48(25) Issue: 25 Pages: 3103-3105

    • DOI

      10.1039/c2cc16975d

    • Related Report
      2013 Final Research Report 2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 液液・固液界面での化学反応を利用した高分子ナノ材料の創成2012

    • Author(s)
      樋口倫太郎、甲斐嵩平、坂口和樹、上村忍、國武雅司
    • Journal Title

      ネットワークポリマー

      Volume: 33(2) Pages: 146-153

    • NAID

      130004648282

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 反応・吸着の同時平衡制御を利用した二次元規則性高分子ナノ構造の自己組織的構築2011

    • Author(s)
      田上亮太、國武雅司
    • Journal Title

      Colloid & Interface Commun

      Volume: 36 Pages: 24-26

    • NAID

      40020187500

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] ソフト溶液プロセスによる芳香族超薄膜の化学液相成長2013

    • Author(s)
      國武雅司
    • Organizer
      第21回日本ポリイミド・芳香族系高分子会議
    • Place of Presentation
      岡山
    • Year and Date
      2013-12-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 電気化学STMで観察した固液界面その場反応によるナノ構造制御2013

    • Author(s)
      國武雅司
    • Organizer
      電気化学会第80回大会,招2G10
    • Place of Presentation
      仙台
    • Year and Date
      2013-03-30
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 相互作用バランス制御から生まれる高分子の階層的構造制御,依頼講演2013

    • Author(s)
      國武雅司
    • Organizer
      第58回高分子夏季大学
    • Place of Presentation
      広島
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ STM Investigation of 2D Self-Assembly of Melem at the pH-Controlled Aqueous Solution/Au(111) Interfaces2013

    • Author(s)
      K.Nishimae,Y.Nakamura,S.Uemura,M.Kunitake
    • Organizer
      2013 Kyushu-Seibu/Pusan-Gyeongnam Joint Symposium on High Polymers (15th) and Fibers(14th)
    • Place of Presentation
      Saga University, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] STM Investigation of Self-assemble Behavior of Heptazine Derivatives at Solution-Au(111) Interfaces2013

    • Author(s)
      Y.Nakamura, S.Uemura, M. Kunitake
    • Organizer
      12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM)
    • Place of Presentation
      Auckland, New Zealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] Nanoarchitectures of Porphyrin 2-D Covalent Frameworks Based on a Spontaneous Equilibrium Polycondensation at Solid-liquid Interface2013

    • Author(s)
      R.Tanoue, K.Ikebe, R.Higuchi, S.Uemura, M.Kunitake
    • Organizer
      12th International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM)
    • Place of Presentation
      Auckland, New Zealand
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固液界面におけるSchiff baseカップリングを利用した蛍光性π共役高分子薄膜の作製2013

    • Author(s)
      梁井海洋、樋口倫太郎、坂口和樹、田上亮太、上村忍、國武雅司
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都国際会館
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固-液界面におけるヘプタジン環誘導体の自己組織化挙動のSTM観察2013

    • Author(s)
      中村優佑、上村忍、國武雅司
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場およびAIMビル
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固液界面を利用した蛍光性ポリアゾメチン薄膜の作製2013

    • Author(s)
      梁井海洋、樋口倫太郎、坂口和樹、田上亮太、上村忍、國武雅司
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場およびAIMビル
    • Related Report
      2013 Annual Research Report
  • [Presentation] 様々な手法による窒化炭素薄膜の基板上への作製とその形状評価2013

    • Author(s)
      西前建吾, 上村忍、國武雅司
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 窒化炭素薄膜の基板上での作製と形状評価2013

    • Author(s)
      西前建吾, 上村忍、國武雅司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヘプタジン環誘導体のナノ集合体の構築とその機能評価2013

    • Author(s)
      中村優佑, 上村忍、國武雅司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Annual Research Report
  • [Presentation] 相互作用バランス制御から生まれる高分子の階層的構造制御2013

    • Author(s)
      國武 雅司
    • Organizer
      第58回高分子夏季大学 -未来を拓く高分子-
    • Place of Presentation
      広島国際会議場
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ソフト溶液プロセスによる芳香族超薄膜の化学液相成長2013

    • Author(s)
      國武 雅司
    • Organizer
      第21回日本ポリイミド・芳香族系高分子会議
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Aromatic Poly(azomethine)-based Photovoltaic Cells Prepared by Chemical Liquid Deposition2013

    • Author(s)
      樋口倫太郎
    • Organizer
      7th International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      福岡国際会議場
    • Related Report
      2012 Annual Research Report
  • [Presentation] 電気化学STMで観察した固液界面その場反応によるナノ構造制御2013

    • Author(s)
      國武雅司
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      東北大学川内キャンパス
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 2-D and 3-D Polymeric Nano-Architectures Prepared on Substrates using Soft Solution2012

    • Author(s)
      M. Kunitake
    • Organizer
      ICEAN2012
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Self-Assembly of 2-D Nanoarchitectures Based on Adsorption / Reaction Equilibriums in Solutions,依頼講演2012

    • Author(s)
      M. Kunitake
    • Organizer
      2012 Supramolecular Chemistry Conference in Lanzarote
    • Place of Presentation
      Spain
    • Related Report
      2013 Final Research Report
  • [Presentation] 固液界面におけるSchiff baseカップリングを利用した多様なπ共役高分子薄膜の作製2012

    • Author(s)
      樋口倫太郎
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 固液界面選択的な可逆反応による2次元自己組織化構造の構築とその場STM観察2012

    • Author(s)
      田上亮太
    • Organizer
      九州地区高分子若手研究会 ・夏の講演会
    • Place of Presentation
      ホテルクラウンパレス小倉
    • Related Report
      2012 Annual Research Report
  • [Presentation] 化学液相成長法により形成したポリアゾメチン薄膜を利用した有機薄膜太陽電池の作製2012

    • Author(s)
      坂口和樹
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 両連続相マイクロエマルション構造を反映したBMEハイブリッドゲルの作成と動的ミクロ構造評価2012

    • Author(s)
      坂田耕平
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水中での化学液相成長法による芳香族ポリアゾメチンナノウォールの作製2012

    • Author(s)
      樋口倫太郎
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Photovoltaic Cells Based on Poly(azomethine)s Prepared by Chemical Liquid Deposition2012

    • Author(s)
      樋口倫太郎
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Annual Research Report
  • [Presentation] 2 ‐ D and 3 ‐ D Polymeric Nano ‐ Architectures Prepared on Substrates using Soft Solution2012

    • Author(s)
      國武雅司
    • Organizer
      ICEAN2012
    • Place of Presentation
      ブリスベン,オーストラリア
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 固液界面における化学液相成長に基づくπ共役ポリアゾメチン薄膜の作製2012

    • Author(s)
      坂口和樹
    • Organizer
      ポリマー材料フォーラム
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2012 Annual Research Report
  • [Presentation] Self-Assembly of 2-D Nanoarchitectures Based on Adsorption/Reaction Equilibriums in Solutions2012

    • Author(s)
      國武雅司
    • Organizer
      2012 Supramolecular Chemistry Conference
    • Place of Presentation
      Lanzarote, Spain(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Construction and In-Situ Observation of Polymeric Nanoarchitectures on Surfaces Prepared by Soft Solution Processes2011

    • Author(s)
      M. Kunitake
    • Organizer
      2011 Pusan-Gyeongnam/ Kyushu-Seibu Joint Symposium on High Polymers (15th) and Fibers (13th)
    • Place of Presentation
      Busan
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Construction and In-Situ Observation of Polymeric Nanoarchitectures on Surfaces Prepared by Soft Solution Processes2011

    • Author(s)
      國武雅司
    • Organizer
      2011 Pusan-Gyeongnam/Kyushu-Seibu Joint Symposium on High Polymers (15th) and Fibers (13th)
    • Place of Presentation
      Pusan National University, Busan, Korea(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Book] 界面その場成長による高分子ナノシートの創成「高分子ナノテクノロジーハンドブック~最新ポリマーABC技術を中心に~」,第3編高分子ナノ加工第2章ナノサイズマテリアル第3節薄膜,西敏夫編集2014

    • Author(s)
      國武雅司,上村忍
    • Publisher
      株式会社 NTS
    • Related Report
      2013 Final Research Report
  • [Book] 界面その場成長による高分子ナノシートの創成 「高分子ナノテクノロジー ハンドブック~最新ポリマーABC技術を中心に~」2014

    • Author(s)
      國武 雅司、上村 忍
    • Total Pages
      5
    • Publisher
      株式会社 NTS
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://chem.chem.kumamoto-u.ac.jp/~polymers/

    • Related Report
      2013 Final Research Report
  • [Remarks] 國武研究室のホームページ

    • URL

      http://chem.chem.kumamoto-u.ac.jp/~polymers/

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2011-04-06   Modified: 2019-07-29  

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