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Development of novel ultralight and superstrong hybrid materials made of low density metals/alloys reinforced with boron nitride nanotubes for automobile and aerospace applications

Research Project

Project/Area Number 23310082
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionNational Institute for Materials Science

Principal Investigator

GOLBERG Dmitri  独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, ユニット長 (80354405)

Co-Investigator(Kenkyū-buntansha) BANDO Yoshio  (独)物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 最高運営責任者 (10344433)
ZHI ChunYi (ZHI Chunyi)  独立行政法人物質・材料研究機構, その他部局等, 研究員 (50469764)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2011: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords複合材料 / 低密度金属 / 電子顕微鏡 / ナノチューブ / 機能的機能 / 機械的機能
Research Abstract

Aluminum/Boron nitride nanotube (BNNT) composites with up to 5 wt% (i.e. 9.7 vol%) nanotube fractions were prepared via various powder metallurgy routes, namely, Spark Plasma Sintering (SPS) and High Pressure Torsion (HPT) methods. Optical microscopy, transmission electron microscopy, scanning electron microscopy, X-ray diffraction, and energy dispersive X-ray analysis confirmed the integration of the two phases into decently dense and compact composites. No other phases, like Al borides or nitrides, form in the Al-BNNTs macrocomposites of the two series. The hardness of HPT samples was drastically increased with increasing BNNTs content in Al pellets. The value for Al-BNNT 3.0 wt% sample was more than doubled (190 MPa) compared to a pure Al HPT compact (90 MPa). And the room temperature ultimate tensile strength of Al-BNNTs HPT samples containing 3.0 wt% BNNT (~300 MPa) became ~1.5 times larger than that of a BNNT-free HPT Al compact (~200 MPa).

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (39 results)

All 2014 2013 2012 2011 Other

All Journal Article (21 results) (of which Peer Reviewed: 21 results) Presentation (11 results) (of which Invited: 6 results) Book (2 results) Remarks (4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Powder metallurgy routes toward aluminum/boron nitride nanotube composites, their morphologies, structures and mechanical properties2014

    • Author(s)
      Yamaguchi M., Meng F., Firestein K., Tsuchiya K., Golberg D.
    • Journal Title

      J. Mater. Sci. & Eng. A.

      Volume: 604 Pages: 9-17

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nano boron nitride flatland2014

    • Author(s)
      Pakdel A., Bando Y., Golberg D.
    • Journal Title

      Chem. Soc. Rev.

      Volume: 43 Pages: 934-959

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dispersion of boron nitride nanotubes in aqueous solution by simple aromatic molecules2014

    • Author(s)
      Kim D., Sawada T., Zhi C.Y., Bando Y., Golberg D., Serizawa T.
    • Journal Title

      J. Nanosci. Nanotech.

      Volume: 14 Issue: 4 Pages: 3028-3033

    • DOI

      10.1166/jnn.2014.8579

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Length fractionation of boron nitride nanotubes using creamed oil-in-water emulsions2014

    • Author(s)
      Lau Y.-T. R., Yamaguchi M., Li X., Bando Y., Golberg D., Winnick F.M.
    • Journal Title

      Langmuir

      Volume: 30 Issue: 7 Pages: 1735-1740

    • DOI

      10.1021/la404961p

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and characteristics of melt-spun Al ribbons reinforced with nano/micro-BN phases2013

    • Author(s)
      Yamaguchi M., Bernhardt J., Faerstein K., Shtansky D., Bando Y., Golovin I.S., Sinning H.R., Golberg D.
    • Journal Title

      Acta Mater.

      Volume: 61(20) Issue: 20 Pages: 7604-7615

    • DOI

      10.1016/j.actamat.2013.08.062

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nonwetting “white” graphene films2013

    • Author(s)
      Pakdel A., Wang X., Bando Y., Golberg D.
    • Journal Title

      Acta Mater

      Volume: 61 Issue: 4 Pages: 1266-1273

    • DOI

      10.1016/j.actamat.2012.11.002

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transmission electron microscope as an ultimate tool for nanomaterial property studies.2013

    • Author(s)
      N. Kawamoto,^* D. -M. Tang, X. Wei, X. Wang, M. Mitome, Y. Bando, D. Golberg^*
    • Journal Title

      J Electron Microscope

      Volume: 62 Issue: 1 Pages: 157-175

    • DOI

      10.1093/jmicro/dfs078

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonwetting and optical properties of BN nanosheet films2013

    • Author(s)
      Pakdel A., Wang X., Bando Y., Shtansky D., Golberg D.
    • Journal Title

      Surface Innovations

      Volume: 1 Issue: 1 Pages: 32-39

    • DOI

      10.1680/si.12.00007

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thin boron nitride nanotubes with exceptionally high strength and toughness2013

    • Author(s)
      Huang Y., Lin J., Zou J., Wang M.S., Faerstein K., Bando Y. Golberg D.
    • Journal Title

      Nanoscale

      Volume: 5 Issue: 11 Pages: 4840-4846

    • DOI

      10.1039/c3nr00651d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphology-driven nonwettability of nanostructured BN surfaces2013

    • Author(s)
      Pakdel A., Bando Y., Golberg D.
    • Journal Title

      Langmuir

      Volume: 29 Issue: 24 Pages: 7529-7533

    • DOI

      10.1021/la4004356

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Weak morphology dependent valence band structure of boron nitride2013

    • Author(s)
      Zhi C.Y., Ueda S., Zeng H., Wang X., Tian W., Wang X., Bando Y., Golberg D.
    • Journal Title

      J. Appl. Phys.

      Volume: 114 Issue: 5

    • DOI

      10.1063/1.4817430

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of multiwalled boron nitride nanotubes for the reinforcement of lightweight aluminum ribbons2013

    • Author(s)
      Yamaguchi M., Pakdel A., Zhi C.Y., Bando Y., Tang D.M., Faerstein K., Shtansky D.V., Golberg D.
    • Journal Title

      Nanoscale Research Letters

      Volume: 8 Issue: 1

    • DOI

      10.1186/1556-276x-8-3

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural changes of BN nanotubes by Al ion irradiation2013

    • Author(s)
      Obraztsova E.A., Shtansky D.V., Sheveyko A.N., Yamaguchi M., Kovalskii A.M., Mevellec J.-Y., Lefrant S., Golberg D.
    • Journal Title

      Journal of Nanoelectronics & Optoelectronics

      Volume: 8 Issue: 1 Pages: 87-90

    • DOI

      10.1166/jno.2013.1432

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structural analysis and in situ TEM mechanical tests on individual aluminum matrix/boron nitride nanotube nanohybrids2012

    • Author(s)
      Yamaguchi M., Tang D.M., Zhi C.Y., Bando Y., Shtansky D., Golberg D.
    • Journal Title

      Acta Mater.

      Volume: 60 Issue: 17 Pages: 6213-6222

    • DOI

      10.1016/j.actamat.2012.07.066

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal ion implantation of multiwalled boron nitride nanotubes2012

    • Author(s)
      Obraztsova E.A., Shtansky D.V., Sheveyko A.N., Yamaguchi M., Kovalskii A.M., Golberg D.
    • Journal Title

      Scripta Materialia

      Volume: 67(5) Pages: 507-510

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-dimensional boron nitride nanomaterials2012

    • Author(s)
      Pakdel A., Zhi C.Y., Bando Y., Golberg D.
    • Journal Title

      Materials Today

      Volume: 15 Issue: 6 Pages: 256-265

    • DOI

      10.1016/s1369-7021(12)70116-5

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local Coulomb explosion of boron nitride nanotubes under electron beam irradiation2012

    • Author(s)
      Wei X.L., Tang D.M., Chen Q., Bando Y., Golberg D.
    • Journal Title

      ACS Nano

      Volume: 7 Issue: 4 Pages: 3491-3497

    • DOI

      10.1021/nn400423y

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrahigh torsional stiffness and strength of boron nitride nanotubes2012

    • Author(s)
      Garel J., Leven I., Zhi C.Y., Nagapriya K.S., Popovitz-Biro R., Golberg D., Bando Y., Hod O., Joselevich E.
    • Journal Title

      Nano Letters

      Volume: 12 Issue: 12 Pages: 6347-6352

    • DOI

      10.1021/nl303601d

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanomaterial engineering and property studies in a transmission electron microscope2012

    • Author(s)
      Golberg D., C.Y.Zhi, Bando Y, et al
    • Journal Title

      Advanced Materials

      Volume: 24 Issue: 2 Pages: 177-194

    • DOI

      10.1002/adma.201102579

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thin-walled B-C-N ternary microtubes : from synthesis to electrical, CL and FE properties2012

    • Author(s)
      Lin J., Huang Y., Tang C., Zou J., Golberg D.
    • Journal Title

      Journal of Materials Chemistry

      Volume: (on line) Issue: 16 Pages: 8134-8134

    • DOI

      10.1039/c2jm16844h

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties of bamboo-like BN nanotubes by in situ TEM and MD simulations : strengthening effect of interlocked joint interfaces2011

    • Author(s)
      Tang D.M., Ren C.L., Wei X.L., Liu C., Bando Y., Golberg D.
    • Journal Title

      ACS Nano

      Volume: 5 Issue: 9 Pages: 7362-7368

    • DOI

      10.1021/nn202283a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Powder Metallurgy Routes Toward Al-BN Nanotube Composites, Their Morphologies, Structures and Mechanical Properties2014

    • Author(s)
      Maho Yamaguchi, Fanqiang Meng, Konstantin Faerstein, Yoshio Bando, Koichi Tsuchiya, Dmitri Golberg
    • Organizer
      MANA International Symposium
    • Place of Presentation
      エポカルつくば
    • Related Report
      2013 Annual Research Report
  • [Presentation] In situ TEM for nanomaterail property studies : advances and challenges (Keynote lecture)2013

    • Author(s)
      Golberg D.
    • Organizer
      China Nano-2013
    • Place of Presentation
      Beijing
    • Year and Date
      2013-09-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Structural metals / boron nitride nanotube composites by high pressure torsion2013

    • Author(s)
      Maho Yamaguchi, Chunyi Zhi, Yoshio Bando, Dai-Ming Tang, Konstantin Faerstein, Dmitry Shtansky, Dmitri Golberg
    • Organizer
      MRS Fall
    • Place of Presentation
      ボストン、アメリカ
    • Related Report
      2013 Annual Research Report
  • [Presentation] In situ TEM for nanomaterial property studies: advances and challenges2013

    • Author(s)
      Dmitri Golberg
    • Organizer
      China-Nano
    • Place of Presentation
      北京、中国
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Al/BN nanotube composites2013

    • Author(s)
      Maho Yamaguchi, Fanqiang Meng, Konstantin Faerstein, Yoshio Bando, Koichi Tsuchiya, Dmitri Golberg
    • Organizer
      Nanotube 2013
    • Place of Presentation
      Espoo,Finland
    • Related Report
      2013 Annual Research Report
  • [Presentation] Diverse inorganics for various energy applications2012

    • Author(s)
      Golberg D.
    • Organizer
      MRS Spring Meeting
    • Place of Presentation
      San-Francisco, USA
    • Year and Date
      2012-04-09
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] High-resolution transmission electron microscope as a tool for nanomaterial property studies2012

    • Author(s)
      Golberg D.
    • Organizer
      22th Australian Microscopy Conference
    • Place of Presentation
      Perth, Australia(招待講演)
    • Year and Date
      2012-02-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Boron nitride nanotubes : past, present and future2012

    • Author(s)
      Golberg D.
    • Organizer
      12th International Conference on the Science and Technology of Nanotubes
    • Place of Presentation
      Brisbane Convention Center, Queensland, Australia
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] In situ TEM measurements of nanotube and nanosheet properties2012

    • Author(s)
      Golberg D.
    • Organizer
      Microscopy and Microanalysis
    • Place of Presentation
      Phoenix, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Diverse “Nanoinorganics” for various enargy applications2012

    • Author(s)
      Golberg D.
    • Organizer
      Materials Research Society Spring meeting
    • Place of Presentation
      San Francisco, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Boron Nitride Nanotubes2012

    • Author(s)
      Golberg D.
    • Organizer
      13th International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] "Heterogeneous nanotubes", in "Carbon Meta-nanotubes: synthesis, properties and applications", ed. M. Monthioux2011

    • Author(s)
      Golberg D., Terrones M.
    • Publisher
      Wiley & Sons(doi:10.1002/9781119954743)
    • Related Report
      2013 Final Research Report
  • [Book] Heterogeneous nanotubes, in "Carbon Meta-nanotubes : synthesis, properties and applications"2011

    • Author(s)
      Golberg D., Terrones M.
    • Publisher
      Wiley & Sons Ltd
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.nims.go.jp/units/u_nanotubes/index_e.html

    • Related Report
      2013 Final Research Report
  • [Remarks] MANA website

    • URL

      http://www.nims.go.jp/mana/people/principal_investigator/d_golberg/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] Nanotube group website

    • URL

      http://www.nims.go.jp/nanotube/index-e.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.nims.go.jp/units/unanotubes/indexe.html

    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 窒化ホウ素ナノチューブの製造方法2011

    • Inventor(s)
      板東義雄, Zhi C.Y., Golberg D.
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Acquisition Date
      2011-09-09
    • Related Report
      2013 Final Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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